ChemicalBook > CAS DataBase List > (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

Reaction

Product Name: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS No.: 138517-61-0
Chemical Name: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms: TROST LIGAND;(1R,2R)-Trost ligand;(1R,2R)-(+)-1,2-TROST LIGAND;1R,2R- DHAC-Phenyl Trost Ligand;(R,R)-DACH-phenyl Trost ligand;(R,R)-DACH-phenyl Trost ligand 95%;(R,R)-DACH-phenyl Trost ligand;(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphos...;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]
CBNumber: CB8153647
Molecular Formula: C44H40N2O2P2
Formula Weight: 690.75
MOL File: 138517-61-0.mol

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Property

Melting point:: 134-136°C
alpha: +130° (c 1.0, methanol)
Boiling point:: 817.0±65.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 13.35±0.40(Predicted)
form: Powder
color: white to off-white
optical activity: [α]20/D +131°, c = 1 in methanol
InChIKey: AXMSEDAJMGFTLR-UHFFFAOYSA-N
SMILES: C1(NC(=O)C2=CC=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)CCCCC1NC(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692808
Product name: (R,R)-DACH-phenyl Trost ligand
Purity: 95%
Packaging: 250MG
Price: $102.2
Updated: 2025/07/31

Sigma-Aldrich

Product number: 692808
Product name: (R,R)-DACH-phenyl Trost ligand
Purity: 95%
Packaging: 1G
Price: $277.5
Updated: 2025/07/31

Strem Chemicals

Product number: 15-0960
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand
Packaging: 100mg
Price: $41
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0960
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand
Packaging: 500mg
Price: $161
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0960
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl Trost Ligand
Packaging: 2g
Price: $495
Updated: 2024/03/01

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties,Usage,Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers

China 99 Germany 2 Norway 1 Switzerland 1 Ukraine 1 United Kingdom 1 United States 4 Global 109

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7471
Advantage: 65

Shanghai Chiral bio-compound co., Ltd.

Tel: 021-5068 3667/17749785980/1029026415; 17749785980
Fax: 021-50683667
Email: 1029026415@qq.com
Country: China
ProdList: 3397
Advantage: 58

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 976
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Innochem(Beijing) Technology Co.,Ltd.

Tel: 010-56541685 13070143590
Fax: 010-56541685
Email: sales@innochem.cn
Country: China
ProdList: 166
Advantage: 57

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 291
Advantage: 62

Tianjin Derchemist Science & Technology Co., Ltd.

Tel: 22-58627059 13920586291
Fax: 022-58620305
Email: zdcomcon@126.com
Country: China
ProdList: 3829
Advantage: 50

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9546
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 67216634
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 271
Advantage: 64

Chongqing Xingcan Pharmaceutical Technology Co., Ltd.

Tel: 023-13650506873 19923294409
Email: xingcanyaoye@sina.com
Country: China
ProdList: 1604
Advantage: 58

Hangzhou J&H Chemical Co., Ltd.

Tel: 0571-87396432
Fax: 0571-87396431
Email: sales@jhechem.com
Country: China
ProdList: 14912
Advantage: 59

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Zhengzhou Changkuan Technology Co., Ltd

Tel: 0371-63769919 18530983798
Fax: 0371-55057218
Email: sales5@changkuantech.com
Country: China
ProdList: 164
Advantage: 55

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 6687
Advantage: 55

Yancheng KangdiSen Pharmaceutical Co., Ltd.

Tel: 13812573443
Fax: -
Email: tongbenwan22@163.com
Country: China
ProdList: 1980
Advantage: 55

Shanghai Xilong Biochemical Technology Co., Ltd.

Tel: 021-52907766-8042
Fax: 021-52906523
Country: China
ProdList: 9941
Advantage: 58

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Chengdu Huachun Technology Co., Ltd

Tel: 400-1166-196 15982826727
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 14603
Advantage: 60

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13305
Advantage: 58

Shanghai Kangman Biological Technology Co., Ltd.

Tel: 18800375331
Fax: 021-50908862
Email: kangmansales@163.com
Country: China
ProdList: 7570
Advantage: 55

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2280
Advantage: 58

Wuxi KaideRui Pharmaceutical Technology Co., Ltd

Tel: 19906241957
Fax: -
Email: 1557216087@qq.com
Country: China
ProdList: 1837
Advantage: 55

Greenherbs Science and Technology Development Co., Ltd.

