ChemicalBook > CAS DataBase List > Methyl 2-amino-5-bromonicotinate

Methyl 2-amino-5-bromonicotinate

Product Name
Methyl 2-amino-5-bromonicotinate
CAS No.
50735-34-7
Chemical Name
Methyl 2-amino-5-bromonicotinate
Synonyms
2-AMINO-5-BROMONICOTINATE;METHYL 2-AMINO-5-BROMONICOTINAT;METHYL 2-AMINO-5-BROMONICOTINATE;2-AMino-5-broMo-nicotinic acid ethyl ester;2-AMINO-5-BROMO-NICOTINIC ACID METHYL ESTER;METHYL 2-AMINO-5-BROMOPYRIDINE-3-CARBOXYLATE;Methyl 2-amino-5-bromonicotinate ISO 9001：2015 REACH;3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl e;TIANFU-CHEM Methyl 2-amino-5-bromonicotinate 50735-34-7;3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl ester
CBNumber
CB7700860
Molecular Formula
C7H7BrN2O2
Formula Weight
231.05
MOL File
50735-34-7.mol
More
Less

Methyl 2-amino-5-bromonicotinate Property

Melting point:
143-146°C
Boiling point:
275.2±35.0 °C(Predicted)
Density 
1.662±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
2.45±0.49(Predicted)
Appearance
White to yellow Solid
InChI
InChI=1S/C7H7BrN2O2/c1-12-7(11)5-2-4(8)3-10-6(5)9/h2-3H,1H3,(H2,9,10)
InChIKey
POWKBBOOIZBIRZ-UHFFFAOYSA-N
SMILES
C1(N)=NC=C(Br)C=C1C(OC)=O
More
Less

Safety

HazardClass 
IRRITANT
HS Code 
2933399990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Usbiological
Product number
283940
Product name
Methyl 2-Amino-5-bromonicotinate
Packaging
250mg
Price
$358
Updated
2021/12/16
TRC
Product number
M285720
Product name
Methyl2-Amino-5-bromonicotinate
Packaging
5g
Price
$415
Updated
2021/12/16
AK Scientific
Product number
J50922
Product name
Methyl2-amino-5-bromopyridine-3-carboxylate
Packaging
1g
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
043330
Product name
Methyl 2-amino-5-bromonicotinate
Purity
95+%
Packaging
1g
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
043330
Product name
Methyl 2-amino-5-bromonicotinate
Purity
95+%
Packaging
5g
Price
$34
Updated
2021/12/16
More
Less

Methyl 2-amino-5-bromonicotinate Chemical Properties,Usage,Production

Uses

Methyl 2-Amino-5-bromonicotinate is a chemical reagent used in the synthesis of pharmaceutical agents.

Synthesis

14667-47-1

50735-34-7

To a stirred solution of methyl 2-aminopyridine-3-carboxylate (2 g, 13.15 mmol) and sodium bicarbonate (2.2 g, 26.31 mmol) in dichloromethane (30 mL) was slowly added a dichloromethane solution of bromine dropwise (1.01 mL bromine dissolved in 20 mL dichloromethane). The reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the reaction was quenched with sodium bisulfite solution (50 mL). The reaction mixture was extracted with dichloromethane (2 x 40 mL) and the combined organic phases were washed with brine (40 mL) and dried over anhydrous sodium sulfate. After filtration, the solvent was evaporated under reduced pressure to give methyl 2-amino-5-bromopyridine-3-carboxylate as a yellow solid (3 g, 99% yield).LCMS m/z (79Br/81Br) 231/233 (M+H)+.

References

[1] Patent: US2017/29420, 2017, A1. Location in patent: Paragraph 0034

Methyl 2-amino-5-bromonicotinate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl 2-amino-5-bromonicotinate Suppliers

