1,2-Cyclohexanedione
- Product Name
- 1,2-Cyclohexanedione
- CAS No.
- 765-87-7
- Chemical Name
- 1,2-Cyclohexanedione
- Synonyms
- Cyclohexane-1,2-dione;1,2-CYCLOHEXANDIONE;Cyclohexane-1,2-dione 98%;1,2-CycL;AKOS 197;AI3-25042;NSC 32950;CCRIS 6296;BRN 0507419;DIHYDROCATECHOL
- CBNumber
- CB7854271
- Molecular Formula
- C6H8O2
- Formula Weight
- 112.13
- MOL File
- 765-87-7.mol
1,2-Cyclohexanedione Property
- Melting point:
- 34-38 °C (lit.)
- Boiling point:
- 193-195 °C (lit.)
- Density
- 1,118 g/cm3
- refractive index
- 1.518-1.52
- FEMA
- 3458 | 2-HYDROXY-2-CYCLOHEXEN-1-ONE
- Flash point:
- 184 °F
- storage temp.
- 2-8°C
- solubility
- Soluble in DMSO
- form
- Liquid After Melting
- color
- Clear yellow
- Odor
- at 10.00 % in dipropylene glycol. sweet acorn nut skin maple caramel brothy
- Odor Type
- nutty
- Water Solubility
- Soluble
- JECFA Number
- 424
- BRN
- 507419
- LogP
- 0.252 (est)
- CAS DataBase Reference
- 765-87-7(CAS DataBase Reference)
- NIST Chemistry Reference
- c-hexane-1,2-dione(765-87-7)
- EPA Substance Registry System
- 1,2-Cyclohexanedione (765-87-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- C101400
- Product name
- 1,2-Cyclohexanedione
- Purity
- 97%
- Packaging
- 1g
- Price
- $50.9
- Updated
- 2024/03/01
- Product number
- C101400
- Product name
- 1,2-Cyclohexanedione
- Purity
- 97%
- Packaging
- 5g
- Price
- $111
- Updated
- 2024/03/01
- Product number
- C0728
- Product name
- 1,2-Cyclohexanedione
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $73
- Updated
- 2024/03/01
- Product number
- C0728
- Product name
- 1,2-Cyclohexanedione
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $288
- Updated
- 2024/03/01
- Product number
- A14401
- Product name
- 1,2-Cyclohexanedione, 98+%
- Packaging
- 5g
- Price
- $91.4
- Updated
- 2024/03/01
1,2-Cyclohexanedione Chemical Properties,Usage,Production
Chemical Properties
clear yellow liquid after melting
Uses
1,2-Cyclohexanedione is utilized as a substrate to study enzyme cyclohexane-1,2-dione hydrolase, which is a new tool to degrade alicyclic compounds. It also acts as a specific reagent for arginine residues.
Uses
1,2-Cyclohexanedione have been used as a substrate to study enzyme cyclohexane-1,2-dione hydrolase as a new tool to degrade alicyclic compounds.
Definition
ChEBI: Cyclohexane-1,2-dione is a cyclohexanedione carrying oxo substituents at positions 1 and 2.
Reactions
1,2-Cyclohexanedione may effectively occupy vacant coordination sites and thus promote the present cycloisomerization[1]. Tanaka et al. research the catalytic cycloisomerization of 1,6- and 1,7-diynes leading to trienes and vinylpyrroles by using a cationic rhodium(I)/Segphos complex (2.5-10 mol %) and 1,2-cyclohexanedione (100 mol %).
Synthesis Reference(s)
Journal of the American Chemical Society, 73, p. 4658, 1951 DOI: 10.1021/ja01154a048
Tetrahedron Letters, 25, p. 603, 1984 DOI: 10.1016/S0040-4039(00)99949-0
The Journal of Organic Chemistry, 39, p. 3295, 1974 DOI: 10.1021/jo00936a034
References
[1] Ken Tanaka, Masao Hirano, Yousuke Otake. “Cationic Rhodium(I)/Segphos-Catalyzed Cycloisomerization of 1,6- and 1,7-Diynes in the Presence of 1,2-Cyclohexanedione.” Organic Letters 9 20 (2007): 3953–3956.
1,2-Cyclohexanedione Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,2-Cyclohexanedione manufacturers
- Product
- 1,2-Cyclohexanedione 765-87-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1MT
- Release date
- 2023-05-22
- Product
- 1,2-Cyclohexanedione 765-87-7
- Price
- US $0.00-0.00/kg T
- Min. Order
- 1kg T
- Purity
- 96%MIN
- Supply Ability
- 20TONS
- Release date
- 2023-03-20
- Product
- 1,2-Cyclohexanedione 765-87-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-17