ChemicalBook > CAS DataBase List > 2-Bromo-1-(bromomethyl)-4-fluorobenzene

2-Bromo-1-(bromomethyl)-4-fluorobenzene

Product Name
2-Bromo-1-(bromomethyl)-4-fluorobenzene
CAS No.
61150-57-0
Chemical Name
2-Bromo-1-(bromomethyl)-4-fluorobenzene
Synonyms
2-BroMo-1-(broMoMeth;2-Bromo-4-Fluorobenzyl;2-Bromo-4-fluorobenzene;2-BROMO-4-FLUOROBENZYL BROMIDE;2-Bromo-4-fluorobenzylbromide,96%;2-Bromine-4-Fluoride Bromine Benzyl;2-BROMO-1-(BROMOMETHYL)-4-FLUOROBENZENE;Benzene, 2-bromo-1-(bromomethyl)-4-fluoro-;2-Bromo-1-(bromomethyl)-4-fluorobenzene, alpha,2-Dibromo-4-fluorotoluene
CBNumber
CB8190648
Molecular Formula
C7H5Br2F
Formula Weight
267.92
MOL File
61150-57-0.mol
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2-Bromo-1-(bromomethyl)-4-fluorobenzene Property

Boiling point:
254.0±25.0 °C(Predicted)
Density 
1.923±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Solid
Appearance
Off-white to light yellow Crystal
CAS DataBase Reference
61150-57-0(CAS DataBase Reference)
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Safety

RIDADR 
3261
HazardClass 
8
PackingGroup 
Ⅲ
HS Code 
2903998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
B692133
Product name
2-Bromo-4-fluorobenzylbromide
Packaging
1g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
W7343
Product name
2-Bromo-4-fluorobenzylbromid
Packaging
1g
Price
$14
Updated
2021/12/16
Apolloscientific
Product number
PC1236
Product name
2-Bromo-4-fluorobenzylbromide
Packaging
1g
Price
$15
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-B-30
Product name
2-Bromo-4-fluorobenzyl bromide
Packaging
1g
Price
$16
Updated
2021/12/16
Matrix Scientific
Product number
074333
Product name
2-Bromo-4-fluorobenzylbromide
Purity
95+%
Packaging
5g
Price
$24
Updated
2021/12/16
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2-Bromo-1-(bromomethyl)-4-fluorobenzene Chemical Properties,Usage,Production

Chemical Properties

white crystal powde

Synthesis

1422-53-3

61150-57-0

General procedure for the synthesis of 2-bromo-4-fluorobenzyl bromide from 2-bromo-4-fluorotoluene: In a round-bottomed flask equipped with a reflux condenser, 2-bromo-4-fluorotoluene (15 g, 79.3 mmol), N-bromosuccinimide (18.08 g, 101.6 mmol) and 2,2'-azobisisobutyronitrile (3.9 g, 23.8 mmol) were dissolved in carbon tetrachloride (150 mL). The reaction mixture was heated to reflux for 21 hours. After completion of the reaction, the mixture was cooled and the solvent was removed by distillation under reduced pressure. The crude product was suspended in dichloromethane and the organic layer was washed with water. Subsequently, the organic layer was washed with saturated aqueous sodium chloride solution and dried with anhydrous sodium sulfate. After filtration, the solvent was removed by distillation under reduced pressure to obtain the crude product. Purification of the crude product by column chromatography (eluent: 1% hexane solution of ethyl acetate tapered to 10% hexane solution of ethyl acetate) afforded 2-bromo-4-fluorobenzyl bromide as an oily white solid (18.5 g, 87% yield).GC-MS analysis showed m/z 268 [M]+.

References

[1] Synlett, 2011, # 17, p. 2525 - 2528
[2] Patent: WO2008/144223, 2008, A2. Location in patent: Page/Page column 28
[3] Patent: WO2007/70041, 2007, A1. Location in patent: Page/Page column 126
[4] Journal of Medicinal Chemistry, 2003, vol. 46, # 3, p. 409 - 416
[5] Collection of Czechoslovak Chemical Communications, 1999, vol. 64, # 4, p. 649 - 672

2-Bromo-1-(bromomethyl)-4-fluorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-1-(bromomethyl)-4-fluorobenzene Suppliers

China 129 Europe 2 Germany 1 India 3 Italy 1 Ukraine 1 United Kingdom 9 United States 18 Global 164
Accela ChemBio Inc.
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View Lastest Price from 2-Bromo-1-(bromomethyl)-4-fluorobenzene manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
2-Bromo-1-(bromomethyl)-4-fluorobenzene 61150-57-0
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-11
Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
2-Bromo-4-fluorobenzylbromide 61150-57-0
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-11
Shaanxi Dideu Medichem Co. Ltd
Product
2-Bromo-1-(bromomethyl)-4-fluorobenzene 61150-57-0
Price
US $0.00-0.00/KG
Min. Order
10mg
Purity
99%
Supply Ability
2000tons
Release date
2020-01-16

61150-57-0, 2-Bromo-1-(bromomethyl)-4-fluorobenzeneRelated Search:

alpha-Chloro-o-fluorotoluene BRETYLIUM TOSYLATE Ethyl bromodifluoroacetate [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-pro p-1-enyl-cyclopropane-1-carboxylate 4-Fluorobenzyl chloride 2-Bromo-4-fluorotoluene 3-Fluorobenzyl bromide BROMOTRIFLUOROMETHANE 4-Fluorobenzyl bromide Fluorobenzene 1-Bromo-2-(bromomethyl)-4-fluorobenzene Bromine 1-Bromo-4-bromomethyl-3-fluorobenzene 1-Bromo-3-bromomethyl-2-fluorobenzene TETRABROMO-4-FLUORO-O-XYLENE 2-Bromo-1-(bromomethyl)-4-fluorobenzene 3-bromo-4-fluorobenzyl bromide 1-bromo-4-(bromomethyl)-2-fluorobenzene

  • 2-BROMO-4-FLUOROBENZYL BROMIDE
  • 2-BROMO-1-(BROMOMETHYL)-4-FLUOROBENZENE
  • 2-Bromo-4-Fluorobenzyl
  • 2-BroMo-1-(broMoMeth
  • 2-Bromo-1-(bromomethyl)-4-fluorobenzene, alpha,2-Dibromo-4-fluorotoluene
  • Benzene, 2-bromo-1-(bromomethyl)-4-fluoro-
  • 2-Bromine-4-Fluoride Bromine Benzyl
  • 2-Bromo-4-fluorobenzylbromide,96%
  • 2-Bromo-4-fluorobenzene
  • 61150-57-0
  • C7H5Br2F
  • Fluorine series
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • alkyl bromide| alkyl Fluorine