Tris(2-phenylpyridine)iridium (Ir(ppy)3)
Applications Reactions- Product Name
- Tris(2-phenylpyridine)iridium (Ir(ppy)3)
- CAS No.
- 94928-86-6
- Chemical Name
- Tris(2-phenylpyridine)iridium (Ir(ppy)3)
- Synonyms
- Ir(ppy)3;TRIS(2-PHENYLPYRIDINE)IRIDIUM;fac-Tris(2-phenylpyridine)iridium;sublimed grade;tris[2-(2-pyridyl)phenyl]iridium;TRIS(2-PHENYLPYRIDINE)IRIDIUM (III);Tris[2-phenylpyridinato-C2,N]iridium(III);(ppy)3Ir;Tris(2-phenyL;pyridine)iridium
- CBNumber
- CB8112370
- Molecular Formula
- C33H24IrN3
- Formula Weight
- 654.79
- MOL File
- 94928-86-6.mol
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Property
- Melting point:
- 328°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
- CAS DataBase Reference
- 94928-86-6(CAS DataBase Reference)
- Absorption
- λmax?282, 377 nm?in THF
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 694924
- Product name
- Tris[2-phenylpyridinato-C2,N]iridium(III)
- Purity
- sublimed grade
- Packaging
- 250mg
- Price
- $715
- Updated
- 2024/03/01
- Product number
- 688096
- Product name
- Tris[2-phenylpyridinato-C2,N]iridium(III)
- Purity
- 99%
- Packaging
- 250mg
- Price
- $402
- Updated
- 2024/03/01
- Product number
- T3716
- Product name
- Tris(2-phenylpyridinato)iridium(III)
- Purity
- >98.0%(HPLC)
- Packaging
- 200mg
- Price
- $250
- Updated
- 2024/03/01
- Product number
- T1946
- Product name
- Tris(2-phenylpyridinato)iridium(III) (purified by sublimation)
- Purity
- >95.0%(HPLC)
- Packaging
- 200mg
- Price
- $533
- Updated
- 2024/03/01
- Product number
- 77-7015
- Product name
- Tris(2-phenylpyridinato-C2,N)iridium(III), 95%
- Packaging
- 50mg
- Price
- $64
- Updated
- 2024/03/01
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Chemical Properties,Usage,Production
Applications
Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Utilizing all of its singlet and triplet excitons for the emission, this green light emitting Ir(ppy)3 exhibits a very bright phosphorescence with an internal quantum yield of almost 100%. It is one of the most successful green-triplet emitters in the rapidly developing field of OLED display technology.
Reactions
- Photocatalyst for ?-amino C–H arylation of cyano(hetero)arenes by tertiary amines
- Photocatalyst for trifluoromethylation of alkenes and alkynes
- Photocatalyst for reduction of alkyl, alkenyl, aryl iodides (a) and intramolecular reductive cyclizations (d)
- Photocatalyst for organocatalyst assisted direct arylation of allylic sp3 C–H bonds
- Photocatalyst for the generation multifluorinated biaryls via functionalization of the C−F bond of a perfluoroarene and C−H bond of the other arene in the presence of amines
- Photocatalyst for visible-light photoredox arylation of thiols with various aryl halides
Description
Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
Chemical Properties
Light yellow to red solid
Uses
suzuki reaction
Uses
Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.
General Description
Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Preparation Products And Raw materials
Raw materials
Preparation Products
Tris(2-phenylpyridine)iridium (Ir(ppy)3) Suppliers
View Lastest Price from Tris(2-phenylpyridine)iridium (Ir(ppy)3) manufacturers
- Product
- Fac-Ir (ppy)3 94928-86-6
- Price
- US $0.00/g
- Min. Order
- 1g
- Purity
- 99.90%
- Supply Ability
- 100kgs
- Release date
- 2021-09-16
- Product
- Tris(2-phenylpyridine)iridium /Ir(ppy)3 94928-86-6
- Price
- US $0.00/g
- Min. Order
- 1g
- Purity
- 98%; 99%
- Supply Ability
- 500G
- Release date
- 2021-05-28
- Product
- Tris(2-phenylpyridine)iridium (Ir(ppy)3) 94928-86-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98.0%min
- Supply Ability
- 100kg
- Release date
- 2023-03-15