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Tris(2-phenylpyridine)iridium (Ir(ppy)3)

Applications Reactions
Product Name
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
CAS No.
94928-86-6
Chemical Name
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Synonyms
Ir(ppy)3;TRIS(2-PHENYLPYRIDINE)IRIDIUM;fac-Tris(2-phenylpyridine)iridium;sublimed grade;tris[2-(2-pyridyl)phenyl]iridium;TRIS(2-PHENYLPYRIDINE)IRIDIUM (III);Tris[2-phenylpyridinato-C2,N]iridium(III);(ppy)3Ir;Tris(2-phenyL;pyridine)iridium
CBNumber
CB8112370
Molecular Formula
C33H24IrN3
Formula Weight
654.79
MOL File
94928-86-6.mol
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Property

Melting point:
328°C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
yellow
Sensitive 
air sensitive
CAS DataBase Reference
94928-86-6(CAS DataBase Reference)
Absorption
λmax?282, 377 nm?in THF
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
694924
Product name
Tris[2-phenylpyridinato-C2,N]iridium(III)
Purity
sublimed grade
Packaging
250mg
Price
$715
Updated
2024/03/01
Sigma-Aldrich
Product number
688096
Product name
Tris[2-phenylpyridinato-C2,N]iridium(III)
Purity
99%
Packaging
250mg
Price
$402
Updated
2024/03/01
TCI Chemical
Product number
T3716
Product name
Tris(2-phenylpyridinato)iridium(III)
Purity
>98.0%(HPLC)
Packaging
200mg
Price
$250
Updated
2024/03/01
TCI Chemical
Product number
T1946
Product name
Tris(2-phenylpyridinato)iridium(III) (purified by sublimation)
Purity
>95.0%(HPLC)
Packaging
200mg
Price
$533
Updated
2024/03/01
Strem Chemicals
Product number
77-7015
Product name
Tris(2-phenylpyridinato-C2,N)iridium(III), 95%
Packaging
50mg
Price
$64
Updated
2024/03/01
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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties,Usage,Production

Applications

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.

Reactions

  1. Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
  2. Photocatalyst for trifluoromethylation of alkenes and alkynes
  3. Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
  4. Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
  5. Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
  6. Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides

Description

Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.

Chemical Properties

Light yellow to red solid

Uses

suzuki reaction

Uses

Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.

General Description

Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Tris(2-phenylpyridine)iridium (Ir(ppy)3) Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(2-phenylpyridine)iridium (Ir(ppy)3) Suppliers

China 218 Germany 1 India 3 Japan 1 Switzerland 1 United Kingdom 4 United States 17 Global 245
HANSHANG CHEMICAL SCIENTIFIC LIMITED
Tel
021-50521775 15800962688
Fax
86-21-58306291
Email
sales@hanshangchem.com
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China
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Shenzhen Feiming Science and Technology Co.,Ltd.
Tel
0755-85232577
Fax
+86-755-84594577
Email
sale@fmect.com
Country
China
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Beijing Beibaoled Technology Co., Ltd.
Tel
010-60271698; 18001249871
Fax
010-60271698
Email
bjbdoyd@163.com
Country
China
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Panjin Greenchem Technology Co., Ltd.
Tel
13121959385 13121959385
Email
chemrocking@bjgreenchem.com
Country
China
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Shengyang Runze (Beijing) Technology Co.,
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010-010-57302162 17611011830
Email
lyt001@syrz01.com
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China
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169
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Wuhan Zhuojia Technology Co., Ltd
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027-51118240 13476056444
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027-87208412
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sales@zossin.com
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China
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
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jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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View Lastest Price from Tris(2-phenylpyridine)iridium (Ir(ppy)3) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tris(2-phenylpyridine)iridium /Ir(ppy)3 94928-86-6
Price
US $0.00/g
Min. Order
1g
Purity
98%; 99%
Supply Ability
500G
Release date
2021-05-28
Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
Fac-Ir (ppy)3 94928-86-6
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100kgs
Release date
2021-09-16
LY Global chemicals co.,ltd .
Product
Tris(2-phenylpyridine)iridium (Ir(ppy)3) 94928-86-6
Price
US $0.00/kg
Min. Order
1kg
Purity
98.0%min
Supply Ability
100kg
Release date
2023-03-15

94928-86-6, Tris(2-phenylpyridine)iridium (Ir(ppy)3)Related Search:

Iridium Pyridine sulfur trioxide 2-Phenylpyridine TRIPHENYLBORANE Triphenylphosphine BIS-Tris BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) 2,4,6-Collidine Triphenylphosphine oxide Triphenylmethyl Chloride Tricine Tris(hydroxymethyl)aminomethane Thieno[3,2-b]thiophene tris(2-carboxyethyl)phosphine Tris(2-chloroethyl) phosphate tris-(1,10-phenanthroline)ruthenium N,N'- Dibutylquinacridone Coumarin 6

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  • 94928-86-6
  • C30H24IrN3
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  • Electronic Chemicals
  • electronic
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  • Highly Purified Reagents
  • Ir (Iridium) Compounds
  • Other Categories
  • Refined Products by Sublimation
  • Transition Metal Compounds
  • olde Materials
  • oled materials
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
  • OLED
  • 94928-86-6