ChemicalBook > CAS DataBase List > 4-Acetylphenylboronic acid

4-Acetylphenylboronic acid

Product Name
4-Acetylphenylboronic acid
CAS No.
149104-90-5
Chemical Name
4-Acetylphenylboronic acid
Synonyms
AKOS BRN-0001;TIMTEC-BB SBB000146;RARECHEM AH PB 0162;4-Boronoacetophenone;4-Acetylphenylboroni;4-Acetylphenylboronic;Acetylphenylboronic acid;4-Acetylphenylboronicaci;4-ACETYLPHENYLBORONIC ACID;P-ACETYLPHENYLBORONIC ACID
CBNumber
CB8260446
Molecular Formula
C8H9BO3
Formula Weight
163.97
MOL File
149104-90-5.mol
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4-Acetylphenylboronic acid Property

Melting point:
240-244 °C(lit.)
Boiling point:
354.2±44.0 °C(Predicted)
Density 
1.19±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Crystalline Powder
pka
7.58±0.10(Predicted)
color 
Pale yellow to yellow
Water Solubility 
25 g/L
BRN 
7869162
CAS DataBase Reference
149104-90-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant/Keep Cold
HazardClass 
IRRITANT
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
470821
Product name
4-Acetylphenylboronic acid
Purity
95%
Packaging
5g
Price
$64.5
Updated
2024/03/01
Sigma-Aldrich
Product number
470821
Product name
4-Acetylphenylboronic acid
Purity
95%
Packaging
25g
Price
$301
Updated
2024/03/01
TCI Chemical
Product number
A1907
Product name
4-Acetylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
A1907
Product name
4-Acetylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$53
Updated
2024/03/01
Alfa Aesar
Product number
B23234
Product name
4-Acetylbenzeneboronic acid, 98%
Packaging
1g
Price
$22.65
Updated
2024/03/01
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4-Acetylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

suzuki reaction

Uses

Reactant involved in:

  • Palladium-catalyzed decarboxylative coupling
  • Copper-catalyzed hydroxylation
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling
  • Cross-coupling with α-bromocarbonyl compounds
  • Oxidation catalyzed by Baeyer-Villiger monooxygenases
  • 1,5-substitution reactions

Uses

4-Acetylphenylboronic acid4-Acetylphenylboronic Acid is used in several metal catalyzed cross-coupling reaction studies.

General Description

4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.

4-Acetylphenylboronic acid Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid 4'-Bromoacetophenone Triethyl orthoformate Tetrahydrofuran Triisopropyl borate n-Butyllithium

Preparation Products

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View Lastest Price from 4-Acetylphenylboronic acid manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Acetylphenylboronic acid 149104-90-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Acetylphenylboronic acid 149104-90-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
4-Acetylphenylboronic acid 149104-90-5
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10MT
Release date
2018-12-17

149104-90-5, 4-Acetylphenylboronic acidRelated Search:

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  • 149104-90-5
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  • BORONIC ACID
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  • Aryl
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  • B (Classes of Boron Compounds)
  • Boronate Ester
  • Potassium Trifluoroborate
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