(S)-(+)-Benzyl glycidyl ether
- Product Name
- (S)-(+)-Benzyl glycidyl ether
- CAS No.
- 16495-13-9
- Chemical Name
- (S)-(+)-Benzyl glycidyl ether
- Synonyms
- (S)-BENZYL GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;BENZYL (S)-(+)-GLYCIDYL ETHER;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
- CBNumber
- CB8164324
- Molecular Formula
- C10H12O2
- Formula Weight
- 164.2
- MOL File
- 16495-13-9.mol
(S)-(+)-Benzyl glycidyl ether Property
- Boiling point:
- 130 °C (0.1 mmHg)
- alpha
- 5.1 º (c=5 in toluene)
- Density
- 1.072 g/mL at 20 °C(lit.)
- refractive index
- n20/D 1.517
- Flash point:
- >110°C
- storage temp.
- 2-8°C
- solubility
- Chloroform, Ethanol
- form
- Oil
- color
- Colourless
- Specific Gravity
- 1.077
- optical activity
- [α]20/D +5.1°, c = 5 in toluene
- BRN
- 5246495
- CAS DataBase Reference
- 16495-13-9(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- RTECS
- TX2860030
- HS Code
- 29109000
- Toxicity
- mic-sat 660 nmol/plate MUREAV 298,197,1993
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 363537
- Product name
- (S)-(+)-Glycidyl benzyl ether
- Purity
- 99%
- Packaging
- 1g
- Price
- $9.64
- Updated
- 2024/03/01
- Product number
- B2239
- Product name
- Benzyl (S)-(+)-Glycidyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $16
- Updated
- 2024/03/01
- Product number
- B2239
- Product name
- Benzyl (S)-(+)-Glycidyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $25
- Updated
- 2024/03/01
- Product number
- L14033
- Product name
- Benzyl (S)-(+)-glycidyl ether, 98+%
- Packaging
- 1g
- Price
- $72.65
- Updated
- 2024/03/01
- Product number
- L14033
- Product name
- Benzyl (S)-(+)-glycidyl ether, 98+%
- Packaging
- 5g
- Price
- $236.65
- Updated
- 2024/03/01
(S)-(+)-Benzyl glycidyl ether Chemical Properties,Usage,Production
Chemical Properties
Colorless to light yellow liqui
Uses
(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.
Uses
(S)-(+)-Glycidyl benzyl ether may be employed for the total asymmetric synthesis of (+)-gigantecin.
General Description
(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.
Safety Profile
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (S)-(+)-Benzyl glycidyl ether manufacturers
- Product
- (S)-(+)-Benzyl glycidyl ether 16495-13-9
- Price
- US $10.70/KG
- Min. Order
- 10KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-21
- Product
- 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE 16495-13-9
- Price
- US $2.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100g , 1kg, 5kg , 50kg
- Release date
- 2020-01-07