Tel: 010-61136123
Fax: +86 (10) 8857-9127
Email: pub02@greenherbs.com.cn
Country: China
ProdList: 4049
Advantage: 58

Shanghai BaiShun Biological Technology Co., Ltd

Tel: 021-37581181
Fax: 021-57456066
Email: sales@chem-mall.com
Country: China
ProdList: 10330
Advantage: 58

Shanghai Zhen Li Biological Technology Co., Ltd

Tel: 021-16621358918; 18516310516
Fax: 13045646768
Email: zhenlipharma888@163.com
Country: China
ProdList: 19035
Advantage: 58

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: (5)02557626880
Email: dt3@aikonchem.com
Country: China
ProdList: 15493
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6039 18920764717
Email: sales@heowns.com
Country: China
ProdList: 23771
Advantage: 60

Shanghai Anyinuo Biomedical Technology Co., Ltd.

Tel: 021-34625901 18018851262;
Email: 420970979@qq.com
Country: China
ProdList: 5894
Advantage: 58

Shanghai Hongle Biotechnology Co., Ltd

Tel: 021-56145923; 4001631568
Email: sales@honglebiotech.com
Country: China
ProdList: 920
Advantage: 58

Zhengzhou Alfa Chemical Co.,Ltd

Tel: +8618530059196
Email: sale04@alfachem.cn
Country: China
ProdList: 11811
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

Hefei Hirisun Pharmatech Co., Ltd

Tel: +8615056975894
Fax: 86-0551-62678551
Email: shawn@hirisunpharm.com
Country: CHINA
ProdList: 9911
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 9989
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Chengdu Feibo Pharm Technology Co., Ltd

Tel: +86 028-84641798 15982321820
Email: abby@arkpharm.com
Country: China
ProdList: 10000
Advantage: 58

Shanghai Yanze Chemical Co., Ltd.

Tel: 021-021-13773155751 19975051755
Email: 260924549@qq.com
Country: China
ProdList: 10524
Advantage: 58

Chongqing Chemdad Co., Ltd

Tel: +86-023-6139-8061 +86-86-13650506873
Email: sales@chemdad.com
Country: China
ProdList: 39927
Advantage: 58

Shanghai Jiegu Biotechnology Co., Ltd.

Tel: 021-51698675
Email: sales@jiejiegroup.com
Country: China
ProdList: 8020
Advantage: 58

CONIER CHEM AND PHARMA LIMITED

Tel: +8618523575427
Email: sales@conier.com
Country: China
ProdList: 49975
Advantage: 58

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

Tel: +86-021-61551413 +8618813727289
Email: contact@trustwe.com
Country: China
ProdList: 5743
Advantage: 58

Less

View Lastest Price from (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R,R)-DACH-phenyl Trost ligand 138517-61-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 138517-61-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

138517-61-0, (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)Related Search:

(1R,2R)-(+)-N,N'-DI-P-TOSYL-1,2-CYCLOHEXANEDIAMINE (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-Diphenylphosphinobenzaldehyde Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine N-(2-AMINO-CYCLOHEXYL)-ACETAMIDE TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE (1R,2R)-(-)-1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine

(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl

Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.

N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]

TROST LIGAND

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1R,2R)-(+)-1,2-TROST LIGAND

"N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand"

2-diphenylphosphanyl-n-[(1r,2r)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand

(R,R)-DACH-phenyl Trost ligand

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl

(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane

(R,R)-DACH-phenyl Trost ligand 95%

(1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)

1R,2R- DHAC-Phenyl Trost Ligand

(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand

(1R,2R)-N,N'-1,2-Diaminocyclohexane-bis(2'-diphenylphosphinobenzoyl)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphos...

(1R,2R)-Trost ligand

N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide

(1R,2R)-(+)-1,2-Diaminocyclohexane- N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand

(<i>R</i>,<i>R</i>)-DACH-phenyl Trost ligand

N,N'-((1R,2R)-cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)

(1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) - [C88535]

138517-61-0

C44H40N2O2P2

Chiral Nitrogen

DACH&Trost Series