Furfuryl alcohol

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Furfuryl alcohol

Description References

Product Name: Furfuryl alcohol
CAS No.: 98-00-0
Chemical Name: Furfuryl alcohol
Synonyms: FA;2-FURANMETHANOL;FURANMETHANOL;FURFURAL ALCOHOL;Furfuranol;2-FURYLMETHANOL;2-furanemethanol;HPFA;2-Furanylmethanol;Furfuryl Alchohol
CBNumber: CB7854741
Molecular Formula: C5H6O2
Formula Weight: 98.1
MOL File: 98-00-0.mol

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Furfuryl alcohol Property

Melting point:: -29 °C (lit.)
Boiling point:: 170 °C (lit.)
Density: 1.135 g/mL at 25 °C (lit.)
vapor density: 3.4 (vs air)
vapor pressure: 0.5 mm Hg ( 20 °C)
refractive index: n20/D 1.486(lit.)
FEMA: 2491 | FURFURYL ALCOHOL
Flash point:: 149 °F
storage temp.: Store below +30°C.
solubility: alcohol: soluble
form: Liquid
pka: 14.02±0.10(Predicted)
color: Clear yellow
PH: 6 (300g/l, H2O, 20℃)
Odor: Mildly irritating.
Odor Threshold: 8 ppm
Odor Type: bready
explosive limit: 1.8-16.3%(V)
Water Solubility: MISCIBLE
FreezingPoint: -29℃
Merck: 14,4305
JECFA Number: 451
BRN: 106291
Exposure limits: NIOSH REL: TWA 10 ppm (40 mg/m³), STEL 15 ppm (60 mg/m³), IDLH 75 ppm; OSHA PEL: TWA 50 ppm; ACGIH TLV: TWA 10 ppm, STEL 15 ppm (adopted).
LogP: 0.3 at 25℃
CAS DataBase Reference: 98-00-0(CAS DataBase Reference)
NIST Chemistry Reference: 2-Furanmethanol(98-00-0)
IARC: 2B (Vol. 119) 2019
EPA Substance Registry System: 2-Furanmethanol (98-00-0)

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Safety

Hazard Codes: Xn,T
Risk Statements: 20/21/22-48/20-40-36/37-23-21/22
Safety Statements: 23-36/37/39-63-45-36/37-24/25
RIDADR: UN 2874 6.1/PG 3
WGK Germany: 1
RTECS: LU9100000
F: 8
Autoignition Temperature: 915 °F
TSCA: Yes
HS Code: 2932 13 00
HazardClass: 6.1
PackingGroup: III
Hazardous Substances Data: 98-00-0(Hazardous Substances Data)
Toxicity: LC50 (4 hr) in rats: 233 ppm (Jacobson)
IDLA: 75 ppm

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W249166
Product name: Furfuryl Alcohol
Purity: natural, ≥95%, FG
Packaging: 1kg
Price: $135
Updated: 2024/03/01

Sigma-Aldrich

Product number: W249166
Product name: Furfuryl Alcohol
Purity: natural, ≥95%, FG
Packaging: 10Kg
Price: $805
Updated: 2024/03/01

Sigma-Aldrich

Product number: W249166
Product name: Furfuryl Alcohol
Purity: natural, ≥95%, FG
Packaging: 25kg
Price: $1880
Updated: 2024/03/01

Sigma-Aldrich

Product number: W249106
Product name: Furfuryl Alcohol
Purity: ≥97%, FG
Packaging: 1kg
Price: $76.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: W249106
Product name: Furfuryl Alcohol
Purity: ≥97%, FG
Packaging: 5kg
Price: $142
Updated: 2024/03/01

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Furfuryl alcohol Chemical Properties,Usage,Production

Description

Furfuryl alcohol is clear colorless organic liquid having a furan substituted with a hydroxymethyl group. It is primarily used for the synthesis of furans resins which are used in thermoset polymer matrix composites, cements, adhesive and coatings. It plays an essential role in the production of foundry sand binder and has long been used to produce cores and molds for metal casting. Other applications include as a fuel and wood treatment. In industry, it is manufactured through either direct reduction of furfural, or through the disproportionation via the Cannizaro reaction in NaOH solution. The basic raw materials for its manufacturing are waste vegetable materials such as rice hulls, sugar cane bagasse, oat hulls or corncobs.

References

https://en.wikipedia.org/wiki/Furfuryl_alcohol
http://www.furan.com/furfuryl_alcohol_applications.html

Description

Furfural alcohol is a colorless to amber liquidthat darkens on exposure to light. It has a faint, burningodor. Molecular weight=98.11; Specific gravityFurfuryl alcohol 1371(H2O:1)=1.13; Boiling point: 171℃; Melting point:215℃; Vapor pressure=6 mmHg at 25℃; Flash point =65℃ (cc); 75℃ (oc); Autoignition temperature=491℃.Explosive limits: LEL=1.8%; UEL=16.3%. HazardIdentification (based on NFPA-704 M Rating System):Health 1, Flammability 2, Reactivity 1. Soluble in water.

