METHYL 3-AMINOFURAN-2-CARBOXYLATE

Product Name: METHYL 3-AMINOFURAN-2-CARBOXYLATE
CAS No.: 956034-04-1
Chemical Name: METHYL 3-AMINOFURAN-2-CARBOXYLATE
Synonyms: Ethyl 3-aMinofuran-2-carboxylate;SW-34;SWF-34;Methyl 3-amino-2-furoate;Methyl 3-aminofuran-4-carboxylate;METHYL 3-AMINOFURAN-2-CARBOXYLATE;2-Furancarboxylic acid, 3-aMino-, Methyl ester
CBNumber: CB72453238
Molecular Formula: C6H7NO3
Formula Weight: 141.12
MOL File: 956034-04-1.mol

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METHYL 3-AMINOFURAN-2-CARBOXYLATE Property

Boiling point:: 244.4±20.0 °C(Predicted)
Density: 1?+-.0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
pka: 1.50±0.10(Predicted)
Appearance: Yellow to brown Solid
InChI: InChI=1S/C6H7NO3/c1-9-6(8)5-4(7)2-3-10-5/h2-3H,7H2,1H3
InChIKey: UTLPWTWCOSOPMX-UHFFFAOYSA-N
SMILES: O1C=CC(N)=C1C(OC)=O

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M328478
Product name: Methyl3-aminofuran-2-carboxylate
Packaging: 250mg
Price: $385
Updated: 2021/12/16

AK Scientific

Product number: W9755
Product name: Methyl3-aminofuran-2-carboxylate
Packaging: 1g
Price: $396
Updated: 2021/12/16

Matrix Scientific

Product number: 073301
Product name: Methyl 3-aminofuran-2-carboxylate
Purity: 95+%
Packaging: 1g
Price: $420
Updated: 2021/12/16

AK Scientific

Product number: W9755
Product name: Methyl3-aminofuran-2-carboxylate
Packaging: 250mg
Price: $180
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H58-1-VV
Product name: Methyl 3-aminofuran-2-carboxylate
Purity: 97.0%
Packaging: 1g
Price: $690
Updated: 2021/12/16

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METHYL 3-AMINOFURAN-2-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

956034-03-0

956034-04-1

General procedure for the synthesis of methyl 3-aminofuran-2-carboxylate from methyl 3-((tert-butoxycarbonyl)amino)furan-2-carboxylate: To a solution of methyl 3-((tert-butoxycarbonyl)amino)furan-2-carboxylate (13.5 g, 55.96 mmol) in dichloromethane (100 mL) was added trifluoroacetic acid (TFA, 50 mL). The reaction mixture was stirred at room temperature for 5 hours. Upon completion of the reaction, the crude product was concentrated to dryness under reduced pressure. The residue was dissolved in dichloromethane (200 mL) and washed with saturated aqueous sodium bicarbonate (NaHCO3) (3 x 100 mL). The organic layer was dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated to dryness under reduced pressure. The resulting residue was purified by fast column chromatography (silica gel, eluent methanol/chloroform, gradient 0 to 20%) to afford methyl 3-aminofuran-2-carboxylate (7.89 g, 100%) as a light yellow oil.1H NMR (300 MHz, CDCl3) δ 7.26 (d, J = 1.9 Hz, 1H), 6.13 (d, J = 2.0 Hz, 1H ), 4.51 (s, 2H), 3.88 (s, 3H). Mass spectrum (ES+): m/z 164.2 ([M + Na]+).

References

[1] Patent: WO2011/79230, 2011, A2. Location in patent: Page/Page column 56; 57
[2] Patent: US2015/336982, 2015, A1. Location in patent: Paragraph 0240; 0243
[3] Patent: US2008/76758, 2008, A1. Location in patent: Page/Page column 77
[4] Patent: WO2008/70740, 2008, A1. Location in patent: Page/Page column 137
[5] Patent: WO2008/73785, 2008, A2. Location in patent: Page/Page column 163-164

METHYL 3-AMINOFURAN-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-AMINOFURAN-2-CARBOXYLATE Suppliers

China 105 India 1 United States 14 Global 120

Shanghai Jian Chao Chemical Technology Co., Ltd.

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View Lastest Price from METHYL 3-AMINOFURAN-2-CARBOXYLATE manufacturers

Career Henan Chemical Co

Product: METHYL 3-AMINOFURAN-2-CARBOXYLATE 956034-04-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-06-24

956034-04-1, METHYL 3-AMINOFURAN-2-CARBOXYLATERelated Search:

tert-butyl 4-(4-broMothiazol-2-yl)piperazine-1-carboxylate (6-Methylpyridazin-3-yl)MethanaMine dihydrochloride No Chinese name rac-4-(6-chloro-2-oxo-2,3-dihydro-1H-indol-3-yl)-piperidine-1-carboxylic acid tert-butyl 5-METHYL-4,5,6,7-TETRAHYDRO[1,3]THIAZOLO[5,4-C]PYRIDIN-2-AMINE 1-METHYL-5-NITRO-1H-INDAZOLE 2,4-dichloro-7H-Pyrrolo[2,3-d]pyriMidine-7-carboxylic acid 1,1-diMethylethyl ester 5-BROMO-2-METHYL-3-NITROPHENYL METHYLCARBOXYLATE 1H-Pyrrolo[2,3-b]pyridine, 2-methyl-1-(phenylsulfonyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- Pyrrolidine-3-carboxaMide hydrochloride 5-Bromoindazole (2R,5S)-tert-butyl 4-benzyl-2,5-diMethylpiperazine-1-carboxylate 2-cyclopylcyclopropane-1-carboxylic acid 4-FLUORO-2-HYDROXYBENZALDEHYDE 4-CYANO-7-AZAINDOLE 5-Bromoindole (+/-)-BOC-ALPHA-PHOSPHONOGLYCINE TRIMETHYL ESTER 1-Boc-4-(Hydroxymethyl)-4-methyl-piperidine

METHYL 3-AMINOFURAN-2-CARBOXYLATE

2-Furancarboxylic acid, 3-aMino-, Methyl ester

Ethyl 3-aMinofuran-2-carboxylate

SWF-34

SW-34

Methyl 3-amino-2-furoate

Methyl 3-aminofuran-4-carboxylate

956034-04-1