ChemicalBook > CAS DataBase List > 1,2-Cyclohexanedione

1,2-Cyclohexanedione

Product Name
1,2-Cyclohexanedione
CAS No.
765-87-7
Chemical Name
1,2-Cyclohexanedione
Synonyms
Cyclohexane-1,2-dione;1,2-CYCLOHEXANDIONE;Cyclohexane-1,2-dione 98%;1,2-CycL;AKOS 197;AI3-25042;NSC 32950;CCRIS 6296;BRN 0507419;DIHYDROCATECHOL
CBNumber
CB7854271
Molecular Formula
C6H8O2
Formula Weight
112.13
MOL File
765-87-7.mol
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1,2-Cyclohexanedione Property

Melting point:
34-38 °C (lit.)
Boiling point:
193-195 °C (lit.)
Density 
1,118 g/cm3
refractive index 
1.518-1.52
FEMA 
3458 | 2-HYDROXY-2-CYCLOHEXEN-1-ONE
Flash point:
184 °F
storage temp. 
2-8°C
solubility 
Soluble in DMSO
form 
Liquid After Melting
color 
Clear yellow
Odor
at 10.00 % in dipropylene glycol. sweet acorn nut skin maple caramel brothy
Odor Type
nutty
Water Solubility 
Soluble
JECFA Number
424
BRN 
507419
LogP
0.252 (est)
CAS DataBase Reference
765-87-7(CAS DataBase Reference)
NIST Chemistry Reference
c-hexane-1,2-dione(765-87-7)
EPA Substance Registry System
1,2-Cyclohexanedione (765-87-7)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
Safety Statements 
24/25
WGK Germany 
3
RTECS 
GV0340000
F 
8
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29142990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C101400
Product name
1,2-Cyclohexanedione
Purity
97%
Packaging
1g
Price
$50.9
Updated
2024/03/01
Sigma-Aldrich
Product number
C101400
Product name
1,2-Cyclohexanedione
Purity
97%
Packaging
5g
Price
$111
Updated
2024/03/01
TCI Chemical
Product number
C0728
Product name
1,2-Cyclohexanedione
Purity
>97.0%(GC)
Packaging
5g
Price
$73
Updated
2024/03/01
TCI Chemical
Product number
C0728
Product name
1,2-Cyclohexanedione
Purity
>97.0%(GC)
Packaging
25g
Price
$288
Updated
2024/03/01
Alfa Aesar
Product number
A14401
Product name
1,2-Cyclohexanedione, 98+%
Packaging
5g
Price
$91.4
Updated
2024/03/01
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1,2-Cyclohexanedione Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid after melting

Uses

1,2-Cyclohexanedione is utilized as a substrate to study enzyme cyclohexane-1,2-dione hydrolase, which is a new tool to degrade alicyclic compounds. It also acts as a specific reagent for arginine residues.

Uses

1,2-Cyclohexanedione have been used as a substrate to study enzyme cyclohexane-1,2-dione hydrolase as a new tool to degrade alicyclic compounds.

Definition

ChEBI: Cyclohexane-1,2-dione is a cyclohexanedione carrying oxo substituents at positions 1 and 2.

Reactions

1,2-Cyclohexanedione may effectively occupy vacant coordination sites and thus promote the present cycloisomerization[1]. Tanaka et al. research the catalytic cycloisomerization of 1,6- and 1,7-diynes leading to trienes and vinylpyrroles by using a cationic rhodium(I)/Segphos complex (2.5-10 mol %) and 1,2-cyclohexanedione (100 mol %).

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 4658, 1951 DOI: 10.1021/ja01154a048
Tetrahedron Letters, 25, p. 603, 1984 DOI: 10.1016/S0040-4039(00)99949-0
The Journal of Organic Chemistry, 39, p. 3295, 1974 DOI: 10.1021/jo00936a034

References

[1] Ken Tanaka, Masao Hirano, Yousuke Otake. “Cationic Rhodium(I)/Segphos-Catalyzed Cycloisomerization of 1,6- and 1,7-Diynes in the Presence of 1,2-Cyclohexanedione.” Organic Letters 9 20 (2007): 3953–3956.

1,2-Cyclohexanedione Preparation Products And Raw materials

Raw materials

Selenium dioxide Cyclohexanone

Preparation Products

1,2-CYCLOHEXANEDIONE DIOXIME
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1,2-Cyclohexanedione Suppliers

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View Lastest Price from 1,2-Cyclohexanedione manufacturers

Jiangsu Nata Opto-electronic Material Co.,Ltd.
Product
1,2-Cyclohexanedione 765-87-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1MT
Release date
2023-05-22
Milestone Chemical Wuxi Co.,Ltd
Product
1,2-Cyclohexanedione 765-87-7
Price
US $0.00-0.00/kg T
Min. Order
1kg T
Purity
96%MIN
Supply Ability
20TONS
Release date
2023-03-20
Henan Aochuang Chemical Co.,Ltd.
Product
1,2-Cyclohexanedione 765-87-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-17

765-87-7, 1,2-CyclohexanedioneRelated Search:

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  • BioChemical
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