2-Fluoro-6-nitrophenol

Product Name: 2-Fluoro-6-nitrophenol
CAS No.: 1526-17-6
Chemical Name: 2-Fluoro-6-nitrophenol
Synonyms: 2-Fluoro-6-nitrophen;2-Fluor-6-nitro-phenol;6-FLUORO-2-NITROPHENOL;2-FLUORO-6-NITROPHENOL;2-NITRO-6-FLUORO PHENOL;fluoro-2 nitro-6 phenol;Phenol,2-fluoro-6-nitro-;Fluoro-6-nitrophenol, 2-;2-Fluoro-6-nitrophenol98%;2-Fluoro-6-nitrophenol>
CBNumber: CB7371453
Molecular Formula: C6H4FNO3
Formula Weight: 157.1
MOL File: 1526-17-6.mol

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2-Fluoro-6-nitrophenol Property

Melting point:: 92-94°C
Boiling point:: 201.5±20.0 °C(Predicted)
Density: 1.511±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 5.67±0.24(Predicted)
color: Light yellow to Yellow to Orange
BRN: 1870307
InChI: InChI=1S/C6H4FNO3/c7-4-2-1-3-5(6(4)9)8(10)11/h1-3,9H
InChIKey: HIGRXCJEFUYRNW-UHFFFAOYSA-N
SMILES: C1(O)=C([N+]([O-])=O)C=CC=C1F
CAS DataBase Reference: 1526-17-6(CAS DataBase Reference)
EPA Substance Registry System: 2-Fluoro-6-nitrophenol (1526-17-6)

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Safety

Hazard Codes: Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36/37/39-36/37
RIDADR: 2811
HazardClass: IRRITANT
PackingGroup: III
HS Code: 29089990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H301Toxic if swalloed

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: F0623
Product name: 2-Fluoro-6-nitrophenol
Purity: >98.0%(GC)
Packaging: 1g
Price: $32
Updated: 2025/07/31

TCI Chemical

Product number: F0623
Product name: 2-Fluoro-6-nitrophenol
Purity: >98.0%(GC)
Packaging: 5g
Price: $95
Updated: 2025/07/31

TRC

Product number: F594845
Product name: 2-Fluoro-6-nitrophenol
Packaging: 10g
Price: $230
Updated: 2021/12/16

TRC

Product number: F594845
Product name: 2-Fluoro-6-nitrophenol
Packaging: 25g
Price: $470
Updated: 2021/12/16

AK Scientific

Product number: H640
Product name: 2-Fluoro-6-nitrophenol
Packaging: 5g
Price: $11
Updated: 2021/12/16

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2-Fluoro-6-nitrophenol Chemical Properties,Usage,Production

Uses

2-Fluoro-6-nitrophenol has antifungal- and high plant-growth-regulating activity.

Synthesis

367-12-4

7440-44-0

1526-17-6

403-19-0

A. Synthesis of 2-fluoro-4-nitrophenol To a stirred dichloromethane solution of 2-fluorophenol (32.3 g, 0.288 mol) was slowly added 90% nitric acid (1 g, 0.31 mol HNO3) in an ice-salt bath cooled to -10°C. The addition process was controlled to be completed in 1 hour. During the reaction, the temperature was maintained at about -5 °C. After the addition was completed, stirring was continued at 0°C for 1 hour. At the end of the reaction, the precipitate was collected by filtration and washed several times with cold dichloromethane. Analysis by GC and thin layer chromatography (silica gel, 7:3 hexane-acetone) showed that the product was mainly a single compound and that the by-products produced in the reaction were of low polarity and volatility. The solid was dissolved in ether, washed with water, dried (MgSO4) and the solvent evaporated. The resulting solid was recrystallized with methylcyclohexane to give 13 g of a pale yellow solid with a melting point of 119°-121°C. NMR (CDCl3) analysis confirmed the product as 2-fluoro-4-nitrophenol. The dichloromethane mother liquor was treated, washed with water, dried (MgSO4) and the solvent evaporated. The solid obtained was ground with boiling hexane (3 x 150 ml) to effectively remove the least polar and highly volatile reaction by-products. The hexane solution was treated with activated charcoal, filtered and concentrated to about 300 ml and cooled to give 13.5 g (30% yield) of the by-product 2-fluoro-6-nitrophenol as a yellow solid with a melting point of 70°-86 °C.

References

[1] Patent: US4750931, 1988, A
[2] Patent: EP142328, 1991, B1

2-Fluoro-6-nitrophenol Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Fluoro-6-nitrophenol Suppliers

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View Lastest Price from 2-Fluoro-6-nitrophenol manufacturers

Henan Fengda Chemical Co., Ltd

Product: 2-Fluoro-6-nitrophenol 1526-17-6
Price: US $8.00-0.80/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-22

Hebei Senko Biotechnology Co., Ltd.

Product: 2-Fluoro-6-nitrophenol 1526-17-6
Price: US $10.00/Kg/Bag
Min. Order: 1KG
Purity: 99%
Supply Ability: 10Tons
Release date: 2021-07-20

Career Henan Chemical Co

Product: 2-Fluoro-6-nitrophenol 1526-17-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 1ton
Release date: 2020-01-08

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