ChemicalBook > CAS DataBase List > Acetoacetic Acid
Acetoacetic Acid
- Product Name
- Acetoacetic Acid
- CAS No.
- 541-50-4
- Chemical Name
- Acetoacetic Acid
- Synonyms
- ACETOACETATE;3-oxobutanoic acid;diacetic acid;Acetoacitic acid;3-ketobutyric acid;3-oxobutanate;3-KETOBUTYRATE;acetoaceticaci;Acetoacetic Acid;3-Oxobutyric acid
- CBNumber
- CB71015921
- Molecular Formula
- C4H6O3
- Formula Weight
- 102.09
- MOL File
- 541-50-4.mol
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Acetoacetic Acid Property
- Melting point:
- 36-37°
- Boiling point:
- 131.37°C (rough estimate)
- Density
- 1.1717 (rough estimate)
- refractive index
- 1.4540 (estimate)
- pka
- 3.58(at 18℃)
- PH
- 3.4(1 mM solution);2.83(10 mM solution);2.3(100 mM solution)
- Water Solubility
- sol H2O, alcohol
- LogP
- -0.467 (est)
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Safety
- RIDADR
- 1759
- HazardClass
- 8
- PackingGroup
- III
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N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- CHM0310800
- Product name
- ACETOACETIC ACID
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $505.59
- Updated
- 2021/12/16
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Acetoacetic Acid Chemical Properties,Usage,Production
Uses
In organic syntheses.
Definition
ChEBI: A 3-oxo monocarboxylic acid that is butyric acid bearing a 3-oxo substituent.
Reactivity Profile
Acetone enolate equivalent in alkylations, carbonyl additions, conjugate additions, and diazonium ion coupling reactions[4-7].
Synthesis
Traditionally prepared by base hydrolysis of Ethyl Acetoacetate. A high yield synthesis by acid hydrolysis of Diketene is also reported[1-3].
storage
Handling, Storage, and Precautions: acetoacetic acid is extremely hygroscopic but can be stored under vacuum in a freezer for several weeks with little change. It decomposes rapidly to acetone and carbon dioxide when heated above the melting point. Use in a fume hood.
References
1. Grayson, D. H.; Tuite, M. R. J. JCS(P1) 1986, 2137
2. Grande, K. D.; Rosenfeld, S. M. JOC 1980, 45, 1626.
3. Krueger, R. C. JACS 1952, 74, 5536.
4. Kjonaas, R. A.; Patel, D. D. TL 1984, 25, 5467.
5. Grayson, D. H.; Tuite, M. R. J. JCS(P1) 1986, 2137.
6. Fujii, M.; Terao, Y.; Sekiya, M. CPB 1974, 22, 2675.
7. (a) Parmerter, S. M. OR 1959, 10, 1. (b) Phillips, R. R. OR 1959, 10, 143.
Acetoacetic Acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Acetoacetic Acid manufacturers
Shaanxi Dideu Medichem Co. Ltd
- Product
- Acetoacetic Acid 541-50-4
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2020-01-06
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