Methyl 2-amino-5-bromonicotinate

Product Name: Methyl 2-amino-5-bromonicotinate
CAS No.: 50735-34-7
Chemical Name: Methyl 2-amino-5-bromonicotinate
Synonyms: 2-AMINO-5-BROMONICOTINATE;METHYL 2-AMINO-5-BROMONICOTINAT;METHYL 2-AMINO-5-BROMONICOTINATE;2-AMino-5-broMo-nicotinic acid ethyl ester;2-AMINO-5-BROMO-NICOTINIC ACID METHYL ESTER;METHYL 2-AMINO-5-BROMOPYRIDINE-3-CARBOXYLATE;Methyl 2-amino-5-bromonicotinate ISO 9001：2015 REACH;3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl e;TIANFU-CHEM Methyl 2-amino-5-bromonicotinate 50735-34-7;3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl ester
CBNumber: CB7700860
Molecular Formula: C7H7BrN2O2
Formula Weight: 231.05
MOL File: 50735-34-7.mol

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Methyl 2-amino-5-bromonicotinate Property

Melting point:: 143-146°C
Boiling point:: 275.2±35.0 °C(Predicted)
Density: 1.662±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 2.45±0.49(Predicted)
Appearance: White to yellow Solid
InChI: InChI=1S/C7H7BrN2O2/c1-12-7(11)5-2-4(8)3-10-6(5)9/h2-3H,1H3,(H2,9,10)
InChIKey: POWKBBOOIZBIRZ-UHFFFAOYSA-N
SMILES: C1(N)=NC=C(Br)C=C1C(OC)=O

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Safety

HazardClass: IRRITANT
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Usbiological

Product number: 283940
Product name: Methyl 2-Amino-5-bromonicotinate
Packaging: 250mg
Price: $358
Updated: 2021/12/16

TRC

Product number: M285720
Product name: Methyl2-Amino-5-bromonicotinate
Packaging: 5g
Price: $415
Updated: 2021/12/16

AK Scientific

Product number: J50922
Product name: Methyl2-amino-5-bromopyridine-3-carboxylate
Packaging: 1g
Price: $10
Updated: 2021/12/16

Matrix Scientific

Product number: 043330
Product name: Methyl 2-amino-5-bromonicotinate
Purity: 95+%
Packaging: 1g
Price: $10
Updated: 2021/12/16

Matrix Scientific

Product number: 043330
Product name: Methyl 2-amino-5-bromonicotinate
Purity: 95+%
Packaging: 5g
Price: $34
Updated: 2021/12/16

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Methyl 2-amino-5-bromonicotinate Chemical Properties,Usage,Production

Uses

Methyl 2-Amino-5-bromonicotinate is a chemical reagent used in the synthesis of pharmaceutical agents.

Synthesis

14667-47-1

50735-34-7

To a stirred solution of methyl 2-aminopyridine-3-carboxylate (2 g, 13.15 mmol) and sodium bicarbonate (2.2 g, 26.31 mmol) in dichloromethane (30 mL) was slowly added a dichloromethane solution of bromine dropwise (1.01 mL bromine dissolved in 20 mL dichloromethane). The reaction mixture was stirred at room temperature for 1 hour. Upon completion of the reaction, the reaction was quenched with sodium bisulfite solution (50 mL). The reaction mixture was extracted with dichloromethane (2 x 40 mL) and the combined organic phases were washed with brine (40 mL) and dried over anhydrous sodium sulfate. After filtration, the solvent was evaporated under reduced pressure to give methyl 2-amino-5-bromopyridine-3-carboxylate as a yellow solid (3 g, 99% yield).LCMS m/z (79Br/81Br) 231/233 (M+H)+.

References

[1] Patent: US2017/29420, 2017, A1. Location in patent: Paragraph 0034

Methyl 2-amino-5-bromonicotinate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-amino-5-bromonicotinate Suppliers

China 146 France 1 Germany 1 India 3 United Kingdom 3 United States 19 Global 173

Labex Corporation

Tel: +91-11-26135922 or +91-11-46160359
Fax: +91-11-26124735
Email: labex@labex.net
Country: India
ProdList: 391
Advantage: 55

A.J Chemicals

Tel: --
Fax: --
Email: sales@ajchem.in
Country: India
ProdList: 6100
Advantage: 58

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View Lastest Price from Methyl 2-amino-5-bromonicotinate manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: Methyl 2-amino-5-bromonicotinate 50735-34-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-02-12

Shaanxi Haibo Biotechnology Co., Ltd

Product: Methyl 2-amino-5-bromonicotinate 50735-34-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000ton
Release date: 2023-08-31

Henan Fengda Chemical Co., Ltd

Product: Methyl 2-amino-5-bromonicotinate 50735-34-7
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

50735-34-7, Methyl 2-amino-5-bromonicotinateRelated Search:

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METHYL 2-AMINO-5-BROMONICOTINATE

METHYL 2-AMINO-5-BROMOPYRIDINE-3-CARBOXYLATE

Methyl 2-amino-5-bromopyridine-3-carboxylate, 2-Amino-5-bromo-3-(methoxycarbonyl)pyridine

METHYL 2-AMINO-5-BROMONICOTINAT

3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl ester

2-AMino-5-broMo-nicotinic acid ethyl ester

2-AMINO-5-BROMO-NICOTINIC ACID METHYL ESTER

2-AMINO-5-BROMONICOTINATE

3-Pyridinecarboxylic acid, 2-aMino-5-broMo-, Methyl e

Methyl 2-amino-5-bromonicotinate ISO 9001：2015 REACH

TIANFU-CHEM Methyl 2-amino-5-bromonicotinate 50735-34-7

50735-34-7

Pyridine

Heterocycle-Pyridine series