ChemicalBook > CAS DataBase List > 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE

3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE

Product Name
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
CAS No.
856834-95-2
Chemical Name
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
Synonyms
3-bromo-2-chloro-5-nitro-6-picolin;5-Bromo-6-chloro-3-nitro-2-picoline;3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE;2-Picoline, 5-bromo-6-chloro-3-nitro-;Chloro-3-bromo-5-nitro-6-methylpyridine;3-Bromo-2-chloro-6-methyl-5-nitropyridine;3-Bromo-2-chloro-5-nitro-6-methylpyridine;2-Chloro-3-bromo-5-nitro-6-methylpyridine;Pyridine, 3-bromo-2-chloro-6-methyl-5-nitro-;3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE ISO 9001:2015 REACH
CBNumber
CB71093017
Molecular Formula
C6H4BrClN2O2
Formula Weight
251.47
MOL File
Mol file
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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Property

Melting point:
93℃
Boiling point:
296℃
Density 
1.810
Flash point:
133℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
pka
-4.03±0.10(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C6H4BrClN2O2/c1-3-5(10(11)12)2-4(7)6(8)9-3/h2H,1H3
InChIKey
WKGHUAZJNBXABN-UHFFFAOYSA-N
SMILES
C1(Cl)=NC(C)=C([N+]([O-])=O)C=C1Br
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS021075
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
25 mg
Price
$107
Updated
2025/07/31
TRC
Product number
B684563
Product name
3-Bromo-2-chloro-5-nitro-6-picoline
Packaging
50mg
Price
$55
Updated
2021/12/16
ChemScene
Product number
CS-0019331
Product name
2-Picoline,5-bromo-6-chloro-3-nitro-
Purity
99.23%
Packaging
5g
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB141897
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
50mg
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB141897
Product name
3-Bromo-2-chloro-6-methyl-5-nitropyridine
Packaging
100mg
Price
$120
Updated
2021/12/16
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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Chemical Properties,Usage,Production

Chemical Properties

light yellow crystal powder

Synthesis

874493-25-1

856834-95-2

3-Bromo-6-methyl-5-nitropyridin-2-ol (9.2 g, 36.7 mmol) was used as starting material, which was dissolved in phosphorus oxychloride (POCl3, 56.2 g, 366.7 mmol). The reaction mixture was stirred and reacted at 80 °C overnight. Upon completion of the reaction, the mixture was slowly poured into water (800 mL) and the solid product was precipitated. The solid was collected by filtration and dried to afford the target compound 3-bromo-2-chloro-5-nitro-6-methylpyridine (7.5 g, 81.4% yield).

References

[1] Patent: US2018/170909, 2018, A1. Location in patent: Paragraph 1925; 1926
[2] Patent: WO2015/89192, 2015, A1. Location in patent: Paragraph 00275; 00276
[3] Patent: WO2016/37005, 2016, A1. Location in patent: Paragraph 00259-00260
[4] Patent: WO2008/101682, 2008, A2. Location in patent: Page/Page column 42-43

3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE Suppliers

Nanjing YakeLun Pharmaceutical Co., Ltd.
Tel
025-66096098 3165145969
Fax
QQ3165145969
Email
sales@accoronpharm.com
Country
China
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3924
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55
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
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57
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
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66
Nan Jing Dirise Chemcial Co.,LTD
Tel
025-52161033 15312098939
Fax
025-83254025
Email
sales@njdrschem.com
Country
China
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Wuhan Arike Technology Co., Ltd.
Tel
027- 51832457 94518350
Fax
E-Mail Inquiry
Country
China
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746
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62
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
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57
Shanghai ZaiQi Bio-Tech Co., Ltd.
Tel
021-54824098, 021-37212705 021-37212706, 13391256916
Fax
021-54824069
Email
sales@chemzq.com
Country
China
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Chiba Pharmaceutical Science and technology Co, Ltd.
Tel
0531-81313138 13066006660
Fax
QQ: 3366077777
Email
chibapharm@foxmail.com
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China
ProdList
3991
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Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6175
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58
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
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58
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View Lastest Price from 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE 856834-95-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-06-03
Shaanxi Dideu Medichem Co. Ltd
Product
3-bromo-2-chloro-5-nitro- 6-picoline 856834-95-2
Price
US $1.00-1.00/Kg/Drum
Min. Order
1g
Purity
99%
Supply Ability
50tons
Release date
2020-05-13
Henan Fengda Chemical Co., Ltd
Product
3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE 856834-95-2
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08

856834-95-2, 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINERelated Search:


  • 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE
  • 3-Bromo-2-chloro-6-methyl-5-nitropyridine
  • 5-Bromo-6-chloro-3-nitro-2-picoline
  • 3-bromo-2-chloro-5-nitro-6-picolin
  • 2-Picoline, 5-bromo-6-chloro-3-nitro-
  • 2-Chloro-3-bromo-5-nitro-6-methylpyridine
  • Pyridine, 3-bromo-2-chloro-6-methyl-5-nitro-
  • 3-BROMO-2-CHLORO-5-NITRO-6-PICOLINE ISO 9001:2015 REACH
  • 3-Bromo-2-chloro-5-nitro-6-methylpyridine
  • Chloro-3-bromo-5-nitro-6-methylpyridine
  • 856834-95-2