Zinc trifluoromethanesulfonate

Reaction

Product Name: Zinc trifluoromethanesulfonate
CAS No.: 54010-75-2
Chemical Name: Zinc trifluoromethanesulfonate
Synonyms: Zn(OTf)2;ZINC TRIFLATE;zinc(ii) triflate;trifluoromethanesulphonate;Zinc trifluoromethylsulfonate;Bis(trifluoromethanesulfonato)zinc;Trifluoromethane sulfonic acid zinc;Zinc trifL;Zinc Ditriflate;Zinc trifluoromethylsulfonat
CBNumber: CB8137568
Molecular Formula: C2F6O6S2Zn
Formula Weight: 363.53
MOL File: 54010-75-2.mol

More

Less

Zinc trifluoromethanesulfonate Property

Melting point:: ≥300 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
color: White to light-gray
Water Solubility: Soluble in water and acetonitrile. Slightly soluble in methanol. Insoluble in dichloromethane.
Sensitive: Hygroscopic
BRN: 4028195
Stability:: hygroscopic
InChI: InChI=1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChIKey: CITILBVTAYEWKR-UHFFFAOYSA-L
SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S([O-])(=O)=O.[Zn+2]
CAS DataBase Reference: 54010-75-2(CAS DataBase Reference)
EPA Substance Registry System: Methanesulfonic acid, trifluoro-, zinc salt (54010-75-2)

More

Less

Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 3-10
Hazard Note: Irritant/Hygroscopic
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 29049090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 290068
Product name: Zinc trifluoromethanesulfonate
Purity: 98%
Packaging: 10g
Price: $60
Updated: 2024/03/01

Sigma-Aldrich

Product number: 290068
Product name: Zinc trifluoromethanesulfonate
Purity: 98%
Packaging: 50g
Price: $227
Updated: 2024/03/01

TCI Chemical

Product number: T1294
Product name: Zinc(II) Trifluoromethanesulfonate
Purity: >98.0%(T)
Packaging: 5g
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: T1294
Product name: Zinc(II) Trifluoromethanesulfonate
Purity: >98.0%(T)
Packaging: 25g
Price: $53
Updated: 2024/03/01

Alfa Aesar

Product number: L15969
Product name: Zinc trifluoromethanesulfonate
Purity: 98%
Packaging: 5g
Price: $54.1
Updated: 2024/03/01

More

Less

Zinc trifluoromethanesulfonate Chemical Properties,Usage,Production

Reaction

Catalyst for the addition of acetylenes to carbonyls and nitrones.
Claisen rearrangement.
Catalyst for the enantioselective Henry and Aza-Henry reactions.
Pd-catalyzed hydroalkylation of styrenes with zinc reagents.

Chemical Properties

white to light-grey powder

Uses

Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.

Synthesis

Triflic acid (0.056mol) was added dropwise to a suspension of zinc carbonate (0.02 mol)in dry methanol (20 ml) at room temperature. During the addition, CO2 was evolved. The mixture was stirred at 25°C for 20 minutes and refluxed for 2 h. The clear solution was cooled to 25°C and concentrated under reduced pressure. The resulting white powder was dried at 125°C for 2 h to afford Zinc trifluoromethanesulfonate (Zn(OTf)2 )(98% yield).

Purification Methods

It should be dried at 125o for 2hours at 3mm before use. It is soluble in CH2Cl2 but insoluble in pet ether. [Corey & Shimoji Tetrahedron Lett 24 169 1983.]

Zinc trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Trifluoromethanesulfonic acid Zinc carbonate

Preparation Products

More

Less

Zinc trifluoromethanesulfonate Suppliers

Belgium 4 China 286 France 3 Germany 6 India 12 Japan 6 Russia 1 Switzerland 4 The Netherlands 1 United Kingdom 10 United States 40 Global 373

Acros Organics (Part of Thermo Fisher Scientific )

Tel: --
Fax: --
Email: fo@acros.com
Country: Belgium
ProdList: 3824
Advantage: 58

Alkemi BVBA

Tel: --
Fax: --
Email: nfo@alkemi.be
Country: Belgium
ProdList: 2201
Advantage: 58

TCI EUROPE N.V.

