2-Hydroxyethyl acrylate

2-Hydroxyethyl acrylate Property

Melting point:

-60 °C

Boiling point:

90-92 °C12 mm Hg(lit.)

Density 

1.106 g/mL at 20 °C

vapor density 

>1 (vs air)

vapor pressure 

<0.1 mm Hg ( 20 °C)

refractive index 

n20/D 1.45(lit.)

Flash point:

209 °F

storage temp. 

2-8°C

form 

Oily Liquid

pka

13.85±0.10(Predicted)

color 

Yellow to brown

Water Solubility 

soluble

FreezingPoint 

-35

Sensitive 

Light Sensitive

BRN 

969853

Exposure limits

ACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3

InChIKey

OMIGHNLMNHATMP-UHFFFAOYSA-N

LogP

-0.17 at 25℃

CAS DataBase Reference

818-61-1(CAS DataBase Reference)

NIST Chemistry Reference

2-Propenoic acid, 2-hydroxyethyl ester(818-61-1)

EPA Substance Registry System

2-Hydroxyethyl acrylate (818-61-1)

Safety

Hazard Codes 

T,N

Risk Statements 

24-34-43-50-20/22-22

Safety Statements 

26-36/39-45-61-36/37/39

RIDADR 

UN 2927 6.1/PG 2

WGK Germany 

3

RTECS 

AT1750000

F 

8

TSCA 

Yes

HazardClass 

8

PackingGroup 

II

HS Code 

29161290

Hazardous Substances Data

818-61-1(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

2-Hydroxyethyl acrylate Chemical Properties,Usage,Production

Description

2-Hydroxyethyl acrylate (HEA) forms homopolymers and copolymers. HEA is used mainly either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. In the manufacture of polymers, HEA can be co-polymerized with acrylic acid, acrylates, methacrylates, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and the like. Co-reactants with HEA include aromatic and aliphatic isocyanates, anhydrides, and epoxides. The polymers and chemical intermediates made with HEA find applications in automotive top coatings, architectural coatings, photocure resins, and adhesives. Globally about half of the HEA produced is used in the production of acrylic enamels for the automotive industry, where a clear topcoat is applied to a pigmented base coat to increase corrosion protection and durability.

Chemical Properties

Hydroxyethyl acrylate is a clear colorless liquid. miscible with water, soluble in general organic solvents. The commodity generally contains 400ppm of hydroquinone methylether, a polymerization inhibitor. Hydroxyethyl acrylate is a difunctional acrylate monomer with the characteristic high reactivity. Hydroxyethyl acrylate is used in a crylics for coatings, adhesives and UV reacitve oligomers. It can be used for crosslinking with isocyantes or melamines.

Uses

As a reactive monomer 2-Hydroxyethyl acrylate is used as a crosslinking agent for resins, plastics and rubber modifiers. Further, it is used in the synthesis of amphilic block copolymers by nitroxide mediated living radical polymerization. In addition to this, it is used to prepare tuned poly(hydroxyethyl acrylate) by atom transfer radical polymerization.

Uses

2-Hydroxyethyl acrylate is an acrylic monomer for use in UV inks, adhesives, lacquers, artificial nails, etc.

Application

2-Hydroxyethyl acrylate (HEA) is a monomer that is widely used in the field of material synthesis for the production of various types of polymers, such as hydrogels, coatings, adhesives, and thermosets. Its versatility lies in its ability to copolymerize with a variety of monomers, resulting in a wide range of polymer properties and applications. Its main use is in the production of hydrogels, which are highly absorbent and can be used in wound dressings, contact lenses, drug delivery systems, and other biomedical applications. Additionally, 2-hydroxyethyl acrylate-based coatings and adhesives are used in various surface modification and bonding applications, owing to their excellent adhesion, flexibility, and chemical resistance properties.

Definition

ChEBI: 2-Hydroxyethyl acrylate is a functional monomer for the manufacture of thermosetting acrylic resins.

General Description

A clear colorless liquid. Less dense than water. Vapors heavier than air. Corrosive to tissue. Flash point 120°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Used to make plastics.

Air & Water Reactions

Flammable. Slightly soluble in water.

Reactivity Profile

A functional monomer of thermosetting acrylic resins.

Health Hazard

Inhalation causes irritation of nose and throat. Contact with liquid irritates eyes and skin.

Fire Hazard

Behavior in Fire: Containers may explode

Flammability and Explosibility

Non flammable

Potential Exposure

2-Hydroxyethyl acrylate is contained in Lowicryl 4KM and K11M resins. It caused contact dermatitis in workers embedding media for electron microscopy. It may also be contained in ultraviolet-curable nail gel used for photobonded sculptured nails.

Toxics Screening Level

The Initial Threshold Screening Level (ITSL) 2-hydroxyethyl acrylate is 1 μg/m3 with annual averaging time.