ChemicalBook > CAS DataBase List > 1,2,3-Trichlorobenzene

1,2,3-Trichlorobenzene

Product Name
1,2,3-Trichlorobenzene
CAS No.
87-61-6
Chemical Name
1,2,3-Trichlorobenzene
Synonyms
1,2,3-TCB;ai3-15516;1.2.3-Tric;1,2,3-trcb;Trichlorbenzole;1,2,3-Trichlorobenze;VIC-TRICHLOROBENZENE;1,2,3-Trichlorbenzol;1,2,3-TRICHLORBENZENE;1,2,3-Trichlorobnzene
CBNumber
CB7854514
Molecular Formula
C6H3Cl3
Formula Weight
181.45
MOL File
87-61-6.mol
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1,2,3-Trichlorobenzene Property

Melting point:
51-53 °C (lit.)
Boiling point:
218-219 °C (lit.)
Density 
1,69 g/cm3
vapor density 
6.25 (vs air)
vapor pressure 
0.07 mm Hg ( 25 °C)
refractive index 
1.5693 (estimate)
Flash point:
260 °F
storage temp. 
0-6°C
solubility 
0.02g/l
form 
neat
color 
White crystals or platelets
explosive limit
2.5-6.6%(V)
Water Solubility 
INSOLUBLE
Merck 
14,9630
BRN 
956882
Henry's Law Constant
8.36, 10.3, 13.2, 20.6, and 26.5 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (EPICS-SPME, Dewulf et al., 1999)
CAS DataBase Reference
87-61-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,2,3-trichloro-(87-61-6)
EPA Substance Registry System
1,2,3-Trichlorobenzene (87-61-6)
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Safety

Hazard Codes 
Xn,T,N
Risk Statements 
22-36/37/38-38-39/23/24/25-23/24/25-52/53-51/53
Safety Statements 
36/37-26-45-61-36
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
DC2095000
Autoignition Temperature
1059 °F
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29036990
Hazardous Substances Data
87-61-6(Hazardous Substances Data)
Toxicity
LC50 2,177 to 3,084 μg/L (soil porewater concentration) for earthworm (Eisenia andrei) and 2,540 to 3,084 μg/L (soil porewater concentration) for earthworm (Lumbricus rubellus) (Van Gestel and Ma, 1993).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H370Causes damage to organs

H401Toxic to aquatic life

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P330Rinse mouth.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
T54402
Product name
1,2,3-Trichlorobenzene
Purity
99%
Packaging
5g
Price
$25.1
Updated
2021/03/22
Sigma-Aldrich
Product number
36742
Product name
1,2,3-Trichlorobenzene
Purity
PESTANAL , analytical standard
Packaging
1g
Price
$24.2
Updated
2021/03/22
TCI Chemical
Product number
T0377
Product name
1,2,3-Trichlorobenzene
Packaging
500G
Price
$116
Updated
2021/03/22
TCI Chemical
Product number
T0377
Product name
1,2,3-Trichlorobenzene
Packaging
25G
Price
$26
Updated
2021/03/22
Alfa Aesar
Product number
B22154
Product name
1,2,3-Trichlorobenzene, 99%
Packaging
100g
Price
$24.4
Updated
2021/03/22
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1,2,3-Trichlorobenzene Chemical Properties,Usage,Production

Chemical Properties

White crystalline

Uses

Organic intermediate.

General Description

A white solid with a sharp chlorobenzene odor. Insoluble in water and denser than water. Hence sinks in water. Melting point 63-64°C (145-147°F).

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,2,3-Trichlorobenzene can react with oxidizing agents. . May emit toxic hydrogen chloride and phosgene gases in fire.

Health Hazard

Inhalation may cause irritation of respiratory tract. Irritating to the eyes. May redden skin on contact. Ingestion may cause liver damage.

Environmental Fate

Biological. Under aerobic conditions, soil microbes are capable of degrading 1,2,3- trichlorobenzene to 1,2- and 1,3-dichlorobenzene and carbon dioxide (Kobayashi and Rittman, 1982). A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,3-trichlorobenzene to 2,3,4-, 3,4,5-, and 2,3,6-trichlorophenol (Ballschiter and Scholz, 1980).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,3- trichlorobenzene underwent reductive dechlorination to 1,2- and 1,3-dichlorobenzene at relative molar yields of 1 and 99%, respectively. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 60 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. The sunlight irradiation of 1,2,3-trichlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 56 d yielded 32 ppm pentachlorobiphenyl (Uyeta et al., 1976).
Chemical/Physical. At 70.0 °C and pH values of 3.07, 7.13, and 9.80, the hydrolysis half-lives were calculated to be 19.2, 15.0, and 34.4 d, respectively (Ellington et al., 1986). Emits toxic chloride fumes when heated to decomposition.

Purification Methods

Crystallise it from EtOH. [Beilstein 5 IV 664.]

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1,2,3-Trichlorobenzene Suppliers

Nanjing XiLang Chemical Products Co., Ltd.
Tel
025-5276156
Email
chemxilang@163.com
Country
China
ProdList
3972
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Energy Chemical
Tel
021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
42923
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18227
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12282
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078,021-50426030
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
10006
Advantage
60
Adamas Reagent, Ltd.
Tel
400-600-9262
Email
bxy@titansci.com
Country
China
ProdList
13915
Advantage
59
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View Lastest Price from 1,2,3-Trichlorobenzene manufacturers

Speranza Chemical Co., Ltd.
Product
1,2,3-Trichlorobenzene 87-61-6
Price
US $20.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
300MT/year
Release date
2019-12-24
Hebei Mojin Biotechnology Co., Ltd
Product
1, 2, 3 - trichlorobenzene 87-61-6
Price
US $63.00/KG
Min. Order
25KG
Purity
99.99%
Supply Ability
200ton
Release date
2021-07-09
Zhuozhou Wenxi import and Export Co., Ltd
Product
1,2,3-Trichlorobenzene solution 87-61-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

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