Mannose Triflate

Product Name: Mannose Triflate
CAS No.: 92051-23-5
Chemical Name: Mannose Triflate
Synonyms: MANNOSE TRIFLATE;TATM;TATM USP/EP/BP;MANNOSE TRIFLATE F;beta-D-Mannopyranose;Mannose Triflate?New;Mannose triflate≥ 99%(GC);1,3,4,6-Tetra-O-acetyl-2-O-;Mannose Triflate, ultra pure;Mannose Triflate PLUS, ultra pure
CBNumber: CB7774955
Molecular Formula: C15H19F3O12S
Formula Weight: 480.36
MOL File: 92051-23-5.mol

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Mannose Triflate Property

Melting point:: 118-122 °C
alpha: [α]D20 -14～-17゜(c=1,CHCl3)
Boiling point:: 481.6±45.0 °C(Predicted)
Density: 1.50±0.1 g/cm3(Predicted)
refractive index: -16 ° (C=1, CHCl3)
storage temp.: -20°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Solid
color: White to Off-White
optical activity: [α]22/D -16°, c = 1 in chloroform
BRN: 4341413
InChI: InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3
InChIKey: OIBDVHSTOUGZTJ-UBBZJQTNNA-N
SMILES: [C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r|

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Safety

Hazard Codes: Xi
Safety Statements: 24/25
WGK Germany: 3
F: 10-21
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M1568
Product name: Mannose triflate
Purity: For PET imaging, ≥98% (TLC)
Packaging: 20mg
Price: $27.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: Y0001087
Product name: Tetra-<I>O</I>-acetyl-mannose triflate
Purity: European Pharmacopoeia (EP) Reference Standard
Packaging: 2each
Price: $144
Updated: 2024/03/01

Sigma-Aldrich

Product number: 655112
Product name: β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
Purity: 98%
Packaging: 100mg
Price: $28.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: Y0001087
Product name: Tetra-O-acetyl-mannose triflate
Purity: European Pharmacopoeia (EP) Reference Standard
Packaging: 2EA
Price: $144
Updated: 2023/06/20

TCI Chemical

Product number: T2307
Product name: 1,3,4,6-Tetra-O-acetyl-2-O-(trifluoromethanesulfonyl)-beta-D-mannopyranose
Purity: >98.0%(GC)
Packaging: 100mg
Price: $39
Updated: 2024/03/01

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Mannose Triflate Chemical Properties,Usage,Production

Description

Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.

Physical properties

White to off-white powder or crystal

Uses

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.

Preparation

The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).

Mannose Triflate Preparation Products And Raw materials

Raw materials

Preparation Products

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Mannose Triflate Suppliers

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View Lastest Price from Mannose Triflate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Mannose Triflate 92051-23-5
Price: US $0.00/G
Min. Order: 1G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-17

Zibo Hangyu Biotechnology Development Co., Ltd

Product: TATM 92051-23-5
Price: US $50.00-500.00/kg
Min. Order: 10kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-31

Henan Fengda Chemical Co., Ltd

Product: TATM 92051-23-5
Price: US $6.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-03-28

92051-23-5, Mannose TriflateRelated Search:

Ethyl trifluoromethanesulfonate N-DECYL-BETA-D-GLUCOPYRANOSIDE glucosylglycerol Glabridin 1,3-BUTANEDIOL DIACETATE 2-Butoxyethyl acetate 1,6-Diacetoxyhexane L(+)-Rhamnose monohydrate D-LYXOSE Methyl trifluoromethanesulfonate 2-[(Acetyloxy)methoxy]ethyl acetate Diacetin D-Mannose 1,1,3-TRIMETHOXYBUTANE ISOPROPYL METHANESULFONATE TATM Trifluoromethane FLUOROSULFONIC ACID

MANNOSE TRIFLATE

MANNOSE TRIFLATE F

1,3,4,6-Tetraacetate 2-(trifluoromethanesulfonate) -D-Mannopyranose

tetraacetyltrifluoromethanesulfonyl-beta-D-mannopyranose

Mannose triflate, TATM, 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

1-O,3-O,4-O,6-O-Tetraacetyl-2-O-(trifluoromethylsulfonyl)-β-D-mannopyranose

1-O,3-O,4-O,6-O-Tetraacetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate Mannose triflate

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose

β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose, Mannose triflate, TATM

β-D-Maopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate

1,3,4,6-Tetraacetate 2-(trifluoroMethanesulfonate)

1,3,4,6-Tetra-O-acetyl-2-O-trifluoroMethane

1,3,4,6-Tetra-O-acetyl-2-O-[(trifluoromethyl)sulphonyl]-beta-D-mannopyranose

TATM, 1,3,4,6-Tetra-O-acetyl-2-O-triflyl-beta-D-mannopyranose

b-D-Mannopyranose,1,3,4,6-tetraacetate 2-(trifluoroMethanesulfonate)

beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoroMethanesulfonate 98%

beta-D-Mannopyranose

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-

β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate(TATM)

acetic acid [3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)-2-oxanyl]methyl ester

TATM,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose

BETA-D-MANNOPYRANOSE 1,3,4,6-TETRAACETATE 2-TRIFLATE

BETA-D-MANNOPYRANOSE, 1,3,4,6-TETRAACETATE 2-(TRIFLUOROMETHANE-SULFONATE)

BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETATE 2-O-TRIFLUOROMETHANESULFONATE

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-METHANESULFONYL-BETA-D-MANNOPYRANOSE

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHANSULFONYL-BETA-D-MANNOPYRANOSE

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULPHONYL-B-D-MANNOPYRANOSE

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

TATM

β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate

1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose

tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-*METHANESULFONY

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-b-D-mannopyranose

1,3,4,6-Tetra-O-acetyl-2-O-

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE, TATM

1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE(MANNOSE TRIFLATE)

TETRA-O-ACETYL-2-O-TRIFLUOROMETHANE- &

BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-AC&

Mannose Triflate PLUS, ultra pure

Mannose Triflate, ultra pure packing for GE Microlab

Mannose Triflate, ultra pure packing for GE TRACERlab MXFDG

Mannose Triflate, ultra pure

1,3,4,6-Tetra-O-Acetyl-2-O-(trifluoromethanesulfonyl)-a-D-mannopyranose

Mannose triflate≥ 99%(GC)

[(2R,3R,4S,5S,6S)-3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)oxan-2-yl]methyl acetate

Mannose triflate C15H19F3O12S high quality Cas number：92051-23-5

Tetra-O-acetyl-mannose triflate CRS

β-D-Mannopyranose, 1,3,4,6-tetraacetate 2-(trifluoromethanesulfonate)

TATM USP/EP/BP

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

β-D-Mannopyranose1,3,4,6-tetra-O-acetate2-O-trifluoromethanesulfonate

1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate-β-D-Mannopyranose

(2S,3S,4S,5R,6R)-6-(Acetoxymethyl)-3-(((trifluoromethyl)sulfonyl)oxy)tetrahydro-2H-pyran-2,4,5-triyl triacetate

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose

1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyr