Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Reaction

Product Name: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS No.: 12354-85-7
Chemical Name: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms: Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
CBNumber: CB7482876
Molecular Formula: C20H30Cl4Rh210*
Formula Weight: 618.08
MOL File: 12354-85-7.mol

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Property

Melting point:: >300°C
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: crystal
color: red
Water Solubility: Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:: Hygroscopic
NIST Chemistry Reference: Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements: 26-36-S36-S26-24/25
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 338370
Product name: Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity: 97%
Packaging: 250mg
Price: $344
Updated: 2024/03/01

Sigma-Aldrich

Product number: 338370
Product name: Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity: 97%
Packaging: 1g
Price: $855
Updated: 2024/03/01

TCI Chemical

Product number: P1788
Product name: (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity: >96.0%(T)
Packaging: 1g
Price: $476
Updated: 2024/03/01

TCI Chemical

Product number: P1788
Product name: (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity: >96.0%(T)
Packaging: 200mg
Price: $162
Updated: 2024/03/01

Alfa Aesar

Product number: 033657
Product name: Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
Packaging: 250mg
Price: $203
Updated: 2023/06/20

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Usage,Production

Reaction

Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
Catalyst used in the asymmetric transfer hydrogenation of imines in water.
Facile rhodium-catalyzed synthesis of fluorinated pyridines.
Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

reaction suitability

core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Suppliers

Americas 1 Australia 1 Belgium 3 Brazil 1 Canada 1 CHINA 181 Czech Republic 1 France 1 Germany 7 India 12 Japan 2 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 35 Global 257

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Energy Chemical

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View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2024-08-05

Longyan Tianhua Biological Technology Co., Ltd

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

12354-85-7, Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Related Search:

DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane (Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium

Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-

DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE

DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER

BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]

PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&

PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER

PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER

Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer

Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99%

di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer,98%

Pentamethylcyclopentadienylrhodium(III) chloride dimer, 33% Rh, Product of Umicore

DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer

Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate

DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE

Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%

Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0]

Bis[(pentamethylcycl

PentaMethyl cyclopentadienyl RhodiuM dichloride diMer

Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2

Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer

Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2

PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97%

1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex

Bis(dichloro(pentamethylcyclopentadienyl)rhodium)

Bis(pentamethylcyclopentadienylrhodium dichloride)

tube1183

(Pentamethylcyclopentadienyl)rhodium(III)DichlorideDimer&gt

)rhodium(III) DichL

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] ISO 9001：2015 REACH

Rh(Cp*)Cl2]2

TIANFU-CHEM--Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Di( μ -chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III)

Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium

RHODIUM (III) CHLORIDE DIMER

Chiralyst P618

Pentamethylcyclopentadineylrhodium(III) chloride dimer

12354-85-7

C10H15Cl4Rh2

C20H48Cl4Rh2

CH35C5RhCl22

RhC5Me5Cl22

C20H30Cl4Rh2

C20H30Cl4Rh210

2C10H152Cl2Rh

Catalysis and Inorganic Chemistry

metallocene

Catalysis and Inorganic Chemistry

Chemical Synthesis

Rhodium

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Metal Complexes

Rh (Rhodium) Compounds