China 146 France 1 Germany 1 India 3 United Kingdom 3 United States 19 Global 173
Shaanxi Dideu Medichem Co. Ltd
Tel
029-81124267 17392282731
Fax
029-88380327
Email
1073@dideu.com
Country
China
ProdList
9992
Advantage
58
Shandong Lingyida Pharmaceutical Technology Co., Ltd
Tel
18762280800 15195955353
Email
2115358020@qq.com
Country
China
ProdList
68
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Tetranov Biopharm
Tel
13526569071
Email
sales@leadmedpharm.com
Country
China
ProdList
7892
Advantage
64
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Boc Chemical Co.,Ltd
Tel
021-34975603-808 18721111801
Fax
+86-21-34975602-805
Email
sales@bocpharma.com
Country
China
ProdList
1009
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Beijing Isomersyn Technology CO;LTD
Tel
010-82954736 13391601435
Email
sales@isomersyn.com
Country
China
ProdList
3295
Advantage
57
SpringPharma Tech Co.,Ltd
Tel
+86-25-68710855, +86-25-68710897
Fax
025-68710856
Email
sales@springpharma.net
Country
China
ProdList
1261
Advantage
62
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Hangzhou Sage Chemical Co., Ltd.
Tel
+86057186818502 13588463833
Fax
Pls mail us for more information!
Email
info@sagechem.com
Country
China
ProdList
10266
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
SuZhou ShiYa Biopharmaceuticals, Inc.
Tel
86(512)5235 8471 17715136450
Fax
86(512)5235 6881
Email
sales@shiyabiopharm.com
Country
China
ProdList
4169
Advantage
58
shanghai cooperpharm co.,LTD .
Tel
+86-021-58975553
Fax
+86-021-58975554
Email
sales@cooperpharm.com
Country
China
ProdList
1210
Advantage
56
Cantotech Chemicals, Ltd.
Tel
86-0755-86635001
Fax
86-0755-22642228
Email
cantotech@126.com
Country
China
ProdList
4566
Advantage
55
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
Tel
+86-28-85122536 85324413
Fax
+86-28-85326443
Email
market@astatech.cn
Country
China
ProdList
8026
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Porse Fine Chemical Co.,LTD
Tel
20-66003216 18666003216
Fax
+86-20-28069063
Email
info@porsefinechemical.com
Country
China
ProdList
1941
Advantage
62
Shanghai Worldyang Chemical Co.,Ltd.
Tel
021-021-56795766
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9476
Advantage
58
Wuxi Zhongkun Biochemical Technology Co., Ltd.
Tel
0510-85629785 18013409632
Fax
051085625359
Email
sales@reading-chemicals.com
Country
China
ProdList
15178
Advantage
58
Finetech Industry Limited
Tel
027-87465837 19945049750
Fax
027-8777-2287
Email
sales@finetechnology-ind.com
Country
China
ProdList
9637
Advantage
58
Zhengzhou TRIZ Pharmaceutical Technology Co., Ltd.
Tel
19943855286
Fax
0371-53392065
Email
triz-4@trizpharma.cn
Country
China
ProdList
1936
Advantage
56
Mashilabs (Shanghai) Co.,Ltd.
Tel
19916721580
Fax
QQ：3154870176
Email
mafarm@126.com
Country
China
ProdList
4542
Advantage
58
Shanghai Xingui Biotechnology Co., Ltd.
Tel
15121041756
Email
xingui2022@126.com
Country
China
ProdList
9979
Advantage
58
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
Lanzhou HuaHao Pharmaceutical Co., Ltd.
Tel
18189674620
Email
761137152@qq.com
Country
China
ProdList
489
Advantage
55
Hangzhou Milestone Pharmtech Co., Ltd.
Tel
0571-82896630 18969958410
Email
sales_hz@milestonepharmtech.com
Country
China
ProdList
4894
Advantage
55
AN PharmaTech Co Ltd
Tel
86(21)68097365
Fax
86(21)33321566
Email
sales@anpharma.net
Country
China
ProdList
4891
Advantage
55
Quzhou Rundong Chemical (Technology) Co.
Tel
0570-8789886 18892685668
Fax
0570-8789985
Email
info@rundongchemical.com
Country
China
ProdList
4053
Advantage
60
Struchem Co., Ltd.
Tel
0512-63009836 18994340901
Fax
0512-63006936
Email
helen@struchem.com
Country
China
ProdList
3981
Advantage
60
Suzhou Xinkai Bio-Medical Technology Co., Ltd.
Tel
0512-67213637 13952409868
Email
peter19zhang@163.com
Country
China
ProdList
442
Advantage
55
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6498
Advantage
58
JW & Y Pharmlab Co., Ltd.
Tel
021-64340559 13651849907;
Fax
021- 64345308
Email
xinyu_shi@jwypharmlab.com.cn
Country
China
ProdList
12000
Advantage
58
Chengdu Research Accelerators Technology Co., Ltd.
Tel
028-64353063
Fax
028-64353063 QQ:784253935
Email
reacchemical@163.com
Country
China
ProdList
5253
Advantage
58
Shanghai WeiNie Chemical Technology Co., Ltd.
Tel
15902145085
Fax
-
Email
657990292@qq.com
Country
China
ProdList
668
Advantage
50
Shangdong Youbang Biochemical Technology Co.,LTD.
Tel
15098208899
Fax
0530-7159266
Email
3368029756@qq.com
Country
China
ProdList
292
Advantage
58
Jiaxing Rich Biological Technology Co., Ltd.
Tel
0573-11111111-1111 18969316891
Fax
-
Email
richmol@163.com
Country
China
ProdList
449
Advantage
50
Tcichem, Inc.
Tel
13918644899
Fax
-
Email
tianchong009@hotmail.com
Country
China
ProdList
1818
Advantage
55
Henan CoreyChem Co., Ltd
Tel
0371-86658258
Fax
0371-60996044
Email
info@coreychem.com
Country
China
ProdList
10453
Advantage
58
Zhengzhou Alfachem Co.,Ltd.
Tel
0371-53778726 18003825608
Fax
QQ：2885354392
Email
liuxiaoyan@alfachem.cn
Country
China
ProdList
1986
Advantage
58
TaiChem Taizhou Limited
Tel
052386810091
Email
zcwy9518@yeah.net
Country
China
ProdList
3912
Advantage
58
Shanghai Qing Cang Chemical Technology Co., Ltd.
Tel
00000000000
Fax
-
Email
sales@qingcangchem.com
Country
China
ProdList
509
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Shanghai QianYan Bio-technology Co., Ltd
Tel
02781293128
Email
orders@biochemsafebuy.com
Country
China
ProdList
9923
Advantage
55
Changzhou Hopschain Chemical Co.,Ltd.
Tel
0519-85528066 13775048983
Fax
0519-85528066
Email
sales@hopschem.com
Country
China
ProdList
31553
Advantage
55
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Henan Anky Chemical Technology Co., Ltd.
Tel
17836913271
Fax
0374-8348899
Email
3224305243@qq.com
Country
China
ProdList
2944
Advantage
58
More
Less