Chemical Properties

clear yellow liquid

Chemical Properties

Furfural alcohol is a colorless to amber liquid that darkens on exposure to light. It has a faint, burning odor.

Chemical Properties

Furfuryl alcohol has a very mild, warm, oily, “burnt” odor and a cooked sugar taste.

Physical properties

Clear, colorless to pale yellow liquid with an irritating odor. Darkens to yellowish-brown on exposure to air. A detection odor threshold concentration of 32 mg/m³ (8.0 ppm_v) was determined by Jacobson et al. (1958).

Occurrence

Reported found in roasted almonds, cooked apple, apple juice, roasted barley, beans, beef fat, canned beef stew, beer, brandy, white bread, cocoa, cocoa bean, roasted coffee, roasted flberts, honey, heated skim milk, dried mushrooms, roasted onion, yellow passion fruit, roasted peanuts, pineapple, popcorn, potato chips, roasted sesame seeds, cheeses, milk, meats, grape wines, cognac, whiskies, soybean products, coconut, corn oil, shrimps, clams and other sources

Uses

Colorless liquid that turns dark in air

Uses

Furfuryl Alcohol has been obtained by yeast reduction of furfural. Furfuryl Alcohol is used as solvent and in the manufacturing of wetting agents, resins.

Uses

Solvent; manufacture of wetting agents, resins.

Preparation

Usually prepared from furfural that is obtained by the processing of corncobs; oil obtained by steam distillation of roasted coffee bean meal consists of 50% furfuryl alcohol; prepared industrially by the catalytic reduction of furfural using nickel and Cu-CrO catalysts.

Definition

ChEBI: A member of the class of furans bearing a hydroxymethyl substituent at the 2-position.

Aroma threshold values

Detection: 1 to 2 ppm.

Taste threshold values

Taste characteristics at 50 ppm: burnt, sweet, caramellic and brown.

Synthesis Reference(s)

Synthesis, p. 246, 1977
Tetrahedron Letters, 33, p. 5417, 1992 DOI: 10.1016/S0040-4039(00)79109-X

General Description

A clear colorless liquid. Flash point 167°F. Boiling point 171°F. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion and skin contact and moderately toxic by inhalation.

Air & Water Reactions

Slightly soluble in water.

Hazard

May react explosively with mineral acids and some organic acids. Toxic by inhalation and skin absorption. Approved for food products. Toxic by skin absorption.

Health Hazard

Inhalation causes headache, nausea, and irritation of nose and throat. Vapor irritates eyes; liquid causes inflammation and corneal opacity. Contact of skin with liquid causes dryness and irritation. Ingestion causes headache, nausea, and irritation of mouth and stomach.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: The product darkens and forms water insoluble material on exposure to air or acids. This reaction is accelerated at elevated temperatures; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Biochem/physiol Actions

Taste at 20-40ppm

Safety Profile

Poison by ingestion, skin contact, and subcutaneous routes.Moderately toxic by inhalation and intraperitoneal routes. Mutation data reported. An eye irritant. Flammable when exposed to heat or flame; can react with oxidtzing materials. Moderate explosion hazard when exposed to heat or flame. Reacts violently with acids (e.g., formic acid, cyanoacetic acid + heat). Ignites on contact with 85% hydrogen peroxide. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

Potential Exposure

Used as a starting monomer in the production of furan resins and used to produce tetrahydro furfural alcohol (THFA).

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Carcinogenicity

The NTP conducted a 2-year inhalation study on furfuryl alcohol. F344 rats and B6C3F1 mice were exposed to 0, 2, 8, or 32 ppm furfuryl alcohol for 6 h/day, 5 days/week. All rats exposed to 32 ppm died by week 99; survival of all other animals was similar to control animals. There were increased incidences of nasal tumors in the male rats and increased incidences of kidney tubule tumors in male mice. Increased incidences of nonneoplastic lesions of the nose and increased severities of nephropathy were observed in male and female rats and male mice. Nonneoplastic lesions of nose and corneal degeneration occurred in female mice.

Source

Furfuryl occurs naturally in yarrow, licorice, sesame seeds, clove flowers, and tea leaves (Duke, 1992). Also detected in barrel-aged red, white, and model wines. Concentrations ranged from 3.5 mg/L in white wine after 55 wk of aging to 9.6 mg/L after 11 wk of aging (Spillman et al., 1998). Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996).

