ChemicalBook > CAS DataBase List > Amyl acetate

Amyl acetate

Product Name
Amyl acetate
CAS No.
628-63-7
Chemical Name
Amyl acetate
Synonyms
PENTYL ACETATE;N-AMYL ACETATE;ACETIC ACID PENTYL ESTER;N-PENTYL ACETATE;n-amyl;1-PENTYL ACETATE;normal;PEAR OIL;ai3-02729;Birnenoel
CBNumber
CB7166381
Molecular Formula
C7H14O2
Formula Weight
130.18
MOL File
628-63-7.mol
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Amyl acetate Property

Melting point:
−100 °C(lit.)
Boiling point:
142-149 °C(lit.)
Density 
0.876 g/mL at 25 °C(lit.)
vapor density 
4.5 (vs air)
vapor pressure 
4 mm Hg ( 20 °C)
refractive index 
n20/D 1.402(lit.)
Flash point:
75 °F
storage temp. 
Store below +30°C.
solubility 
10g/l
form 
Powder
color 
White
Odor
Pleasant banana-like; mild; characteristic banana- or pear-like odor.
Odor Type
fruity
explosive limit
1.1-7.5%(V)
Water Solubility 
10 g/L (20 ºC)
FreezingPoint 
-70.8℃
BRN 
1744753
Henry's Law Constant
10.73 at 37 °C (static headspace-GC, Bylaite et al., 2004)
Dielectric constant
5.0（20℃）
Exposure limits
TLV-TWA 100 ppm (～525 mg/m3) (ACGIH, MSHA, and OSHA); IDLH 4000 ppm.
LogP
2.300
CAS DataBase Reference
628-63-7(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, pentyl ester(628-63-7)
EPA Substance Registry System
n-Amyl acetate (628-63-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-66
Safety Statements 
23-25-24/25
RIDADR 
UN 1104 3/PG 3
WGK Germany 
3
RTECS 
AJ1925000
F 
21
Autoignition Temperature
680 °F &_& 714 °F
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29153930
Hazardous Substances Data
628-63-7(Hazardous Substances Data)
Toxicity
Acute oral LD50 for rats 6,500 mg/kg (quoted, RTECS, 1985).
IDLA
1,000 ppm
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18700
Product name
n-Amyl acetate
Purity
EMPLURA?
Packaging
1L
Price
$105
Updated
2024/03/01
Sigma-Aldrich
Product number
46022
Product name
Pentyl acetate
Purity
puriss. p.a., ≥98.5% (GC)
Packaging
250ML
Price
$86.9
Updated
2024/03/01
Sigma-Aldrich
Product number
46022
Product name
Pentyl acetate
Purity
puriss. p.a., ≥98.5% (GC)
Packaging
1L
Price
$187
Updated
2024/03/01
Sigma-Aldrich
Product number
109584
Product name
Pentyl acetate
Purity
99%
Packaging
250ml
Price
$77.1
Updated
2024/03/01
Sigma-Aldrich
Product number
109584
Product name
Pentyl acetate
Purity
99%
Packaging
1l
Price
$179
Updated
2024/03/01
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Amyl acetate Chemical Properties,Usage,Production

Description

All isomers of amyl acetate are highly flammable, colorless to yellow, watery liquids. The n- and isoisomers have a persistent, fruity, banana-like or pear-likeodor. The sec-isomer has a mild fruity odor. Molecularweight of isomers 5 130.21. Hazard Identification (basedon NFPA-704 M Rating System): (sec-isomer) Health 2,Flammability 3, Reactivity 0.n-isomer: Boiling point= 121℃; Melting/Freezingpoint=2 72℃; Specific gravity= 0.876 at 20℃; Liquidsurface tension= 5 0.012 N/m at 30℃; Liquid water interfacial tension 5 (estimate) 0.05 N/m at 17℃; Relative vapordensity (air= 1) 5 4.5; Ratio of specific heats of vapor(gas) 5 1.1; Latent heat of vaporization= 3.1 3 105 J/kg;Heat of combustion 5 2 310.8 3 105 J/kg; Vaporpressure= 0.93 kPa at 20℃; Flash point= 16°21℃, 25℃(cc); Autoignition temperature= 360℃; Explosive limits:LEL 5 1.0%; UEL 5 7.5%; Odorthreshold 5 0.0075°7.3 ppm.sec-isomer: Boiling point= 121℃; Melting/Freezingpoint=2 148℃; Critical temperature= 326℃; Criticalpressure= 411.6 psia 5 28.0 atm 5 2.83 MN/m2; Specificgravity= 0.861°0.866 at 20℃; Liquid surface tension 5 28.9 dynes/cm 5 0.0289 N/m at 20℃; Liquidwater interfacial tension 5 (estimate) 0.0441 N/m at20℃; Relative vapor density (air= 1) 5 4.5; Ratio of specific heats of vapor (gas) 5 (estimate).1°1.1 at 20℃;Latent heat of vaporization= (estimate) 5 3.0 3 105 J/kg;Heat of combustion 5 2 14.402 Btu/lb 5 2 8000cal/g 5 2 334.9 3 105 J/kg; Vapor pressure= 7 mmHg at20℃; Flash point= 32℃; Explosive limits: LEL 5 1.1%;UEL 5 7.0%; Odor threshold 5 0.002 ppm.tert-isomer: Boiling point= 125℃; Flash point= 26℃;Explosive limits: LEL 5 1.0%; UEL 5 7.5%; Odor threshold 5 0.08 *0.0006 in water.iso-isomer: Boiling point= 142℃; Melting/Freezingpoint=2 78.5℃; Critical temperature 326.1℃; Criticalpressure= 2.84 MN/m2; Specific gravity= 0.876 at 15℃;Liquid surface tension= 5 0.02477 N/m at 20℃; Liquid waterinterfacial tension5 0.0502 N/m at 15℃; Relative vapor density (air= 1) 5 4.5; Ratio of specific heats of vapor (gas) 5(estimate).1°1.1; Latent heat of vaporization= (estimate) 53.07 3 105 J/kg; Heat of combustion 5 2 334.9 3 105 J/kg;Vapor pressure= 4 mmHg at 20℃; Autoignitiontemperature5 379℃; Flash point= 25℃; Autoignitiontemperature5 379℃; Explosive limits: LEL5 1.2% at 100℃;UEL 5 7.5%; Odor threshold 5 0.015.They all float on water and have poor (slight to negligible)solubility. Water contact forms a flammable, irritatingvapor. Hazard Identification (based on NFPA-704 M RatingSystem): Health 1, Flammability 3, Reactivity 0.*The range of accepted odor threshold values is quite broadand caution should be used in relying on odor alone as awarning of potentially hazardous exposure.

