Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI)

Product Name: Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI)
CAS No.: 1439-09-4
Chemical Name: Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI)
Synonyms: 5-bromo-4-methylpyrimidine;Pyrimidine, 5-bromo-4-methyl-;5-Bromo-4-methylpyrimidine 98%;Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI);Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) ISO 9001：2015 REACH
CBNumber: CB71082512
Molecular Formula: C5H5BrN2
Formula Weight: 173.01
MOL File: 1439-09-4.mol

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Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) Property

Melting point:: 215℃
Boiling point:: 221.3±20.0℃ (760 Torr)
Density: 1.596±0.06 g/cm3 (20 ºC 760 Torr)
Flash point:: 87.7±21.8℃
storage temp.: 2-8°C
pka: 0.50±0.16(Predicted)
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C5H5BrN2/c1-4-5(6)2-7-3-8-4/h2-3H,1H3
InChIKey: ALRPHTZYJPXPGN-UHFFFAOYSA-N
SMILES: C1=NC=C(Br)C(C)=N1

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Safety

Hazard Codes: Xn
Risk Statements: 22-37/38-41
Safety Statements: 26-39
HazardClass: IRRITANT
HS Code: 2933599590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B697643
Product name: 5-Bromo-4-methylpyrimidine
Packaging: 50mg
Price: $55
Updated: 2021/12/16

Matrix Scientific

Product number: 057914
Product name: 5-Bromo-4-methylpyrimidine
Purity: 95%
Packaging: 250mg
Price: $49
Updated: 2021/12/16

AK Scientific

Product number: W3133
Product name: 5-Bromo-4-methylpyrimidine
Packaging: 250mg
Price: $67
Updated: 2021/12/16

Matrix Scientific

Product number: 057914
Product name: 5-Bromo-4-methylpyrimidine
Purity: 95%
Packaging: 1g
Price: $109
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H32-9-DC
Product name: 5-Bromo-4-methylpyrimidine
Purity: 98%
Packaging: 250mg
Price: $176
Updated: 2021/12/16

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Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) Chemical Properties,Usage,Production

Synthesis

4595-59-9

917-54-4

1439-09-4

An ether solution of methyl lithium (109 mmol, 1.09 M, 100 mL) was added dropwise to an ether (100 mL) solution of 5-bromopyrimidine (17.3 g, 109 mmol) at room temperature. The resulting reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, water (1.96 mL, 109 mmol) and a solution of tetrahydrofuran (150 mL) of 2,3-dichloro-5,6-dicyano-p-benzoquinone (24.7 g, 109 mmol) were added to the reaction mixture, and stirring was continued for 16 hours at room temperature. Upon completion of the reaction, water and ethyl acetate were added for extraction and the organic layer was separated. The organic layer was washed with 1 M aqueous sodium hydroxide, dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate=1/1) to afford the target product 5-bromo-4-methylpyrimidine (2.9 g, 15% yield). Product properties: yellow oil. 1H-NMR (CDCl3) δ: 2.65 (s, 3H), 8.72 (s, 1H), 8.98 (s, 1H).

References

[1] Patent: WO2009/57827, 2009, A1. Location in patent: Page/Page column 167

Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) Suppliers

China 112 Europe 1 India 2 Switzerland 1 United Kingdom 1 United States 14 Global 131

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View Lastest Price from Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 5-BroMo-4-MethylpyriMidine 1439-09-4
Price: US $1.00-900.00/KG
Min. Order: 1g
Purity: 98%
Supply Ability: 50ton
Release date: 2020-05-15

Dideu Industries Group Limited

Product: Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) 1439-09-4
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons Min
Release date: 2021-12-06

Career Henan Chemical Co

Product: Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) 1439-09-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-08

1439-09-4, Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI)Related Search:

5-Bromo-2,4-dichloro-6-methylpyrimidine 2-AMINO-5-BROMO-4-HYDROXY-6-METHYLPYRIMIDINE 5-Bromo-2-(methylthio)pyrimidine-4-carboxylic acid 4-AMINO-5-BROMO-6-METHYLPYRIMIDINE 2-Amino-5-bromo-4,6-dimethylpyrimidine 5-Bromo-2-methyl-4-pyrimidinecarboxylic acid 2-AMINO-5-BROMO-4-HYDROXY-6-PHENYLPYRIMIDINE 2-Amino-4-methyl-5-bromopyrimidine 5-Bromo-4-phenylpyrimidine 5-BROMO-4-HYDRAZINO-6-METHYLPYRIMIDINE 2-PYRIMIDINAMINE, 5-BROMO-4-CHLORO-6-METHYL- 2-(5-BROMO-2-CHLOROPYRIMIDIN-4-YL)-2-(1-METHYL-2,3-DIHYDRO-1H-BENZO[D]IMIDAZOL-2-YLIDEN)ACETONITRILE 2-(1H-BENZO[D]IMIDAZOL-2-YL)-2-(5-BROMO-2-CHLORO-6-METHYLPYRIMIDIN-4-YL)ACETONITRILE 5-BROMO-4-HYDRAZINO-2,6-DIPHENYLPYRIMIDINE 2-AMINO-4-METHYL-5-BROMO-6-TRIFLUOROPYRIMIDINE 4,5-DIBROMO-2,6-DIPHENYLPYRIMIDINE SULFABROMOMETHAZINE (PHENYL-13C6) 2-(5-BROMO-2-CHLORO-6-METHYLPYRIMIDIN-4-YL)-2-(1-METHYL-2,3-DIHYDRO-1H-BENZO[D]IMIDAZOL-2-YLIDEN)ACETONITRILE

Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI)

5-bromo-4-methylpyrimidine

Pyrimidine, 5-bromo-4-methyl-

Pyrimidine, 5-bromo-4-methyl- (7CI,8CI,9CI) ISO 9001：2015 REACH

5-Bromo-4-methylpyrimidine 98%

1439-09-4

Heterocycle-Pyrimidine series

PYRIMIDINE