Environmental Fate

Biological. In activated sludge inoculum, following a 20-d adaptation period, 97.3% COD removal was achieved. The average rate of biodegradation was 41.0 mg COD/g?h (Pitter, 1976).
Chemical/Physical. Easily resinified by acids (Windholz et al., 1983). Furfuryl alcohol will not hydrolyze because it has no hydrolyzable functional group.
In barrel-aged red, white, and model wines, naturally occurring furfuryl alcohol decreased in concentration with time. In red wine, furfuryl ethyl ether was identified as a degradation product after 55 wk of storage. The average percentage decrease of furfuryl alcohol was 73% (Spillman et al., 1998).

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Metal containers involving the transfer of=gallonsor more of ethyl acetate should be grounded and bonded.Drums must be equipped with self-closing valves, pressurevacuum bungs, and flame arresters. Use only nonsparkingtools and equipment, especially when opening and closingcontainers of ethyl acetate. Store in containers that are properly labeled with health hazard information and safe handling procedures. Wherever ethyl acetate is used, handled,manufactured, or stored, use explosion-proof electricalequipment and fittings. Furfuryl alcohol must be stored toavoid contact with strong oxidizers (such as chlorine, bromine, and fluorine) and any acid, since violent reactionsoccur. Store in tightly closed containers in a cool, well-ventilated area away from heat. Sources of ignition, such assmoking and open flames, are prohibited where furfurylalcohol is used, handled, or stored in a manner that couldcreate a potential fire or explosion hazard. Wherever furfuryl alcohol is used, handled, manufactured, or stored, useexplosion-proof electrical equipment and fittings.

Shipping

UN2874 Furfuryl alcohol, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Distil it under reduced pressure to remove tarry material, shake with aqueous NaHCO3, dry it with Na2SO4 and fractionally distil it under reduced pressure from Na2CO3. It can be further dried by shaking with Linde 5A molecular sieves. [Beilstein 17/3 V 338.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with acids can cause polymerization. Strong reaction with oxidizers. Incompatible with alkaline earth and alkali metals; strong caustics; aliphatic amines; isocyanates, acetaldehyde, benzoyl peroxide; chromic acid, chromium trioxide; cyanoacetic acid; dialkylzincs, dichlorine oxide; ethylene oxide; hydrogen per oxide; isopropyl chlorocarbonate; lithium tetrahydroalumi nate; nitric acid; nitrogen dioxide; pentafluoroguanidine, phosphorus pentasulfide; tangerine oil; triethylaluminum, trii sobutylaluminum. Attacks some plastics, coatings and rubber.

Waste Disposal

Incineration in admixture with a more flammable solvent.

Furfuryl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

Furfuryl acetate 2-Allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one FURFURYL ALCOHOL RESIN CALCIUM LEVULINATE Levulinic acid 2-Methylfuran Ranitidine 3-Hydroxy-2-methyl-4H-pyran-4-one 4-(BROMOMETHYL)-3-NITROBENZOIC ACID Tetrahydrofurfuryl alcohol Ethyl maltol

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View Lastest Price from Furfuryl alcohol manufacturers

Guangzhou PI PI BIOTECH INC

Product: Furosemide Impurity 5
Price: US $0.00-0.00/mg
Min. Order: 10mg
Purity: 90%+
Supply Ability: 10g
Release date: 2020-05-31

Hebei Mojin Biotechnology Co., Ltd

Product: Furfuryl alcohol 98-00-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
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Release date: 2023-08-18

Hebei Guanlang Biotechnology Co,.LTD

Product: 2-(Hydroxymethyl)Furan 98-00-0
Price: US $10.50/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 ton
Release date: 2021-07-01

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Methanol, (2-furyl)-

FURAN-2-METHANOL

FEMA 2491

FA(R)

FURFURYL ALCOHOL 98+%

FurfurylAlcoholForSynthesis

FurfurylAlcohol,>99%

Furfurylalcohol,98%min

TIMTEC-BB SBB004373

RARECHEM AL BD 0007

furfurylalcohol,2-hydroxymethylfuran

Pyr-2-ylmethanol

2-FURYLALCOHOL

FURANMETHANOL

Furfurylalkohol

2-furfurylalkoho

furfralcohol

FURFURYL ALCOHOL WITH GC

(Fur-2-yl)methanol, Furfuryl alcohol

Furfuryl alcohol, 98% 1LT

Furfuryl alcohol, 98% 250ML

NCI-C56224

Qo furfuryl alcohol

ALPHA-FURYLCARBINOL

AKOS BBS-00004319

A-FURYLCARBINOL

2-(HYDROXYMETHYL)FURAN

2-FURYLMETHANOL

2-FURFURYLALCOHOL

2-FURANMETHANOL

2-FURYLCARBINOL

2-FURANCARBINOL

LABOTEST-BB LT01986403

HPFA

FURFURYL ALCOHOL

FURFURAL ALCOHOL

FURFURALCOHOL

2-FurylMethyl Alcohol

CheM-Rez 200