Chemical Properties

All isomers of amyl acetate are highly flammable, colorless to yellow, watery liquids.

Physical properties

Colorless liquid with a sweet, banana-like odor. A detection odor threshold concentration of 275 μg/m3 (52 ppbv) was reported by Punter (1983). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 1,650 ppmv.

Uses

A colorless liquid made by adding sulfuric acid to a mixture of amyl alcohol and acetic acid with subsequent recovery by distillation. It is slightly soluble in water but insoluble in alcohol. Amyl acetate was used as one of the solvents in making celluloid film and as fuel for the Alteneck lamp, adopted as the standard light in sensitometry by the International Congress of Photography in 1889.

Uses

Banana essence. Used as test odorant in studies of olfactory function and in studies of the psychosocial effects of odor.

Uses

n-Amyl acetate is used as a solvent forlacquers and paints; in fabrics’ printing; innail polish; and as a flavoring agent.

Production Methods

n-Amyl acetate is the produced by the esterification of N-amyl alcohol with acetic acid.

Definition

ChEBI: An acetate ester of pentanol.

Synthesis Reference(s)

Synthetic Communications, 21, p. 1545, 1991 DOI: 10.1080/00397919108021051
Tetrahedron Letters, 50, p. 395, 2009 DOI: 10.1016/j.tetlet.2008.11.024
The Journal of Organic Chemistry, 45, p. 2915, 1980 DOI: 10.1021/jo01302a035

General Description

A mixture of isomers. A clear colorless liquid with a banana-like odor. Flash point varies from 65°F. to 95°F. Less dense (at 7.2 lb / gal) than water and slightly soluble in water. Hence floats on water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

AMYL ACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Amyl acetate is incompatible with the following: Nitrates; strong oxidizers, alkalis & acids .

Hazard

Flammable, high fire risk. Explosive limits in air 1.1–7.5%.

Health Hazard

n-Amyl acetate is a narcotic, an irritant tothe eyes and respiratory passage, and at highconcentrations, an anesthesia. Exposure toabout 300 ppm in air for 30 minutes mayproduce eye irritation in humans. Higherconcentrations (>1000 ppm) may produceheadache, somnolence, and narcotic effects.Exposure to 5200 ppm for 8 hours was lethalto rats. It is more toxic than the loweraliphatic esters. An LD50 value in rats iswithin the range 6000 mg/kg.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Moderately toxic by intraperitoneal route. Human systemic effects by inhalation: conjunctiva irritation, headache, and somnolence. A human eye irritant. Apparently more toxic than butyl acetate. Chronic toxicity is of a low order. Dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Moderately explosive in the form of vapor when exposed to flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS, AMYL ALCOHOL, and ACETIC ACID.

Potential Exposure

(n-isomer): Primary irritant (w/o allergic reaction), (sec-isomer) Human Data. Amyl acetates are used as industrial solvents and in the manufacturing and dry-cleaning industry; making artificial fruit-flavoring agents; cements, coated papers, lacquers; in medications as an inflammatory agent; pet repellents, insecticides and miticide. Many other uses.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Carcinogenicity

Not listed by ACGIH, California Proposition 65, IARC, NTP, or OSHA.

Source

Identified among 139 volatile compounds identified in cantaloupe (Cucumis melo var. reticulates cv. Sol Real) using an automated rapid headspace solid phase microextraction method (Beaulieu and Grimm, 2001).