Tel: --
Fax: --
Email: sales@tcieurope.be
Country: Belgium
ProdList: 2200
Advantage: 66

Acros Organics

Tel: --
Fax: --
Email: info@acros.com
Country: Belgium
ProdList: 6772
Advantage: 81

More

Less

View Lastest Price from Zinc trifluoromethanesulfonate manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: ZINC TRIFLUOROMETHANESULFONATE 54010-75-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-25

Hebei Mojin Biotechnology Co.,Ltd

Product: ZINC TRIFLUOROMETHANESULFONATE 54010-75-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-09-02

Hebei Mojin Biotechnology Co., Ltd

Product: ZINC TRIFLUOROMETHANESULFONATE 54010-75-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-12

54010-75-2, Zinc trifluoromethanesulfonateRelated Search:

Trifluoromethanesulfonic acid PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method] Trifluoromethane Lithium bis(trifluoromethanesulphonyl)imide CALCIUM TRIFLUOROMETHANESULFONATE Iron(III) trifluoromethanesulfonate BORON TRIFLUORIDE-PHENOL COMPLEX (1:2) Zinc tetrafluoroborate ZINC TRIFLUOROACETATE TRIBUTYL(1-ETHOXYVINYL)TIN YTTERBIUM(III) TRIFLATE HYDRATE, 99.90% Bis(tributyltin) oxide Sodium trifluoromethanesulfinate TRIFLUOROMETHYL SULFINYL CHLORIDE Silver(I) trifluoromethanethiolate Lanthanum trifluoromethanesulfonate Aluminum trifluoromethanesulfonate YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Zinc Triflate

Zinc trifluoromethylsulfonate

Zn(OTf)2

Bis(trifluoromethanesulfonato)zinc

trifluoro-methanesulfonicacizincsalt

Trifluoromethane sulfonic acid zinc

Zinc trifluoromethanesulfonate, min. 98%

ZINC TRIFLUOROMETHANESULFONATE

ZINC TRIFLUOROMETHANESULPHONATE

ZINC TRIFLATE

TRIFLUOROMETHANESULFONIC ACID ZINC SALT

Zinctrifluoromethanesulfonate,min.98%(Zinctriflate)

Methanesulfonic acid, trifluoro-, zinc salt

trifluoromethanesulfonic acid zinc(ii) salt

zinc(ii) triflate

Zinc trifluoromethanesulphonate 98%

Trifluoromethanesulfonic acid zinc salt, Zinc

Zinctrifluoromethanesulphonate98%

Zinc Trifluoromethanesulfonate Powder

trifluoromethanesulphonate

ZINC TRIFLUOROMETHANESULFONATE, 98%ZINC TRIFLUOROMETHANESULFONATE, 98%ZINC TRIFLUOROMETHANESULFONATE, 98%ZINC TRIFLUOROMETHANESULFONATE, 98%

Bis(trifluoromethanesulfonic acid)zinc salt

Bis(trifluoromethylsulfonyloxy) zinc

Zinc bis(trifluoromethanesulfonate)

Zinc trifluoromethanesulfonate,98%

ZINC TRIFLUOROMETHANESULFONATE (ZINC TRIFLATE)

Zinc Trifluoromethanesulfonate Monohydrate

Trifluoromethanesulfonic acid zinc salt, Zinc triflate

Zinc trifluoromethanesulfonate,Trifluoromethanesulfonic acid zinc salt, Zinc triflate

Zinc trifluoromethanesulfonate ,97.5%

Zinc (II) trifluoromethanesulfonate, 98% (Zinc triflate)

Zinc(II) trifluoromethanesulphonate 98%

Zinc Ditriflate

trifluoroMethanesulfonate zinc

Zinc trifluoroMethanesulfonate, 98% 10GR

Zinc trifluoroMethanesulfonate 98% Zn(CF3SO3)2 F.W.381,40

Zinc trifluoroMethanesulfonate,98% (Zinc triflate) Zn(CF3SO3)2

Trifluoromethanesulfonic Acid Zinc(II) Salt Zinc(II) Triflate

Zinc trifluoroMethanesulfonate 98%

Zinctrifluoro Methene sulfonate

Zinc(II) TrifluoroMethanesulfonate, 98.0%(T)

Zinc(II) Trifluoromethanesulphonate

Zinc trifL

ZINC TRIFLUOROMETHANESULFONATE ISO 9001：2015 REACH

54010-75-2 ZINC TRIFLUOROMETHANESULFONATE

zinc(2+) ditrifluoromethanesulfonate

Zinc trifluoromethylsulfonat

54010-75-2

ZnSO3CF32

CF3SO32Zn

2CF3O3SZn

C2F6O6S2Zn

ZnCF3SO32

CF3O3SZn

Catalysis and Inorganic Chemistry

Zinc

Classes of Metal Compounds

Transition Metal Compounds

Catalysts for Organic Synthesis