Reaction
ChemicalBook > CAS DataBase List > Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Reaction
Product Name
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS No.
12354-85-7
Chemical Name
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms
Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
CBNumber
CB7482876
Molecular Formula
C20H30Cl4Rh210*
Formula Weight
618.08
MOL File
12354-85-7.mol
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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Property

Melting point:
>300°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
red
Water Solubility 
Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:
Hygroscopic
NIST Chemistry Reference
Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements 
26-36-S36-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
338370
Product name
Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity
97%
Packaging
250mg
Price
$344
Updated
2024/03/01
Sigma-Aldrich
Product number
338370
Product name
Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity
97%
Packaging
1g
Price
$855
Updated
2024/03/01
TCI Chemical
Product number
P1788
Product name
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity
>96.0%(T)
Packaging
1g
Price
$476
Updated
2024/03/01
TCI Chemical
Product number
P1788
Product name
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity
>96.0%(T)
Packaging
200mg
Price
$162
Updated
2024/03/01
Alfa Aesar
Product number
033657
Product name
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
Packaging
250mg
Price
$203
Updated
2023/06/20
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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Usage,Production

Reaction

  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Suppliers

Americas 1 Australia 1 Belgium 3 Brazil 1 Canada 1 CHINA 170 Czech Republic 1 France 1 Germany 7 India 12 Japan 2 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 36 Global 247
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23662
Advantage
75
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View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

12354-85-7, Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Related Search:

DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane (Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile

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  • Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%
  • Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0]
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  • 12354-85-7
  • C10H15Cl4Rh2
  • C20H48Cl4Rh2
  • CH35C5RhCl22
  • RhC5Me5Cl22
  • C20H30Cl4Rh2
  • C20H30Cl4Rh210
  • 2C10H152Cl2Rh
  • Catalysis and Inorganic Chemistry
  • metallocene
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry