ChemicalBook > CAS DataBase List > 5-Fluoro-2-methylaniline

5-Fluoro-2-methylaniline

Product Name
5-Fluoro-2-methylaniline
CAS No.
367-29-3
Chemical Name
5-Fluoro-2-methylaniline
Synonyms
2-AMINO-4-FLUOROTOLUENE;2-METHYL-5-FLUOROANILINE;2-Amino-4-fluorotoluene~5-Fluoro-o-toluidine;TIMTEC-BB SBB004266;5-Fluoro-2-methylani;5-Fluoro-2-toluidine;Fluoromethylaniline7;5-FLUORO-O-TOLUIDINE;4-Fluoro-2-Aminotoluene;5-FLUORO-2-METHYLANILINE
CBNumber
CB8263018
Molecular Formula
C7H8FN
Formula Weight
125.14
MOL File
367-29-3.mol
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5-Fluoro-2-methylaniline Property

Melting point:
38-40 °C (lit.)
Boiling point:
98-100°C 15mm
Density 
1.13 g/cm3 (20℃)
refractive index 
1.538
Flash point:
194 °F
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
form 
Crystalline Solid or Liquid
pka
3.44±0.10(Predicted)
color 
Purple to brown
Water Solubility 
insoluble
BRN 
2637584
InChI
InChI=1S/C7H8FN/c1-5-2-3-6(8)4-7(5)9/h2-4H,9H2,1H3
InChIKey
JLCDTNNLXUMYFQ-UHFFFAOYSA-N
SMILES
C1(N)=CC(F)=CC=C1C
CAS DataBase Reference
367-29-3(CAS DataBase Reference)
NIST Chemistry Reference
5-Fluoro-2-methylaniline(367-29-3)
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Safety

Hazard Codes 
Xn,T,Xi
Risk Statements 
20/21/22-36/37/38-23/24/25
Safety Statements 
26-27-36/37/39-45-36
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
Hazard Note 
Toxic/Irritant
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214300
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
F10402
Product name
5-Fluoro-2-methylaniline
Purity
99%
Packaging
10g
Price
$31.8
Updated
2023/01/07
TCI Chemical
Product number
F0232
Product name
5-Fluoro-2-methylaniline
Purity
>98.0%(GC)
Packaging
5g
Price
$27
Updated
2024/03/01
TCI Chemical
Product number
F0232
Product name
5-Fluoro-2-methylaniline
Purity
>98.0%(GC)
Packaging
25g
Price
$78
Updated
2024/03/01
Alfa Aesar
Product number
B25381
Product name
5-Fluoro-2-methylaniline, 98%
Packaging
10g
Price
$42.65
Updated
2024/03/01
Alfa Aesar
Product number
B25381
Product name
5-Fluoro-2-methylaniline, 98%
Packaging
50g
Price
$141.65
Updated
2024/03/01
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5-Fluoro-2-methylaniline Chemical Properties,Usage,Production

Chemical Properties

purple to brown crystalline solid

Uses

Used as a pharmaceutical intermediate in organic synthesis.

Synthesis

In a nitrogen-fed glovebox, Pd(P(o-tol)3)2 and CyPF-PtBu (1:1 ratio) were dissolved in dioxane and mixed for 5 min. A 20 mL scintation vial was charged with aryl halide (0.60 mmol, 1 equiv), ammonium sulfate (0.90 mmol, 1.5 equiv), and sodium tert-butoxide (2.7 mmol, 4.5 equiv). To this vial was added 6 mL of anhydrous dioxane and the appropriate amount of catalyst from the stock solution. The reaction vial was sealed with a Teflon-lined screw cap and removed from the glovebox. The reaction was stirred at the desired temperature for 12 h. The reaction mixture was diluted with EtOAc and filtered through a pad of Celite. The filtrate was concentrated in vacuo, and the crude product was purified by flash column chromatography. 5-Fluoro-2-methylaniline (Table 3, 2s) (CAS: 367-29-3) The reaction to form this product was conducted with 0.5 mol % Pd(P(o-tol)3)2 and 0.5 mol % CyPF-PtBu for 8 h. The crude product was isolated by flash column chromatography (5:1 Hexanes:EtOAc). 5-Fluoro-2-methylaniline was isolated as an oil in 76% yield. 1(600 MHz, CDCl3): δ 6.97 (t, J= 7.2 Hz, 1H), 6.40 (t, J= 9.9 Hz, 2H), 3.69 (s, 2H), 2.12 (s, 3H). 13C-NMR(151 MHz, CDCl3): δ 162.24 (d, JC-F= 240.9 Hz), 145.82 (d, JC-F= 10.6 Hz), 131.12 (d, JC-F= 9.6 Hz), 117.62 (d, JC-F = 2.6 Hz), 104.67 (d, JC-F= 21.0 Hz), 101.56 (d, JC-F= 24.6 Hz), 16.62 (s).

5-Fluoro-2-methylaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Fluoro-2-methylaniline Suppliers

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View Lastest Price from 5-Fluoro-2-methylaniline manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
5-Fluoro-2-methylaniline 367-29-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20t
Release date
2024-06-18
Henan Aochuang Chemical Co.,Ltd.
Product
5-Fluoro-2-methylaniline 367-29-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-27
Honest Joy Holdings Limited
Product
5-Fluoro-2-methylaniline 367-29-3
Price
US $0.00/KG
Min. Order
1KG
Purity
97.4%
Supply Ability
100 tons
Release date
2022-02-18

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