ChemicalBook > CAS DataBase List > Trifluoromethylthiobenzene

Trifluoromethylthiobenzene

Product Name
Trifluoromethylthiobenzene
CAS No.
456-56-4
Chemical Name
Trifluoromethylthiobenzene
Synonyms
(TRIFLUOROMETHYLTHIO)BENZENE;PHENYL TRIFLUOROMETHYL SULFIDE;TRIFLUOROMETHYL PHENYL SULFIDE;Phenyl(trifluoromethyl)sulfane;PHENYL TRIFLUOROMETHYL SULPHIDE;PhenylTrifluoromethylSulfide>Trifluoromethyl Phenyl Sulpuide;Phenyltrifluoromethylsulphide98%;Trifluoromethyl phenyl thioether;Benzene, [(trifluoromethyl)thio]-
CBNumber
CB8257169
Molecular Formula
C7H5F3S
Formula Weight
178.17
MOL File
456-56-4.mol
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Trifluoromethylthiobenzene Property

Boiling point:
142 °C (lit.)
Density 
1.249 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.466(lit.)
Flash point:
100 °F
form 
clear liquid
color 
Colorless to Almost colorless
Sensitive 
Stench
BRN 
2043134
CAS DataBase Reference
456-56-4(CAS DataBase Reference)
NIST Chemistry Reference
Phenyl trifluoromethyl sulfide(456-56-4)
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Safety

Hazard Codes 
T
Risk Statements 
10-36/37/38
Safety Statements 
16-36-36/37/39-23
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
Hazard Note 
Toxic/Stench
HazardClass 
3
PackingGroup 
III
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
P1693
Product name
Phenyl Trifluoromethyl Sulfide
Purity
>97.0%(GC)
Packaging
5g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
P1693
Product name
Phenyl Trifluoromethyl Sulfide
Purity
>97.0%(GC)
Packaging
25g
Price
$184
Updated
2024/03/01
Alfa Aesar
Product number
L10114
Product name
Phenyl trifluoromethyl sulfide, 98%
Packaging
1g
Price
$24.65
Updated
2024/03/01
Alfa Aesar
Product number
L10114
Product name
Phenyl trifluoromethyl sulfide, 98%
Packaging
5g
Price
$66.65
Updated
2024/03/01
TRC
Product number
P399545
Product name
Phenyl Trifluoromethyl Sulfide
Packaging
500mg
Price
$75
Updated
2021/12/16
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Trifluoromethylthiobenzene Chemical Properties,Usage,Production

Uses

Phenyl trifluoromethyl sulfide may be used in the preparation of:

  • sulfoxides, dithiane dioxide, and dithiolane dioxide via iron-catalyzed oxidation of sulfides, dithiane, or dithiolane with hydrogen peroxide
  • benzophenone hydrazone derivatives
  • trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes

Synthesis Reference(s)

The Journal of Organic Chemistry, 50, p. 4047, 1985 DOI: 10.1021/jo00221a017
Synthesis, p. 721, 1975 DOI: 10.1055/s-1975-23905

General Description

Phenyl trifluoromethyl sulfide (PTFMS) is an aryl trifluoromethyl sulfide. PTFMS with (triethylgermyl)sodium forms a reagent system that has been employed for the trifluoromethylation of certain imines. The reaction between OH radical and PTFMS has been analyzed using pulse radiolysis technique and quantum chemical calculations.

Trifluoromethylthiobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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Trifluoromethylthiobenzene Suppliers

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View Lastest Price from Trifluoromethylthiobenzene manufacturers

Career Henan Chemical Co
Product
Trifluoromethylthiobenzene 456-56-4
Price
US $3.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
200KG
Release date
2020-01-07

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