Environmental Fate

Chemical/Physical. Hydrolyzes in water forming acetic acid and 1-pentanol.
At an influent concentration of 985 mg/L, treatment with GAC resulted in an effluent concentration of 119 mg/L. The adsorbability of the carbon used was 175 mg/g carbon (Guisti et al., 1974).

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trained onits proper handling and storage. Before entering confinedspace where amyl acetates may be present, check to makesure that an explosive concentration does not exist. Store intightly closed containers in a cool, well-ventilated area, preferably a detached shed. Metal containers involving the transfer of this chemical should be grounded and bonded. Wherepossible, automatically pump liquid from drums or otherstorage containers to process containers. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers ofthis chemical. Sources of ignition, such as smoking andopen flames, are prohibited where this chemical is used,handled, or stored in a manner that could create a potentialfire or explosion hazard.

Shipping

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

Purification Methods

Shake the ester with saturated NaHCO3 solution until neutral, washed it with water, dry with MgSO4 and distil it. The ester has also been purfied by repeated fractional distillation through an efficient column or spinning band column. [Timmermann & Hennant-Roland J Chim Phys 52 223 1955, Mumford & Phillips J Chem Soc 75 1950, 1H NMR: Crawford & Foster Can J Phys 34 653 1956, Beilstein 2 IV 152.]

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrates. May soften certain plastics.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Amyl acetate Preparation Products And Raw materials

Raw materials

1-Pentanol Sodium carbonate

Preparation Products

Edible essence Octreotide acetate 6-bromo-3,4-dihydro-3-nitro-2H-chromene Bromophenol Blue FLUMICLORAC-PENTYL Triacetin Alacepril
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Amyl acetate Suppliers

Americas 1 Argentina 1 Australia 1 Belgium 2 Canada 4 China 183 Czech Republic 2 Europe 3 France 2 Germany 13 India 65 Italy 1 Japan 10 Malaysia 2 Mexico 2 Russia 1 Singapore 1 South Africa 1 Spain 3 Switzerland 3 Thailand 1 The Netherlands 1 Turkey 1 United Kingdom 10 United States 96 Global 410
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View Lastest Price from Amyl acetate manufacturers

Hebei Duling International Trade Co. LTD
Product
Amyl acetate 628-63-7
Price
US $56.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2023-05-08
Hebei Yanxi Chemical Co., Ltd.
Product
Amyl acetate 628-63-7
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-29
Hebei Guanlang Biotechnology Co., Ltd.
Product
Amyl acetate 628-63-7
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-19

628-63-7, Amyl acetateRelated Search:

PHENYL ACETATE POLY(VINYL ACETATE) Sodium acetate Triacetin Amyl salicylate 2-Methylbutyl acetate Isoamyl nitrite Isoamyl acetate Linalyl acetate Ethylene glycol monoethyl ether acetate Vinyl acetate 2-Butoxyethyl acetate (-)-DIHYDROCARVYL ACETATE Cellulose acetate Ethyl acetate Glatiramer acetate 1-Methoxy-2-propyl acetate DL-sec-Butyl acetate

  • N-AMYL ACETATE
  • N-PENTYL ACETATE
  • PENTYL ACETATE
  • PENTANYL ACETATE
  • PEAR OIL
  • n-Pentylacetate,99%
  • n-Amyl acetate, 99+%
  • 1-Acetoxypentane
  • 1-Pentanol acetate
  • 1-pentanol,acetate
  • 1-pentanolacetate
  • Acetate d'amyle
  • acetated’amyle
  • acetated’amyle(french)
  • acetated’amylenormal
  • Acetic acid, amyl ester
  • AMYL ACETATE 99+%
  • AmylAcetate,Certified
  • Pentylacetate,tech.
  • AMYLACETATE,NATURAL
  • AMYLACETATE,REAGENT
  • AMYLACETATE,TECHNICAL
  • AMYL ACETATE(SG)
  • Pentyl acetate (all isomers)
  • Amyl acetate, Pentyl acetate
  • prim-Pentyl acetate
  • Acetic acid, 1-pentyl ester
  • Acetic acid amyl
  • Acetic acid pentyl
  • n-Pentyl acetate, tech.
  • Acetic Acid Amyl Ester Pentyl Acetate
  • Amyl acetate, mixture of isomers, synthesis grade
  • Amyl acetate,Amyl acetate, Pentyl acetate
  • n-AMyl acetate, 99% 250ML
  • Essigsure-n-amylester
  • amyl acetate >=99.0%
  • AMYL ACETATE MIX ISOMERS
  • Acetic acid, n-pentyl ester
  • aceticacid,amylester
  • Aceticacidamylester
  • ai3-02729
  • Amyl acetic ether
  • Amylacetateester
  • amylacetates
  • amylaceticether
  • Amylazetat
  • Amylester kyseliny octove
  • amylesterkyselinyoctove
  • amylesterkyselinyoctove(czech)
  • Birnenoel
  • caswellno049a
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  • epapesticidechemicalcode000169
  • Ethanoicacidpentylester
  • holidaypetrepellent
  • holidayrepellentdust
  • n-amyl
  • n-Amylacetat