Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Reaction- Product Name
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
- CAS No.
- 12354-85-7
- Chemical Name
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
- Synonyms
- Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
- CBNumber
- CB7482876
- Molecular Formula
- C20H30Cl4Rh210*
- Formula Weight
- 618.08
- MOL File
- 12354-85-7.mol
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Property
- Melting point:
- >300°C
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- form
- crystal
- color
- red
- Water Solubility
- Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
- Stability:
- Hygroscopic
- NIST Chemistry Reference
- Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38-R36/37/38-R20/21/22
- Safety Statements
- 26-36-S36-S26-24/25
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 338370
- Product name
- Pentamethylcyclopentadienylrhodium(III) chloride dimer
- Purity
- 97%
- Packaging
- 250mg
- Price
- $344
- Updated
- 2024/03/01
- Product number
- 338370
- Product name
- Pentamethylcyclopentadienylrhodium(III) chloride dimer
- Purity
- 97%
- Packaging
- 1g
- Price
- $855
- Updated
- 2024/03/01
- Product number
- P1788
- Product name
- (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
- Purity
- >96.0%(T)
- Packaging
- 1g
- Price
- $476
- Updated
- 2024/03/01
- Product number
- P1788
- Product name
- (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
- Purity
- >96.0%(T)
- Packaging
- 200mg
- Price
- $162
- Updated
- 2024/03/01
- Product number
- 033657
- Product name
- Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
- Packaging
- 250mg
- Price
- $203
- Updated
- 2023/06/20
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Usage,Production
Reaction
- Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
- Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
- Catalyst used in the asymmetric transfer hydrogenation of imines in water.
- Facile rhodium-catalyzed synthesis of fluorinated pyridines.
- Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Chemical Properties
burgundy solid
Uses
Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
Uses
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers
- Product
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11
- Product
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03