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6-Benzylaminopurine

Product Name
6-Benzylaminopurine
CAS No.
1214-39-7
Chemical Name
6-Benzylaminopurine
Synonyms
BA;6-BA;N-BUTYL ACRYLATE;BAP;6-BENZYLADENINE;aminopurine;BENZYLADENINE;6BAP;BUTYL 2-PROPENOATE;ACRYLIC ACID BUTYL ESTER
CBNumber
CB6740007
Molecular Formula
C12H11N5
Formula Weight
225.25
MOL File
1214-39-7.mol
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6-Benzylaminopurine Property

Melting point:
230-233 °C
Boiling point:
145 °C(lit.)
Density 
0.899 g/mL at 20 °C
vapor density 
>1 (vs air)
vapor pressure 
3.3 mm Hg ( 20 °C)
refractive index 
n20/D 1.418(lit.)
Flash point:
103 °F
storage temp. 
2-8°C
solubility 
H2O: soluble
form 
Liquid
pka
9.36±0.20(Predicted)
color 
White to very faint yellow
Odor
Characteristic acrylic.
Water Solubility 
Soluble in water, methanol and acetone. Slightly soluble in ethyl acetate and dichloromethane and toluene. Insoluble in n-hexane.
BRN 
19406
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
NWBJYWHLCVSVIJ-UHFFFAOYSA-N
LogP
1.570
CAS DataBase Reference
1214-39-7(CAS DataBase Reference)
NIST Chemistry Reference
1H-purin-6-amine, n-(phenylmethyl)-(1214-39-7)
EPA Substance Registry System
N-Benzyladenine (1214-39-7)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22-22
Safety Statements 
9-24/25-37/39-26-36-23
RIDADR 
UN 2348 3/PG 3
WGK Germany 
3
RTECS 
UD3150000
F 
8
TSCA 
Yes
HS Code 
29335995
Hazardous Substances Data
1214-39-7(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 2125 mg/kg TOIZAG 19,336,72
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
1g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
5G
Price
$85.1
Updated
2024/03/01
Sigma-Aldrich
Product number
200241
Product name
6-Benzylaminopurine - CAS 1214-39-7 - Calbiochem
Purity
Plant cell division factor.
Packaging
1G
Price
$55.2
Updated
2024/03/01
Sigma-Aldrich
Product number
13151
Product name
6-Benzylaminopurine
Purity
ReagentPlus?, ≥99.0% (HPLC)
Packaging
25g
Price
$163
Updated
2024/03/01
TCI Chemical
Product number
B1088
Product name
N6-Benzyladenine
Purity
>99.0%(HPLC)(T)
Packaging
5g
Price
$60
Updated
2024/03/01
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6-Benzylaminopurine Chemical Properties,Usage,Production

Chemical Properties

Colorless to off-white or yellow powder. Corrosive. Insoluble in water, slightly soluble in ethanol, stable in acid and alkali.

Uses

6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.
6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
inhibitor of respiratory kinase in plants.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.

Application

6-Benzylaminopurine solution has been used as a component in the Murashige & Skoog medium (MS) for culturing mandarin explants and plantlets of Dendrocalamus asper (Schultes f.). It has also been used as a supplement in Nitsch and Nitsch medium (NN) of grapevine explants.

Preparation

synthesis of 6-benzylaminopurine: To 5g hypoxanthine, add 20mL SOCl2, 0.25g DMAP, 10gBTC dissolved in 20mL SOCl2. Heat and add BTC/SOCl2 dropwise. Reflux (refrigerant cooling) to complete dissolution, steam out SOCl2 (containing phosgene, which is used for recovery), evaporated (drained), cooled to room temperature to obtain a milky yellow solid (6-chloropurine and DMAP.Hcl). Directly add 4g benzylamine and 25g triethylamine to it, heat to 70～80 ℃, or microwave heating, until the 6-chloropurine reaction is complete (TLC monitoring), add ethanol, the solid filtered out is washed with ethanol, and dried to obtain 7 g of product 6-benzylaminopurine with a brown color.
Preparation and biological activity of 6-benzylaminopurine derivatives in plants and human cancer cells

Definition

ChEBI: 6-Benzylaminopurine is a member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group. It has a role as a plant metabolite and a cytokinin. It derives from an adenine.

