TRIMETHYLSILYL ISOCYANATE

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TRIMETHYLSILYL ISOCYANATE

Product Name: TRIMETHYLSILYL ISOCYANATE
CAS No.: 1118-02-1
Chemical Name: TRIMETHYLSILYL ISOCYANATE
Synonyms: ISOCYANATOTRIMETHYLSILANE;trimethylsilanylisocyanate;DK481;TRIMETHYLSILYL ISOCYANATE;isocyanatotrimethyl-silan;Trimethylisocyanatosilane;Silane,isocyanatotriMethyl-;Trimethylsilyl isocyanate,95%;TRIMETHYLSILYLISOCYANATE ,75%;(TriMethylsilyl)isocyanate 85%
CBNumber: CB7367144
Molecular Formula: C4H9NOSi
Formula Weight: 115.21
MOL File: 1118-02-1.mol

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TRIMETHYLSILYL ISOCYANATE Property

Melting point:: -49°C
Boiling point:: 90-92 °C(lit.)
Density: 0.851 g/mL at 25 °C(lit.)
refractive index: n20/D 1.396(lit.)
Flash point:: -2 °C
storage temp.: 2-8°C
solubility: Miscible with ethers and o-dichlorobenzene.
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.867
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 1744962
CAS DataBase Reference: 1118-02-1(CAS DataBase Reference)
EPA Substance Registry System: Isocyanatotrimethylsilane (1118-02-1)

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Safety

Hazard Codes: F,T
Risk Statements: 11-23-36/37-42
Safety Statements: 23-26-36/37/39-45
RIDADR: UN 2478 3/PG 2
WGK Germany: 3
F: 10-19-21
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H331Toxic if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 252646
Product name: Trimethylsilyl Isocyanate
Purity: 85%
Packaging: 5g
Price: $99.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 252646
Product name: Trimethylsilyl Isocyanate
Purity: 85%
Packaging: 25g
Price: $154.8
Updated: 2024/03/01

TCI Chemical

Product number: T1106
Product name: Trimethylsilyl Isocyanate
Purity: >95.0%(GC)
Packaging: 5g
Price: $76
Updated: 2024/03/01

TCI Chemical

Product number: T1106
Product name: Trimethylsilyl Isocyanate
Purity: >95.0%(GC)
Packaging: 25g
Price: $198
Updated: 2024/03/01

Alfa Aesar

Product number: A12633
Product name: Trimethylsilyl isocyanate
Purity: 94%
Packaging: 10g
Price: $101
Updated: 2024/03/01

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TRIMETHYLSILYL ISOCYANATE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Uses

Trimethylsilyl isocyanate is used in the preparation of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones. It finds application in the carbamoylation of aromatic hydrocarbons and alcohols. It is also used in the preparation of primary amides from Grignard reagents. Further, it is used in the synthesis of cyclic imides. It is also utilized for the synthesis of trifluoroacetyl isocyanate and cyclic imides. In addition to this, it is employed in the conversion of isocyanates to carbodiimides using cyclopentadienyl Mn(CO)3 catalysis.

Purification Methods

Purify it by repeated fractionation as for the isothiocyanate. [Eaborn J Chem Soc 3077 1950, Beilstein 4 III 1861, 4 IV 4011.]

TRIMETHYLSILYL ISOCYANATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from TRIMETHYLSILYL ISOCYANATE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (Trimethylsilyl)isocyanate 85% 1118-02-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: TRIMETHYLSILYL ISOCYANATE 1118-02-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-14

1118-02-1, TRIMETHYLSILYL ISOCYANATERelated Search:

TriMethyl(broModifluoroMethyl)silane Trimethylboroxine Ethyl trifluoroacetate Ethyl 4,4,4-trifluoroacetoacetate Trimethoxy(pentamethylcyclopentadienyl) titanium(IV) Propyl isocyanate TRIMETHYLSILYL ISOTHIOCYANATE triethyl(3-isocyanatopropyl)silane TRIMETHYLSILYL ISOCYANATE

trimethylsilanylisocyanate

TRIMETHYLSILYL ISOCYANATE

ISOCYANATOTRIMETHYLSILANE

TRIMETHYLSILYL ISOCYANATE, STAB.

TRIMETHYLSILYLISOCYANATE ,75%

Trimethylsilyl isocyanate,95%

TriMethylsilyl isocyanate, 95% 5GR

Silane,isocyanatotriMethyl-

(TriMethylsilyl)isocyanate 85%

isocyanatotrimethyl-silan

Isocyanic acid, trimethylsilyl ester

Trimethylisocyanatosilane

(Trimethylsilyl)Iscyanate, 95%

DK481

1118-02-1

CH33SiNCO

C4H9NOSi

Building Blocks

Nitrogen Compounds

Isocyanates

Si-N Compounds

Trimethylsilylazide, etc.

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Organic Building Blocks

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Si-N Compounds

Synthetic Organic Chemistry

Trimethylsilylazide, etc.