4-Amino-3-fluorophenol

Uses

Product Name: 4-Amino-3-fluorophenol
CAS No.: 399-95-1
Chemical Name: 4-Amino-3-fluorophenol
Synonyms: 4-Amino-3-fluorphenol;4-Amino-3-fL;4-AMino-3-fluo;BUTTPARK 33\04-79;Aminofluorophenol3;IFLAB-BB F2108-0045;4-Amino-3-fluorophen;3-FLUORO-4-AMINOPHENOL;4-AMINO-3-FLUOROPHENOL;2-FLUORO-4-YDROXYANILINE
CBNumber: CB7853597
Molecular Formula: C6H6FNO
Formula Weight: 127.12
MOL File: 399-95-1.mol

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4-Amino-3-fluorophenol Property

Melting point:: 135-137°C
Boiling point:: 270.4±25.0 °C(Predicted)
Density: 1.347±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: soluble in Methanol
pka: 9.23±0.18(Predicted)
form: powder to crystal
color: Light yellow to Brown
InChI: InChI=1S/C6H6FNO/c7-5-3-4(9)1-2-6(5)8/h1-3,9H,8H2
InChIKey: MNPLTKHJEAFOCA-UHFFFAOYSA-N
SMILES: C1(O)=CC=C(N)C(F)=C1
CAS DataBase Reference: 399-95-1(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xi,N
Risk Statements: 22-43-45-51/53
Safety Statements: 45-53-61
RIDADR: 3077
Hazard Note: Toxic
HazardClass: 9
PackingGroup: III
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H350May cause cancer

H401Toxic to aquatic life

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: A2164
Product name: 4-Amino-3-fluorophenol
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $71
Updated: 2025/07/31

TCI Chemical

Product number: A2164
Product name: 4-Amino-3-fluorophenol
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $295
Updated: 2025/07/31

TRC

Product number: A609595
Product name: 4-Amino-3-fluorophenol
Packaging: 1g
Price: $95
Updated: 2021/12/16

TRC

Product number: A609595
Product name: 4-Amino-3-fluorophenol
Packaging: 5g
Price: $245
Updated: 2021/12/16

AK Scientific

Product number: J90717
Product name: 3-Fluoro-4-aminophenol
Packaging: 5g
Price: $14
Updated: 2021/12/16

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4-Amino-3-fluorophenol Chemical Properties,Usage,Production

Uses

4-Amino-3-fluorophenol is a compound that can be used in organic synthesis.

Description

4-amino-3-fluorophenol, a light yellow to brown power, is the raw material of a kind of application medicine, a pesticidal active substance very widely, is a fluorinated insecticide, Phenoxymethyl acetate esters, and benzo pyrrole ketone herbicide, the intermediate of antibacterial and hair dye, etc. Fluoro substituents in the 4-amino-3-fluorophenol molecule increase the lipophile of the whole molecule greatly, thus adding to the membrane permeability of this molecule so that it is suitable as the active component intermediate of some medicines.

Chemical Properties

Dark Brown Solid

Synthesis

Using p-nitrophenol as raw material, after catalytic hydrogenation, a sulfonation reaction is performed first, and then a fluorine substitution reaction is performed to substitute the fluorine at the 3-position. Afterwards, a desulfonation reaction was carried out, and the target product 4-Amino-3-fluorophenol was obtained through extraction.

References

[1] Patent: US2005/277652, 2005, A1. Location in patent: Page/Page column 72-73
[2] Patent: WO2006/124118, 2006, A1. Location in patent: Page/Page column 74
[3] Patent: WO2005/9961, 2005, A2. Location in patent: Page/Page column 46
[4] Patent: WO2008/89388, 2008, A2. Location in patent: Page/Page column 16
[5] Patent: WO2008/89389, 2008, A2. Location in patent: Page/Page column 13

4-Amino-3-fluorophenol Preparation Products And Raw materials

Raw materials

1-Fluoro-2-nitrobenzene

Preparation Products

Flufenoxuron

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4-Amino-3-fluorophenol Suppliers

Americas 1 Canada 3 China 432 China Hong Kong 1 Europe 3 France 1 Germany 7 India 14 Italy 1 Japan 6 The Netherlands 1 Ukraine 1 United Kingdom 23 United States 36 Global 530

Yangzhou juhechang Technology Co., Ltd

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TIANJIN PHARMACN MEDICAL TECHNOLOGY CO.,LTD.

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J & K SCIENTIFIC LTD.

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future industrial shanghai co., ltd

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View Lastest Price from 4-Amino-3-fluorophenol manufacturers

Jinan Ruitong Biotech Co., Ltd.

Product: 4-Amino-3-fluorophenol 399-95-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1
Release date: 2025-08-28

Shaanxi Dideu New Materials Co. Ltd

Product: 4-Amino-3-fluorophenol 399-95-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-05-07

Handan City Zechi trading Co., LTD

Product: 4-amino-3-fluorophenol 399-95-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 10000
Release date: 2025-03-22

399-95-1, 4-Amino-3-fluorophenolRelated Search:

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4-Amino-3-fluorophenolQ: What is 4-Amino-3-fluorophenol Q: What is the CAS Number of 4-Amino-3-fluorophenol Q: What is the storage condition of 4-Amino-3-fluorophenol

4-Amino-3-fluorophenol in acetonitrile

4-Amino-3-fluorophenol 100 μg/mL in Acetonitrile

399-95-1

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