General Description

6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture commodities.

Health Hazard

6-benzylaminopurine (6-BA) is widely used in agriculture and horticulture as plant growth regulator. Its excessive use may pose a potential risk to both environment and human health, which is causing great concern. Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations; If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin.

Agricultural Uses

6-Benzylaminopurine is a plant growth promoter, is the first applied synthetic cytokinin, mainlyused as a broad- spectrum plant growth regulator. It can be used inagriculture, horticulture, for plants at different stages, from germination to harvest. It enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.

Trade name

ABG® 3034; ACCEL®; AGTROL®; 6-BA®; BA® (growth stimulant); CHRYSAL BVB®; EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ® 4609

Safety Profile

Moderately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.

Potential Exposure

A polyamine plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in the EU countries.

Shipping

UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required.

Purification Methods

It is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]

Incompatibilities

May react with strong oxidizers such as chlorates, peroxides, nitrates, etc. May release heat on contact with water. Solid and corrosive amines are chemical bases. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

6-Benzylaminopurine Preparation Products And Raw materials

Raw materials

Acrylic acid Methanol Poly(acrylic acid)

Preparation Products

modified acrylic resin emulsion SB Adhesive for nonwoven fabric HMP muti-functional retanning agent HMP sheeting sensitized glue Acrylic latex 1-Isopropyl-4-piperidone Pressure sensitive adhesive Ethyl pyruvate Ethyl α-cyanoacrylate instantaneous adhesive nonformaldehyde resin finishing agent CN-NF^{3^} acrylate ternary copolymer bound disulfide platinum complex catalyst polyurethane photosensitive prepolymer acrylic resin emulsion FX-1 2-Pentyl-3-methyl-2-cyclopenten-1-one acrylic resin coating finish PAINT Water-soluble electrophoretic paint Pyruvic acid THERMOPLASTIC ACRYLIC RESIN Butyl acrylate coupling agent NBC-1 flocculant TS-614 EAM resin adhesive modified with diisocyanate for orthodontias leather binder CAF Styrene-acrylic latex 4-(4-(Chlorophenyl)imino)-1-isopropyl piperidine methyl 2-(2′-hydroxy phenyl)-3-methoxy acrylate WPT-S silicone modified water proof. fatliquoring and retanning agent Poly(acrylic acid) Lorcainide Silicone acrylic emulsion Construction emulsion BC-01 butadiene resin emulsion LHYJ-DS50 sizing agent NBJ for jet loom Atracurium besylate 6-benzylaminopurine hydrochloride Sodium polyacrylate N-(4-chlorophenyl)-1-isopropylpiperidin-4-amine
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6-Benzylaminopurine Suppliers

Americas 1 Australia 1 Austria 1 Belgium 1 Brazil 1 Canada 3 China 568 Czech Republic 1 Europe 5 France 3 Germany 14 India 52 Italy 2 Japan 6 Poland 1 Russia 1 Slovakia 1 South Korea 1 Switzerland 5 The Netherlands 1 Ukraine 1 United Kingdom 19 United States 76 Global 766
Carbosynth
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Molekula Limited
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Manchester Organics
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View Lastest Price from 6-Benzylaminopurine manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
Benzyladenine 1214-39-7
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-06
Hebei Longbang Technology Co., Ltd
Product
Benzyladenine 1214-39-7
Price
US $6.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-28
Shandong Deshang Chemical Co., Ltd.
Product
6-Benzylaminopurine 1214-39-7
Price
US $10.00-7.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-06

1214-39-7, 6-BenzylaminopurineRelated Search:

Benzyl alcohol EC 2.6.1.2 Triethylamine Acetaminophen Benzyl benzoate Benzyl nicotinate N-Ethylmethylamine Triethanolamine Bis(2-ethylhexyl)amine Sulfamic acid Purine Benzyltriethylammonium chloride Benzyltrimethylammonium chloride Adenine Glucosamine Dibenzylamine Benzyl isocyanate Benzyl chloride

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