ChemicalBook > CAS DataBase List > Silver trifluoroacetate

Silver trifluoroacetate

Product Name
Silver trifluoroacetate
CAS No.
2966-50-9
Chemical Name
Silver trifluoroacetate
Synonyms
TRIFLUOROACETIC ACID SILVER SALT;Silver 2,2,2-trifluoroacetate;SILVER TRIFLUOROACETATE;Silvertrifluoroacetate98%;Trifluoroacetoxysilver(I);SILVER(I) TRIFLUOROACETATE;Silver trifluoroacetate 98%;SILVER TRIFLUOROACETIC ACID;Silvertrifluoroacetate,min.98%;Silver trifluoroacetate ,97.5%
CBNumber
CB6708364
Molecular Formula
C2AgF3O2
Formula Weight
220.88
MOL File
2966-50-9.mol
More
Less

Silver trifluoroacetate Property

Melting point:
257-260 °C (dec.) (lit.)
storage temp. 
Store below +30°C.
form 
Crystalline Powder
color 
Light beige to gray
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
BRN 
3634022
CAS DataBase Reference
2966-50-9(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, trifluoro-, silver(1+) salt (2966-50-9)
More
Less

Safety

Hazard Codes 
Xi,T,N
Risk Statements 
36/38-50-36/37/38
Safety Statements 
26-61-36/39
WGK Germany 
3
3-8
Hazard Note 
Toxic/Hygroscopic
TSCA 
T
HazardClass 
HYGROSCOPIC, TOXIC
HazardClass 
9
HS Code 
28432900
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18003
Product name
Silver trifluoroacetate
Purity
for synthesis
Packaging
10g
Price
$296
Updated
2024/03/01
Sigma-Aldrich
Product number
482307
Product name
Silver trifluoroacetate
Purity
≥99.99% trace metals basis
Packaging
1g
Price
$72.2
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18003
Product name
Silver trifluoroacetate
Purity
for synthesis
Packaging
25g
Price
$706
Updated
2024/03/01
Sigma-Aldrich
Product number
482307
Product name
Silver trifluoroacetate
Purity
≥99.99% trace metals basis
Packaging
2.5g
Price
$164
Updated
2024/03/01
Alfa Aesar
Product number
013933
Product name
Silver trifluoroacetate, 98%
Packaging
5g
Price
$59.9
Updated
2024/03/01
More
Less

Silver trifluoroacetate Chemical Properties,Usage,Production

Chemical Properties

light beige to grey crystalline powder

Uses

Silver Trifluoroacetate functions as a catalyst in the synthesis of cyclobutene-fused azepines/dihydropyridines.

Application

Silver trifluoroacetate is the silver salt of trifluoroacetic acid and is used as a Lewis acid catalyst. It is used as an important raw material for the preparation of triethylsilyl trifloroacetate and triphenylmethyl trifluoroacetate. Further, it is used as a catalyst in the preparation of 4-iodoveratrole from veratrole by reacting with iodine.

Synthesis

Silver trifluoroacetate is prepared by the reaction of silver oxide and trifluoroacetic acid.
Reaction equation: Ag2O+2CF3COOH→2CF3COOAg+H2O
Reaction: 187g (0.81mol) of silver oxide was weighed and suspended in 200mL of water, and 177g (1.55mol) of trifluoroacetic acid was added. After filtration, the filtrate was evaporated to dryness under reduced pressure. The residue was extracted with ether in a Soxhlet extractor. Alternatively, dissolve the residue in 1.2L of ether and filter through a thin layer of activated carbon. After distilling off the ether, 300g of the product was obtained with a yield of 83%.

Purification Methods

The extract is filtered and evaporated to dryness, then the powdered residue is completely dried in a vacuum desiccator over silica gel. Its solubility in Et2O is 33.5g in 750mL. It can be recrystallised from *C6H6 (solubility is: 1.9g in 30mL of *C6H6, and 33.5g will dissolve in 750mL of anhydrous Et2O). [Traynham & Dehn J Org Chem 23 1545 1958, Haszeldine J Chem Soc 584 1951.] Store it in the dark. It is also soluble in trifluoroacetic acid (15.2% at 30o), toluene, o-xylene and dioxane [Hara & Cady J Am Chem Soc 76 4285 1954]. [Beilstein 2 IV 461.]

Silver trifluoroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Silver trifluoroacetate Suppliers

Nanjing Pharmaluxury Co., Ltd.
Tel
025-83726959 15851816062
Fax
025-8666-0986
Email
goodsalejs@163.com
Country
China
ProdList
128
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
Advantage
60
SHANG FLUORO
Tel
021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
375
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8415
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9414
Advantage
66
More
Less

View Lastest Price from Silver trifluoroacetate manufacturers

henan kanbei chemical co.,ltd
Product
Silver trifluoroacetate 2966-50-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-22
Career Henan Chemical Co
Product
Silver trifluoroacetate 2966-50-9
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-20

2966-50-9, Silver trifluoroacetateRelated Search:


  • trifluoro-aceticacisilver(1++)salt
  • SILVER TRIFLUOROACETATE
  • SILVER(I) TRIFLUOROACETATE
  • TRIFLUOROACETIC ACID SILVER SALT
  • SILVER TRIFLUOROACETATE, 99.99+%
  • Silvertrifluoroacetate,min.98%
  • Trifluoroacetic acid silver(I) salt
  • Acetic acid, trifluoro-, silver(1+) salt
  • Silver trifluoroacetate 98%
  • Silvertrifluoroacetate98%
  • Silver 2,2,2-trifluoroacetate
  • Silver trifluoroacetate, min. 98%
  • Trifluoroacetoxysilver(I)
  • Trifluoroacetic acid, silver salt,98%
  • Trifluoroacetic acid, silver saltSilver trifluoroacetate
  • Trifluoroacetic acid, silver salt, 98% 25GR
  • Silver trifluoroacetate,98% AgOOCCF3
  • 5,6-DIHYDRO-2-ISOPROPENYL-4,4,6-TRIMETHY
  • SILVER TRIFLUOROACETATE FOR SYNTHESIS
  • Silver trifluoroacetate ,97.5%
  • Silver(I) 2,2,2-trifluoroethanoate, 2,2,2-Trifluoroethanoic acid, silver(I) salt
  • Silver(I) trifluoroacetate 98%
  • Silver(I) 2,2,2-trifluoroacetate
  • (2,2,2-trifluoroacetoxy)silver
  • Silver trifluoroacetate >=99.99% trace Metals basis
  • SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%
  • Acetic acid, 2,2,2-trifluoro-, silver(1+) salt (1:1)
  • Silver trifluoroacetate ISO 9001:2015 REACH
  • 2966-50-9 Silver trifluoroacetate
  • SILVER TRIFLUOROACETIC ACID
  • 2966-50-9
  • CF3COOAg
  • C2F3O2Ag
  • C2AgF3O2
  • AgOOCCF3
  • Catalysis and Inorganic Chemistry
  • metal acetate salt
  • Ag
  • Organic-metal salt