View Lastest Price from Methyl 2-amino-5-bromonicotinate manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
Methyl 2-amino-5-bromonicotinate 50735-34-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-02-12
Shaanxi Haibo Biotechnology Co., Ltd
Product
Methyl 2-amino-5-bromonicotinate 50735-34-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000ton
Release date
2023-08-31
Henan Fengda Chemical Co., Ltd
Product
Methyl 2-amino-5-bromonicotinate 50735-34-7
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-30

50735-34-7, Methyl 2-amino-5-bromonicotinateRelated Search:

Aminopyrine Acetaminophen Methyl nicotinate Kresoxim-methyl Glucosamine Bensulfuron methyl Methylparaben Methyl 6-aminonicotinate EC 2.6.1.2 Methyl acetate Methyl anthranilate Methyl acrylate METHYL THIOPHENE-2-CARBOXYLATE Methyl 2-aminopyridine-4-carboxylate Sulfamic acid Thiophanate-methyl Methyl Methyl2-bromo-4-hydroxybenzoate

  • METHYL 2-AMINO-5-BROMONICOTINATE
  • METHYL 2-AMINO-5-BROMOPYRIDINE-3-CARBOXYLATE
  • Methyl 2-amino-5-bromopyridine-3-carboxylate, 2-Amino-5-bromo-3-(methoxycarbonyl)pyridine
  • METHYL 2-AMINO-5-BROMONICOTINAT
  • 3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl ester
  • 2-AMino-5-broMo-nicotinic acid ethyl ester
  • 2-AMINO-5-BROMO-NICOTINIC ACID METHYL ESTER
  • 2-AMINO-5-BROMONICOTINATE
  • 3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl e
  • Methyl 2-amino-5-bromonicotinate ISO 9001：2015 REACH
  • TIANFU-CHEM Methyl 2-amino-5-bromonicotinate 50735-34-7
  • 50735-34-7
  • Pyridine
  • Heterocycle-Pyridine series