(R)-3-Amino-1-benzylpiperidine

Product Name: (R)-3-Amino-1-benzylpiperidine
CAS No.: 168466-84-0
Chemical Name: (R)-3-Amino-1-benzylpiperidine
Synonyms: C-3101R;CAS:168466-84-0;Linagliptin Impurity 89;(R)-1-benzylpiperidin-3-amine;(R)-1-BENZYL-3-AMINOPIPERIDINE;(R)-3-AMINO-1-BENZYL-PIPERIDINE;(r)-n-benzyl-3-amino-piperidine;1-BENZYL-PIPERIDIN-(R)-3-YLAMINE;(R)-1-BENZYL-PIPERIDIN-3-YLAMINE;(3R)-1-(Benzyl)-3-piperidinaMine
CBNumber: CB8175940
Molecular Formula: C12H18N2
Formula Weight: 190.28
MOL File: 168466-84-0.mol

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(R)-3-Amino-1-benzylpiperidine Property

Boiling point:: 281.2±33.0 °C(Predicted)
Density: 1.037±0.06 g/cm3(Predicted)
Flash point:: 113℃
storage temp.: 2-8°C(protect from light)
form: solid
pka: 10.21±0.20(Predicted)
color: Yellow
Water Solubility: Slightly soluble in water.
CAS DataBase Reference: 168466-84-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,T
Risk Statements: 25-36/37/38
Safety Statements: 45-37-26
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: A618623
Product name: (R)-3-Amino-1-benzylpiperidine
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Apolloscientific

Product number: OR15666
Product name: (3R)-1-Benzylpiperidin-3-amine
Packaging: 1g
Price: $40
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H30-1-U6
Product name: (R)-3-Amino-1-benzylpiperidine
Packaging: 1g
Price: $44
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK197623
Product name: (R)-1-Benzyl-3-aminopiperidine
Purity: 98%
Packaging: 1g
Price: $56
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA155125
Product name: (R)-3-Amino-1-benzylpiperidine
Packaging: 500mg
Price: $60
Updated: 2021/12/16

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(R)-3-Amino-1-benzylpiperidine Chemical Properties,Usage,Production

Chemical Properties

White powder or yellow liquid

Uses

(R)-3-Amino-1-benzylpiperidine is used as an organic chemical synthesis intermediate.

Synthesis

168466-80-6

168466-84-0

Example 33: Preparation of (R)-1-benzyl-3-aminopiperidine (R)-1-benzylpiperidinamide (1.1 g) described in Example 2 was used as a starting material, which was mixed with water (5 mL), 30% aqueous sodium hydroxide (6.7 g, 10 eq.), tetrahydrofuran (THF, 10 mL), and an aqueous sodium hypochlorite solution (11.2 g, 1.5 eq.). The reaction mixture was stirred at 15°C for 1 hour, then warmed to 60°C and continued stirring for 2 hours. Upon completion of the reaction, the mixture was cooled to 20 °C and extracted three times with toluene (10 mL). After combining the organic layers, the solvent was removed by concentration under reduced pressure to afford the target product (R)-3-amino-1-benzylpiperidine as a yellow-brown oil (0.8 g, yield: 55%).

References

[1] Patent: US2010/105917, 2010, A1. Location in patent: Page/Page column 21

(R)-3-Amino-1-benzylpiperidine Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3-Amino-1-benzylpiperidine Suppliers

China 118 Germany 1 India 3 United Kingdom 7 United States 19 Global 148

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View Lastest Price from (R)-3-Amino-1-benzylpiperidine manufacturers

Career Henan Chemical Co

Product: (R)-3-Amino-1-benzylpiperidine 168466-84-0
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: JD 375
Release date: 2019-09-01

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(R)-1-BENZYL-3-AMINOPIPERIDINE

1-BENZYL-PIPERIDIN-(R)-3-YLAMINE

C-3101R

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(3R)-1-(Benzyl)-3-piperidinaMine

(r)-n-benzyl-3-amino-piperidine

(R)-1-benzylpiperidin-3-amine

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(R)-1-Benzyl-3-aMinopiperidine, ee: 98%

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(3R)-1-(Phenylmethyl)-3-piperidinamine

(R)-1-Benzyl-3-aminopiperidine, 98%, ee: 98%

(R)-1-benzylpiperidin-3-aMine hydrochloride

(R)-3-Amino-1-benzylpiperidine,97%

3-Piperidinamine, 1-(phenylmethyl)-, (3R)-

Linagliptin Impurity 89

CAS:168466-84-0

(R)-3-Amino-1-benzyl-piperidine, CAS 168466-84-0

168466-84-0

Piperidine