Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)

Product Name: Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
CAS No.: 1621274-17-6
Chemical Name: Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
Synonyms: Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-met...;Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2’-methylamino-1,1’-biphenyl-2-yl)palladium(II);Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);DPPF PD G4 Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);(SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium;(SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium (ACI);(SP-4-3)-[1-(Diphenylphosphino-kappap)-1'-(diphenylphosphino)-ferrocene](methanesulfonato-kappao)[2'-(methylamino-kappan)-biphenyl-2-yl-kappac]palladium
CBNumber: CB76187915
Molecular Formula: C48H35FeNO3P2PdS
Formula Weight: 930.08
MOL File: 1621274-17-6.mol

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Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Property

Melting point:: 201 °C
storage temp.: -20°C
form: powder
Appearance: Orange to reddish brown Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H320Causes eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 900454
Product name: DPPF Pd G4
Purity: 95%
Packaging: 250mg
Price: $141
Updated: 2025/07/31

Sigma-Aldrich

Product number: 900454
Product name: DPPF Pd G4
Purity: 95%
Packaging: 1g
Price: $502
Updated: 2025/07/31

Arctom

Product number: AS708397
Product name: (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium
Purity: ≥98%
Packaging: 5g
Price: $594
Updated: 2021/12/16

BLDpharm

Product number: BD01090381
Product name: (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium
Purity: 98+%
Packaging: 5g
Price: $600
Updated: 2021/12/16

Ambeed

Product number: A1155293
Product name: (SP-4-3)-[1-(Diphenylphosphino-κP)-1′-(diphenylphosphino)ferrocene](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium
Purity: 98+%
Packaging: 5g
Price: $600
Updated: 2021/12/16

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Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Chemical Properties,Usage,Production

Uses

DPPF Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Methanesulfonato(1,1-Bis(diphenylphosphino)ferrocene)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Suppliers

China 31 United States 1 Global 32

Adamas Reagent, Ltd.

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1621274-17-6