AdBrettPhos Pd G3
Reaction- Product Name
- AdBrettPhos Pd G3
- CAS No.
- 1445972-29-1
- Chemical Name
- AdBrettPhos Pd G3
- Synonyms
- AdBrettPhos Pd G3;AdBrettPhos Palladacycle Gen. 3;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...;bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane;bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylpChemicalbookhosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3;METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
- CBNumber
- CB23357121
- Molecular Formula
- C56H74NO5PPdS
- Formula Weight
- 1010.66
- MOL File
- 1445972-29-1.mol
AdBrettPhos Pd G3 Property
- Melting point:
- 251-253 °C
- form
- solid
- color
- brown to green
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 776106
- Product name
- AdBrettPhos Pd G3
- Packaging
- 100MG
- Price
- $101
- Updated
- 2023/06/20
- Product number
- 776106
- Product name
- AdBrettPhos Pd G3
- Packaging
- 500MG
- Price
- $362
- Updated
- 2023/06/20
- Product number
- 776106
- Product name
- AdBrettPhos Pd G3
- Packaging
- 2G
- Price
- $1350
- Updated
- 2023/06/20
- Product number
- 776106
- Product name
- AdBrettPhos Pd G3
- Packaging
- 5G
- Price
- $3280
- Updated
- 2023/06/20
- Product number
- 46-0480
- Product name
- Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
- Packaging
- 50mg
- Price
- $42
- Updated
- 2024/03/01
AdBrettPhos Pd G3 Chemical Properties,Usage,Production
Reaction
Palladium catalyst used in the highly selective monoarylation of ammonia.
Uses
Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.
Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
AdBrettPhos Pd G3 Preparation Products And Raw materials
Raw materials
Preparation Products
AdBrettPhos Pd G3 Suppliers
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