ChemicalBook > CAS DataBase List > Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Reaction

Product Name: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS No.: 12354-85-7
Chemical Name: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms: Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
CBNumber: CB7482876
Molecular Formula: C20H30Cl4Rh210*
Formula Weight: 618.08
MOL File: 12354-85-7.mol

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Property

Melting point:: >300°C
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: crystal
color: red
Water Solubility: Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:: Hygroscopic
InChI: InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChIKey: QNIVKTTWBMFSBR-UHFFFAOYSA-J
SMILES: [C]1(C)[C](C)[C](C)[C](C)[C]1C.[C]1(C)[C](C)[C](C)[C](C)[C]1C.[Rh](Cl)Cl.[Rh](Cl)Cl |^1:0,2,4,6,8,10,12,14,16,18|
NIST Chemistry Reference: Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements: 26-36-S36-S26-24/25
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 338370
Product name: Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity: 97%
Packaging: 250mg
Price: $355
Updated: 2025/07/31

Sigma-Aldrich

Product number: 338370
Product name: Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity: 97%
Packaging: 1g
Price: $881
Updated: 2025/07/31

TCI Chemical

Product number: P1788
Product name: (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity: >96.0%(T)
Packaging: 1g
Price: $476
Updated: 2025/07/31

TCI Chemical

Product number: P1788
Product name: (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity: >96.0%(T)
Packaging: 200mg
Price: $162
Updated: 2025/07/31

Strem Chemicals

Product number: 45-0195
Product name: Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
Packaging: 100mg
Price: $86
Updated: 2024/03/01

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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Usage,Production

Reaction

Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
Catalyst used in the asymmetric transfer hydrogenation of imines in water.
Facile rhodium-catalyzed synthesis of fluorinated pyridines.
Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

reaction suitability

core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

Shaanxi Dideu Medichem Co. Ltd

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2024-08-05

Longyan Tianhua Biological Technology Co., Ltd

Product: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

12354-85-7, Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Related Search:

DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane (Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium

Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-

DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE

DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER

BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]

PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&

PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER

PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER

Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer

Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99%

di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer,98%

Pentamethylcyclopentadienylrhodium(III) chloride dimer, 33% Rh, Product of Umicore

DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer

Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate

DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE

Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%

Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0]

Bis[(pentamethylcycl

PentaMethyl cyclopentadienyl RhodiuM dichloride diMer

Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2

Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer

Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2

PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97%

1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex

Bis(dichloro(pentamethylcyclopentadienyl)rhodium)

Bis(pentamethylcyclopentadienylrhodium dichloride)

tube1183

(Pentamethylcyclopentadienyl)rhodium(III)DichlorideDimer&gt

)rhodium(III) DichL

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] ISO 9001：2015 REACH

Rh(Cp*)Cl2]2

TIANFU-CHEM--Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Di( μ -chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III)

Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium

RHODIUM (III) CHLORIDE DIMER

Chiralyst P618

Pentamethylcyclopentadineylrhodium(III) chloride dimer

Bis(chloro)(pentamethylcyclopentadienyl)rhodium(III)Dimer

Bis[(pentamethylevelopentadienvlldichloro-rhodium]

12354-85-7

C10H15Cl4Rh2

C20H48Cl4Rh2

CH35C5RhCl22

RhC5Me5Cl22

C20H30Cl4Rh2

C20H30Cl4Rh210

2C10H152Cl2Rh

C20H30Cl4Rh261807

Catalysis and Inorganic Chemistry

metallocene

Catalysis and Inorganic Chemistry

Chemical Synthesis

Rhodium

Catalysts for Organic Synthesis

Classes of Metal Compounds