1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE

Product Name: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE
CAS No.: 15442-91-8
Chemical Name: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE
Synonyms: TETRABROMODURENE;1,2,4,5-Tetrakis(bromomethyL;5-TETRAKIS(BROMOMETHYL)BENZENE;1,2,4,5-TETRA[BROMOMETHYL]BENZENE;1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE;Benzene,1,2,4,5-tetrakis(broMoMethyl)-;1,2,4,5-Tetrakis(bromomethyl)benzene 95%;1,2,4,5-Tetrakis(bromomethyl)benzene,98%;1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE, 95 %;1,2,4,5-Tetrakis(broMoMethyl)benzene, 95% 25GR
CBNumber: CB7452862
Molecular Formula: C10H10Br4
Formula Weight: 449.8
MOL File: 15442-91-8.mol

More

Less

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Property

Melting point:: 159-161 °C(lit.)
Boiling point:: 326.93°C (rough estimate)
Density: 2.168
refractive index: 1.7040 (estimate)
storage temp.: Refrigerator, under inert atmosphere
solubility: Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form: Crystalline Powder
color: Off-white to light yellow
CAS DataBase Reference: 15442-91-8(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: C
Risk Statements: 34-36/37
Safety Statements: 26-27-28-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: III
HS Code: 29039990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 236616
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: 95%
Packaging: 5g
Price: $204.16
Updated: 2025/07/31

TCI Chemical

Product number: T3901
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: min. 95.0 %
Packaging: 1G
Price: $60
Updated: 2025/07/31

TCI Chemical

Product number: T3901
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: min. 95.0 %
Packaging: 5G
Price: $183
Updated: 2025/07/31

TRC

Product number: T298568
Product name: 1,2,4,5-Tetrakis(Bromomethyl)Benzene
Packaging: 500mg
Price: $125
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK560213
Product name: 1,2,4,5-Tetrakis(bromomethyl)benzene
Purity: 95%
Packaging: 5g
Price: $159
Updated: 2021/12/16

More

Less

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Chemical Properties,Usage,Production

Chemical Properties

off-white to light yellow crystalline powder

Uses

1,2,4,5-Tetrakis(bromomethyl)benzene has been used in the synthesis of:

tetrapodal imidazolium ligands as their PF₆^? salts
6,7-bis(bromomethyl)-2,11,18,21,24-pentaoxatetracyclo[23.4. 0.0^4,9.0¹²,¹⁷]nonacosa-1(25),4(9),5,7,12 (17),13,15,26,28-nonaene
conformationally constrained cyclic α-amino acid derivatives
thiacyclophanes
dendrimeric organoplatinum complexes

Synthesis

95-93-2

15442-91-8

General procedure for the synthesis of tetrabromotoluene from 1,2,4,5-tetramethylbenzene: 1,2,4,5-tetrakis(bromomethyl)benzene (2.8 g, 20 mmol) was prepared by reacting 1,2,4,5-tetramethylbenzene (2.8 g, 20 mmol) with N-bromosuccinimide (NBS, 14.4 g, 80 mmol) and benzoyl peroxide in 50 mL of tetrachloromethane (1c, 1 g, 5.9 mmol). The reaction mixture was heated at 77 °C for 50 min. After completion of the reaction, the precipitate was collected by filtration under reduced pressure and washed with hot tetrachloromethane. The filtrate was concentrated to a small volume and cooled to 4 °C. The crude product was filtered and purified by recrystallization from methanol. The reaction time was less than 1 hour to give a white solid product in 15% yield with a melting point of 159-160°C. The structure of the product was determined by 1H-NMR (CDCl3, δ: 7.37 ppm, 2H, a; 4.60 ppm, 8H, b), 13C-NMR (CDCl3, δ: 137.6 ppm, a; 133.6 ppm, h; 28.7 ppm, b), and FT-IR (KBr, νmax: 3026, 2980, 2933. 1504, 1456, 1210, 911, 797, 678, 598 cm-1) were characterized.

References

[1] Journal of the Chinese Chemical Society, 2002, vol. 49, # 1, p. 77 - 82
[2] Angewandte Chemie - International Edition, 2006, vol. 45, # 26, p. 4281 - 4286
[3] Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1994, vol. 247, p. 23 - 30
[4] Heterocycles, 2015, vol. 90, # 1, p. 645 - 658
[5] Tetrahedron Letters, 2015, vol. 56, # 26, p. 3992 - 3995

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE Suppliers

Belgium 1 China 95 Czech 1 France 1 Germany 3 India 3 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 2 United States 15 Global 124

AbaChemScene

Tel: 732-484-9848
Fax: 888-484-5008
Email: sales@chemscene.com
Country: United States
ProdList: 3982
Advantage: 60

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

Alfa Chemistry

Tel: --
Fax: --
Email: info@Alfa-Chemistry.com
Country: United States
ProdList: 6814
Advantage: 0

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Anvia Chemicals, LLC

Tel: --
Fax: --
Email: sales@anviachem.com
Country: United States
ProdList: 3933
Advantage: 0

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

Syntech Labs

Tel: --
Fax: --
Email: info@syntechlabs.com
Country: United States
ProdList: 730
Advantage: 43

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

Spectrum Chemicals & Laboratory Products

Tel: --
Fax: --
Email: sales@spectrumchemical.com
Country: United States
ProdList: 6699
Advantage: 77

Acros Organics USA

Tel: --
Fax: --
Email: eveleth@fisherchem.com
Country: United States
ProdList: 3846
Advantage: 81

Fisher Scientific

Tel: --
Fax: --
Email: sales@fishersci.com
Country: United States
ProdList: 2337
Advantage: 86

More

Less

View Lastest Price from 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE 15442-91-8
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

15442-91-8, 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENERelated Search:

Biphenyl-3,3',5,5'-tetracarboxylic acid 1,2,3,4-Tetrahydronaphthalene 1,2,4-Trimethylbenzene 1,3-Bis(bromomethyl)benzene 1,3,5-Tris(bromomethyl)benzene 1,2-Bis(bromomethyl)benzene 3,7-dibromo-10H-phenothiazine alpha,alpha'-Dibromo-p-xylene 1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE 2,4-DIMETHYLBENZYL BROMIDE 1,4-BIS(BROMOMETHYL)-2,5-DIMETHYLBENZENE 2,5-DIMETHYLBENZYL BROMIDE 4-Fluorobenzyl bromide HEXAKIS(BROMOMETHYL)BENZENE 3-Methylbenzyl bromide 4-Methylbenzyl bromide 3,4-Dimethylbenzylbromide Benzyl bromide

ALPHA,ALPHA',ALPHA'',ALPHA'''-TETRABROMODURENE

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE

1,2,4,5-TETRA[BROMOMETHYL]BENZENE

TETRABROMODURENE

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE, 95 %

1,2,4,5-Tetrakis(bromomethyl)benzene,98%

1,2,4,5-Tetrakis(broMoMethyl)benzene, 95% 25GR

Benzene,1,2,4,5-tetrakis(broMoMethyl)-

1,2,4,5-Tetrakis(bromomethyl)benzene 95%

1,2,4,5-Tetrakis(bromomethyL

1,2,4,5-Tetrakis(bromomethyl)benzene, 95%, for synthesis

1,2,4,5-TETRAKIS(BROMOMETHYL)BENZENE ISO 9001：2015 REACH

5-TETRAKIS(BROMOMETHYL)BENZENE

15442-91-8

C10H10Br4

C6H2CH2Br4

Organic Building Blocks

Halogenated Hydrocarbons

Aryl

C9 to C12

Building Blocks

Morpholines/Thiomorpholines ,Indazoles