Allylboronic acid pinacol ester

Product Name: Allylboronic acid pinacol ester
CAS No.: 72824-04-5
Chemical Name: Allylboronic acid pinacol ester
Synonyms: 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;ALLYLBORONIC ACID PINACOL ESTER;Allylboronic acid piracol ester
CBNumber: CB7169827
Molecular Formula: C9H17BO2
Formula Weight: 168.04
MOL File: 72824-04-5.mol

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Allylboronic acid pinacol ester Property

Boiling point:: 50-53 °C/5 mmHg (lit.)
Density: 0.896 g/mL at 25 °C (lit.)
refractive index: n20/D 1.4268(lit.)
Flash point:: 115 °F
storage temp.: 2-8°C
solubility: Chloroform, Methanol (Slightly)
form: Liquid
color: Clear colorless
Water Solubility: Not miscible or difficult to mix in water.
BRN: 4244068
CAS DataBase Reference: 72824-04-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 26-36
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 3
PackingGroup: III
HS Code: 29310095

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 324647
Product name: Allylboronic acid pinacol ester
Purity: 97%
Packaging: 1g
Price: $50.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 324647
Product name: Allylboronic acid pinacol ester
Purity: 97%
Packaging: 10g
Price: $308
Updated: 2024/03/01

TCI Chemical

Product number: A2157
Product name: 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
Purity: >96.0%(GC)
Packaging: 1g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: A2157
Product name: 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)
Purity: >96.0%(GC)
Packaging: 5g
Price: $115
Updated: 2024/03/01

Alfa Aesar

Product number: L16232
Product name: Allylboronic acid pinacol ester, 98+%
Packaging: 1g
Price: $37.65
Updated: 2024/03/01

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Allylboronic acid pinacol ester Chemical Properties,Usage,Production

Chemical Properties

Clear corless liquid

Uses

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

Uses

Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .

Allylboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

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Allylboronic acid pinacol ester Suppliers

Americas 1 China 178 Europe 2 France 2 Germany 6 India 5 Japan 1 Switzerland 1 United Kingdom 11 United States 25 Global 232

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

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View Lastest Price from Allylboronic acid pinacol ester manufacturers

Henan Fengda Chemical Co., Ltd

Product: Allylboronic acid pinacol ester 72824-04-5
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

Zhuozhou Wenxi import and Export Co., Ltd

Product: Allylboronic acid pinacol ester 72824-04-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: Allylboronic acid pinacol ester 72824-04-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

72824-04-5, Allylboronic acid pinacol esterRelated Search:

Sodium allylsulfonate Allyl glycidyl ether Diethyl phthalate Dimethyl succinate Cyclopropylboronic acid 1,4-Dioxane Allyl bromide Allylbenzene Tris(trimethylsilyl)phosphate Allyl chloride Pinacol Dodecyl acrylate DIHYDRODICYCLOPENTADIENYL ACRYLATE 4-Acryloylmorpholine Isobornyl acrylate ALLYL PHENYL SULFIDE Allyltriphenylphosphonium bromide POTASSIUM ALLYLTRIFLUOROBORATE

2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Allylboronic acid pinacol ester 97%

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)

4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane

Allyl pinacol boronate

Pinacolyl 2-propenylboronate

2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Allylboronic acid pinacol ester, 98% 1GR

Allylboronic acid pinacol ester(stabilized with Phenothiazine)

2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAB

1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-

(2-Propen-1-yl)-boronic acid pinacol ester

Allyl pinacol boronate Pinacolyl 2-propenylboronate

3-Hydroxy-2,3-dimethylbutan-2-yl hydrogen allylboronate

Allylboronic acid picol ester

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane for synthesis

PINACOL ALLYLBORONATE

ALLYLBORONIC ACID, PINACOL CYCLIC ESTER

ALLYLBORONIC ACID PINACOL ESTER

AKOS BRN-1082

ALLBORONIC ACID,PINACOL CYCLIC ESTER

Allylboronic acid piracol ester

4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane

Allylboronic acid pinacolate

2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE

Allylboronic acid pinacol ester, 98+%

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate

4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)&gt

72824-04-5

CH34C2O2BCH2CHCH2

Boronate Esters

Boronic Acids and Derivatives

Alkyl

Organometallic Reagents

Alkyl Boronate Esters

Boronate Esters

Boronic Acids and Derivatives

Chemical Synthesis

Organometallic Reagents

Olefin

Organoborons

B (Classes of Boron Compounds)

Boronic Acids Esters

CHIRAL CHEMICALS