N-[(Trimethylsilyl)methyl]benzylamine

Product Name: N-[(Trimethylsilyl)methyl]benzylamine
CAS No.: 53215-95-5
Chemical Name: N-[(Trimethylsilyl)methyl]benzylamine
Synonyms: SILANE BENZYL-TMSMA;N-(trimethylsilylmethyl)benzamine;Benzyl(trimethylsilylmethyl)amine;N-BENZYLAMINOMETHYLTRIMETHYLSILANE;N-(TRIMETHYLSILYLMETHYL)BENZYAMINE;N-(TRIMETHYLSILYLMETHYL)BENZYLAMINE;N-Benzyl-1-(trimethylsilyl)methylamine;N-benzyl-1-(trimethylsilyl)methanamine;N-(Trimethylsilylmethyl)benzylamine 95+%;N-Benzyl-N-[(triMethylsilyl)Methyl]aMine
CBNumber: CB6744252
Molecular Formula: C11H19NSi
Formula Weight: 193.36
MOL File: 53215-95-5.mol

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N-[(Trimethylsilyl)methyl]benzylamine Property

Boiling point:: 89-90 °C5 mm Hg(lit.)
Density: 0.88 g/mL at 25 °C(lit.)
refractive index: n20/D 1.496(lit.)
Flash point:: 205 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Liquid
pka: 9.29±0.20(Predicted)
Specific Gravity: 0.88
color: Pale yellow
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
InChI: InChI=1S/C11H19NSi/c1-13(2,3)10-12-9-11-7-5-4-6-8-11/h4-8,12H,9-10H2,1-3H3
InChIKey: WECLUYCAWLJMKM-UHFFFAOYSA-N
SMILES: C1(CNC[Si](C)(C)C)=CC=CC=C1
CAS DataBase Reference: 53215-95-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 303615
Product name: N-[(Trimethylsilyl)methyl]benzylamine
Purity: 98%
Packaging: 5g
Price: $48.5
Updated: 2022/05/15

TCI Chemical

Product number: T3000
Product name: N-[(Trimethylsilyl)methyl]benzylamine
Purity: >96.0%(GC)(T)
Packaging: 5mL
Price: $49
Updated: 2025/07/31

TRC

Product number: B124808
Product name: N-Benzyl-1-(trimethylsilyl)methanamine
Packaging: 100mg
Price: $60
Updated: 2021/12/16

SynQuest Laboratories

Product number: 7680-1-00
Product name: N-(Trimethylsilylmethyl)benzylamine
Purity: 95.0%
Packaging: 25g
Price: $77
Updated: 2021/12/16

Matrix Scientific

Product number: 075352
Product name: N-(Trimethylsilylmethyl)benzylamine
Purity: 95+%
Packaging: 100g
Price: $158
Updated: 2021/12/16

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N-[(Trimethylsilyl)methyl]benzylamine Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

N-[(Trimethylsilyl)methyl]benzylamine may be used in chemical synthesis.

General Description

N-[(Trimethylsilyl)methyl]benzylamine is useful intermediate to cyanoaminosilanes which are subsequently used as azomethine ylide equivalents.

Synthesis

4206-67-1

100-46-9

53215-95-5

General method: Benzylamine derivatives (24.3 mmol, 37 (2.6 g); 28.0 mmol, 38 (3.4 g); 28.0 mmol, 39 (3.8 g); 11.2 mmol, 40 (1.4 g); and 11.2 mmol, 41 (2.0 g)) were dissolved in acetonitrile (120 mL), added K2CO3 (37.4 mmol, 5.2 g (for 37); 46.7 mmol, 2.5 g (for 38-39); 18.7 mmol, 2.6 g (for 40-41)) and Me3SiCH2I (18.5 mmol, 4.0 g (for 37); 38.4 mmol, 59 g (for 38-39); 9.3 mmol, 2.0 g (for 40-41)). The reaction mixture was stirred for 12 h at room temperature. After completion of the reaction, the mixture was concentrated in vacuum to give a residue. The residue was ground with CH2Cl2, dried and concentrated again under vacuum. Finally, it was purified by silica gel column chromatography (eluent ratio: EtOAc:hexane=1:8~1:15) to give the products 421 (3.2 g, 89%), 43 (3.85 g, 79%), 442 (3.3 g, 63%), 45 (1.51 g, 76%) and 46 (1.9 g, 78%), respectively.

References

[1] Tetrahedron Letters, 2015, vol. 56, # 23, p. 3014 - 3018
[2] Organic and Biomolecular Chemistry, 2016, vol. 14, # 44, p. 10502 - 10510
[3] Tetrahedron Letters, 2017, vol. 58, # 10, p. 949 - 954
[4] Tetrahedron, 2017, vol. 73, # 44, p. 6249 - 6261

N-[(Trimethylsilyl)methyl]benzylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N-[(Trimethylsilyl)methyl]benzylamine Suppliers

China 153 Germany 1 India 5 Japan 1 Singapore 1 Slovakia 1 Switzerland 1 United Kingdom 3 United States 23 Global 189

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JinYan Chemicals(ShangHai) Co.,Ltd.

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Shangchem Co., Ltd.

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View Lastest Price from N-[(Trimethylsilyl)methyl]benzylamine manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: N-[(Trimethylsilyl)methyl]benzylamine 53215-95-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-07-07

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: N-(Trimethylsilylmethyl)benzylamine 53215-95-5
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-27

Zhuozhou Wenxi import and Export Co., Ltd

Product: N-[(Trimethylsilyl)methyl]benzylamine 53215-95-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

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<i>N</i>-(Trimethylsilylmethyl)benzylamine

N-BENZYLAMINOMETHYLTRIMETHYLSILANE

N-(TRIMETHYLSILYLMETHYL)BENZYLAMINE

SILANE BENZYL-TMSMA

1-phenyl-N-(trimethylsilylmethyl)methanamine

53215-95-5

C11H19NSi

C6H5CH2NHCH2SiCH33

AMINE

Building Blocks

C11 to C37

Nitrogen Compounds

Organic Building Blocks

Amines

C11 to C38

Nitrogen Compounds

Amines and Anilines