Trimethylsilyl Isocyanate
- Product Name
- Trimethylsilyl Isocyanate
- CAS No.
- 1118-02-1
- Chemical Name
- Trimethylsilyl Isocyanate
- Synonyms
- ISOCYANATOTRIMETHYLSILANE;trimethylsilanylisocyanate;DK481;DKFELEX0110;TRIMETHYLSILYL ISOCYANATE;isocyanatotrimethyl-silan;Trimethylisocyanatosilane;Silane,isocyanatotriMethyl-;Trimethylsilyl isocyanate,95%;TRIMETHYLSILYLISOCYANATE ,75%
- CBNumber
- CB7367144
- Molecular Formula
- C4H9NOSi
- Formula Weight
- 115.21
- MOL File
- 1118-02-1.mol
Trimethylsilyl Isocyanate Property
- Melting point:
- -49°C
- Boiling point:
- 90-92 °C(lit.)
- Density
- 0.851 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.396(lit.)
- Flash point:
- -2 °C
- storage temp.
- 2-8°C
- solubility
- Miscible with ethers and o-dichlorobenzene.
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.867
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 1744962
- CAS DataBase Reference
- 1118-02-1(CAS DataBase Reference)
- EPA Substance Registry System
- Isocyanatotrimethylsilane (1118-02-1)
Safety
- Hazard Codes
- F,T
- Risk Statements
- 11-23-36/37-42
- Safety Statements
- 23-26-36/37/39-45
- RIDADR
- UN 2478 3/PG 2
- WGK Germany
- 3
- F
- 10-19-21
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H331Toxic if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 252646
- Product name
- Trimethylsilyl Isocyanate
- Purity
- 85%
- Packaging
- 5g
- Price
- $99.5
- Updated
- 2024/03/01
- Product number
- 252646
- Product name
- Trimethylsilyl Isocyanate
- Purity
- 85%
- Packaging
- 25g
- Price
- $154.8
- Updated
- 2024/03/01
- Product number
- T1106
- Product name
- Trimethylsilyl Isocyanate
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $76
- Updated
- 2024/03/01
- Product number
- T1106
- Product name
- Trimethylsilyl Isocyanate
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $198
- Updated
- 2024/03/01
- Product number
- A12633
- Product name
- Trimethylsilyl isocyanate
- Purity
- 94%
- Packaging
- 10g
- Price
- $101
- Updated
- 2024/03/01
Trimethylsilyl Isocyanate Chemical Properties,Usage,Production
Chemical Properties
Clear colorless liquid
Uses
Trimethylsilyl isocyanate is used in the preparation of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones. It finds application in the carbamoylation of aromatic hydrocarbons and alcohols. It is also used in the preparation of primary amides from Grignard reagents. Further, it is used in the synthesis of cyclic imides. It is also utilized for the synthesis of trifluoroacetyl isocyanate and cyclic imides. In addition to this, it is employed in the conversion of isocyanates to carbodiimides using cyclopentadienyl Mn(CO)3 catalysis.
Purification Methods
Purify it by repeated fractionation as for the isothiocyanate. [Eaborn J Chem Soc 3077 1950, Beilstein 4 III 1861, 4 IV 4011.]
Trimethylsilyl Isocyanate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Trimethylsilyl Isocyanate manufacturers
- Product
- Trimethylsilyl Isocyanate 1118-02-1
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10
- Release date
- 2024-07-14
- Product
- (Trimethylsilyl)isocyanate 85% 1118-02-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- TRIMETHYLSILYL ISOCYANATE 1118-02-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100kg
- Release date
- 2020-01-14