Reaction
ChemicalBook > CAS DataBase List > Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Reaction
Product Name
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS No.
12354-85-7
Chemical Name
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms
Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
CBNumber
CB7482876
Molecular Formula
C20H30Cl4Rh210*
Formula Weight
618.08
MOL File
12354-85-7.mol
More
Less

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Property

Melting point:
>300°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
red
Water Solubility 
Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:
Hygroscopic
NIST Chemistry Reference
Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements 
26-36-S36-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
338370
Product name
Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity
97%
Packaging
250mg
Price
$344
Updated
2024/03/01
Sigma-Aldrich
Product number
338370
Product name
Pentamethylcyclopentadienylrhodium(III) chloride dimer
Purity
97%
Packaging
1g
Price
$855
Updated
2024/03/01
TCI Chemical
Product number
P1788
Product name
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity
>96.0%(T)
Packaging
1g
Price
$476
Updated
2024/03/01
TCI Chemical
Product number
P1788
Product name
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Purity
>96.0%(T)
Packaging
200mg
Price
$162
Updated
2024/03/01
Alfa Aesar
Product number
033657
Product name
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
Packaging
250mg
Price
$203
Updated
2023/06/20
More
Less

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Usage,Production

Reaction

  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.

Chemical Properties

burgundy solid

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Suppliers

Americas 1 Australia 1 Belgium 3 Brazil 1 Canada 1 CHINA 181 Czech Republic 1 France 1 Germany 7 India 12 Japan 2 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 35 Global 257
Sinocompound Catalysts Co., Ltd.
Tel
0512-67216630 67216634
Fax
0512-56316689
Email
sales@sinocompound.com
Country
China
ProdList
278
Advantage
64
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2409
Advantage
58
Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
Advantage
62
Panjin Greenchem Technology Co., Ltd.
Tel
13121959385 13121959385
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
216
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9512
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9810
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19179
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky（shanghai）International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
291
Advantage
62
Wuhan Fortuna Chemical Co., Ltd
Tel
027-59207852 13308628970
Fax
QQ3130921841
Email
buy@fortunachem.com
Country
China
ProdList
2865
Advantage
58
T&W GROUP
Tel
021-61551611 13296011611
Fax
＋86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9458
Advantage
58
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
18017383231 18017383231
Fax
qq：2817624287
Email
lyh_antaeus@163.com
Country
China
ProdList
9347
Advantage
55
Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Beijing Guofang Dingsheng Technology Co., Ltd.
Tel
18610472091 18610472091
Fax
010-59092859
Email
gfdskj@163.com
Country
China
ProdList
494
Advantage
58
Finetech Industry Limited
Tel
027-87465837 19945049750
Fax
027-8777-2287
Email
sales@finetechnology-ind.com
Country
China
ProdList
9648
Advantage
58
Shanghai Boka-chem Tech. Inc.
Tel
400-026-1533/(021) 6478-0600
Fax
+86 (21) 6459-2060
Email
sales@bokachem.com
Country
China
ProdList
876
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-+86-571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
11578
Advantage
59
Nanjing Duolong Bio-tech Co.,Ltd.
Tel
18905173768
Fax
025-83263139
Email
sales@dolonchem.com
Country
China
ProdList
2331
Advantage
50
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com
Country
China
ProdList
16684
Advantage
50
Cool Pharm, Ltd
Tel
021-58581007 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9958
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai PharmaPartner Co., Ltd.
Tel
19983777532
Fax
-
Email
pharmabridge@163.com
Country
China
ProdList
623
Advantage
55
Twochem Co.Ltd
Tel
021-021-58111628 15800915896
Fax
QQ 3285589261
Email
sales@twochem.com
Country
China
ProdList
304
Advantage
55
ShangHai Vita Chemicals Reagent Co., Ltd.
Tel
021-57120026 13761879068 15221782916
Fax
021-57120026 QQ:3080806090 1852290626
Email
1852290626@qq.com 3080806090@qq.com
Country
China
ProdList
106
Advantage
55
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
17687
Advantage
55
ShangHai Siyan Biological Technology Co., Ltd.
Tel
021-50908862，442785678，326799392 18721037013
Fax
021-50908862
Email
siyansales@126.com
Country
China
ProdList
9627
Advantage
58
ATK CHEMICAL COMPANY LIMITED
Tel
021-51619050 13301662590
Fax
+86-21-51619052
Email
mandy@atkchemical.com
Country
China
ProdList
10199
Advantage
55
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
27313
Advantage
60
parabiochem
Tel
025-83453382-8005
Fax
025-83453382
Email
sale@parabiochem.com
Country
China
ProdList
9595
Advantage
55
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
Tianjin Kailiqi Biotechnology Co., Ltd.
Tel
15076683720
Fax
022-23754520
Email
klq@cw-bio.com
Country
China
ProdList
5930
Advantage
55
Chengdu Dianchun Technology Co., Ltd
Tel
400-1166-196 18502815961
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
14603
Advantage
60
Grader reagent
Tel
18221735425
Email
sales@xinpingchem.com
Country
China
ProdList
9942
Advantage
58
Shanghai SuperLan Chemcial Technique Centre
Tel
021-2022843681 15618226720
Fax
+86-21-51601218
Email
lucy@atkchemical.com
Country
China
ProdList
9952
Advantage
58
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-0371-55629727 13323845623
Fax
037155629727
Email
2885676761@qq.com
Country
China
ProdList
9993
Advantage
58
More
Less

View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2024-08-05
Longyan Tianhua Biological Technology Co., Ltd
Product
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 12354-85-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

12354-85-7, Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]Related Search:

DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane (Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile

  • Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
  • Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
  • DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
  • DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
  • BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
  • PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
  • Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer
  • Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
  • Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99%
  • di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
  • (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer,98%
  • Pentamethylcyclopentadienylrhodium(III) chloride dimer, 33% Rh, Product of Umicore
  • DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC
  • (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
  • Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
  • DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
  • Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%
  • Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0]
  • Bis[(pentamethylcycl
  • PentaMethyl cyclopentadienyl RhodiuM dichloride diMer
  • Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2
  • Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer
  • Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2
  • PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97%
  • 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
  • Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
  • Bis(pentamethylcyclopentadienylrhodium dichloride)
  • tube1183
  • (Pentamethylcyclopentadienyl)rhodium(III)DichlorideDimer&gt
  • )rhodium(III) DichL
  • Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] ISO 9001：2015 REACH
  • Rh(Cp*)Cl2]2
  • TIANFU-CHEM--Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
  • Di( μ -chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III)
  • Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium
  • RHODIUM (III) CHLORIDE DIMER
  • Chiralyst P618
  • Pentamethylcyclopentadineylrhodium(III) chloride dimer
  • 12354-85-7
  • C10H15Cl4Rh2
  • C20H48Cl4Rh2
  • CH35C5RhCl22
  • RhC5Me5Cl22
  • C20H30Cl4Rh2
  • C20H30Cl4Rh210
  • 2C10H152Cl2Rh
  • Catalysis and Inorganic Chemistry
  • metallocene
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds