ChemicalBook > CAS DataBase List > Allylboronic acid pinacol ester

Allylboronic acid pinacol ester

Product Name
Allylboronic acid pinacol ester
CAS No.
72824-04-5
Chemical Name
Allylboronic acid pinacol ester
Synonyms
2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;ALLYLBORONIC ACID PINACOL ESTER;Allylboronic acid piracol ester
CBNumber
CB7169827
Molecular Formula
C9H17BO2
Formula Weight
168.04
MOL File
72824-04-5.mol
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Allylboronic acid pinacol ester Property

Boiling point:
50-53 °C/5 mmHg (lit.)
Density 
0.896 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.4268(lit.)
Flash point:
115 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol (Slightly)
form 
Liquid
color 
Clear colorless
Water Solubility 
Not miscible or difficult to mix in water.
BRN 
4244068
CAS DataBase Reference
72824-04-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
III
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
324647
Product name
Allylboronic acid pinacol ester
Purity
97%
Packaging
1g
Price
$50.1
Updated
2024/03/01
Sigma-Aldrich
Product number
324647
Product name
Allylboronic acid pinacol ester
Purity
97%
Packaging
10g
Price
$308
Updated
2024/03/01
TCI Chemical
Product number
A2157
Product name
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
Purity
>96.0%(GC)
Packaging
1g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
A2157
Product name
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
Purity
>96.0%(GC)
Packaging
5g
Price
$115
Updated
2024/03/01
Alfa Aesar
Product number
L16232
Product name
Allylboronic acid pinacol ester, 98+%
Packaging
1g
Price
$37.65
Updated
2024/03/01
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Allylboronic acid pinacol ester Chemical Properties,Usage,Production

Chemical Properties

Clear corless liquid

Uses

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

Uses

Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .

Allylboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

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Allylboronic acid pinacol ester Suppliers

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View Lastest Price from Allylboronic acid pinacol ester manufacturers

Henan Fengda Chemical Co., Ltd
Product
Allylboronic acid pinacol ester 72824-04-5
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
Allylboronic acid pinacol ester 72824-04-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Allylboronic acid pinacol ester 72824-04-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

72824-04-5, Allylboronic acid pinacol esterRelated Search:

Sodium allylsulfonate Allyl glycidyl ether Diethyl phthalate Dimethyl succinate Cyclopropylboronic acid 1,4-Dioxane Allyl bromide Allylbenzene Tris(trimethylsilyl)phosphate Allyl chloride Pinacol Dodecyl acrylate DIHYDRODICYCLOPENTADIENYL ACRYLATE 4-Acryloylmorpholine Isobornyl acrylate ALLYL PHENYL SULFIDE Allyltriphenylphosphonium bromide POTASSIUM ALLYLTRIFLUOROBORATE

  • 2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • Allylboronic acid pinacol ester 97%
  • 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
  • 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane
  • 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane
  • Allyl pinacol boronate
  • Pinacolyl 2-propenylboronate
  • 2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • Allylboronic acid pinacol ester, 98% 1GR
  • Allylboronic acid pinacol ester(stabilized with Phenothiazine)
  • 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAB
  • 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-
  • (2-Propen-1-yl)-boronic acid pinacol ester
  • Allyl pinacol boronate Pinacolyl 2-propenylboronate
  • 3-Hydroxy-2,3-dimethylbutan-2-yl hydrogen allylboronate
  • Allylboronic acid picol ester
  • 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane for synthesis
  • PINACOL ALLYLBORONATE
  • ALLYLBORONIC ACID, PINACOL CYCLIC ESTER
  • ALLYLBORONIC ACID PINACOL ESTER
  • AKOS BRN-1082
  • ALLBORONIC ACID,PINACOL CYCLIC ESTER
  • Allylboronic acid piracol ester
  • 4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane
  • Allylboronic acid pinacolate
  • 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
  • Allylboronic acid pinacol ester, 98+%
  • 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate
  • 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
  • 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)&gt
  • 72824-04-5
  • CH34C2O2BCH2CHCH2
  • Boronate Esters
  • Boronic Acids and Derivatives
  • Alkyl
  • Organometallic Reagents
  • Alkyl Boronate Esters
  • Boronate Esters
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • Olefin
  • Organoborons
  • B (Classes of Boron Compounds)
  • Boronic Acids Esters
  • CHIRAL CHEMICALS