PROPYL FORMATE

ChemicalBook > CAS DataBase List > PROPYL FORMATE

Product Name: PROPYL FORMATE
CAS No.: 110-74-7
Chemical Name: PROPYL FORMATE
Synonyms: N-PROPYL FORMATE;PROPYL METHANOATE;FEMA 2943;HCOOCH2CH2CH3;propylformates;Propylformiate;PROPYL FORMATE;1-propylformate;PropylFormate>formiatedepropyle
CBNumber: CB8330633
Molecular Formula: C4H8O2
Formula Weight: 88.11
MOL File: 110-74-7.mol

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PROPYL FORMATE Property

Melting point:: -93 °C (lit.)
Boiling point:: 80-81 °C (lit.)
Density: 0.904 g/mL at 25 °C (lit.)
vapor density: 3.03 (vs air)
vapor pressure: 100 mm Hg ( 29.5 °C)
refractive index: n20/D 1.375(lit.)
FEMA: 2943 | PROPYL FORMATE
Flash point:: 25 °F
storage temp.: Flammables area
solubility: water: soluble45 part(lit.)
form: clear liquid
color: Colorless to Almost colorless
Odor: at 10.00 % in dipropylene glycol. sweet ethereal green rum fruity berry
Odor Type: ethereal
explosive limit: 2.4-7.8%(V)
Odor Threshold: 0.96ppm
Water Solubility: 22g/L(22 ºC)
JECFA Number: 117
Merck: 14,7858
BRN: 1739272
Dielectric constant: 7.7199999999999998
Dielectric constant: 7.7（19℃）
LogP: 0.83
CAS DataBase Reference: 110-74-7(CAS DataBase Reference)
EPA Substance Registry System: Formic acid, propyl ester (110-74-7)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37-67
Safety Statements: 9-16-24-33
RIDADR: UN 1281 3/PG 2
WGK Germany: 1
RTECS: LR0175000
Autoignition Temperature: 851 °F
TSCA: Yes
HS Code: 2915.13.5000
HazardClass: 3
PackingGroup: II
Toxicity: LD50 orally in rats: 3980 mg/kg, P. M. Jenner et al., Food Cosmet. Toxicol. 2, 327 (1964)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W294306
Product name: Propyl formate
Purity: ≥97%
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W294306
Product name: Propyl formate
Purity: ≥97%
Packaging: 4kg
Price: $573
Updated: 2024/03/01

Sigma-Aldrich

Product number: 245852
Product name: Propyl formate
Purity: 97%
Packaging: 100ml
Price: $66.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: W294306
Product name: Propyl formate
Purity: ≥97%
Packaging: 1kg
Price: $83.6
Updated: 2023/01/07

TCI Chemical

Product number: F0058
Product name: Propyl Formate
Purity: >95.0%(GC)
Packaging: 25mL
Price: $27
Updated: 2024/03/01

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PROPYL FORMATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLORLESS LIQUID

Chemical Properties

Propyl formate has a characteristic fruity (rum–plum) odor and a corresponding bittersweet flavor.

Occurrence

Reported found in plum, brandy, apple, black currant, and pineapple.

Uses

Propyl formate was used in the synthesis of the radicals - CH₃CH₂CHOCHO, CH₃CHCH₂OCHO, and CH₂CH₂CH₂OCHO by TiCl₃.H₂O₂ radical-generating method.

Uses

Flavoring.

Definition

ChEBI: Propyl formate is a carboxylic ester.

Preparation

By action of sulfuric acid on a mixture of propyl alcohol, formic acid and sodium formate; also by distilling propyl alcohol with anhydrous formic acid in the presence of sodium formate.

Taste threshold values

Taste characteristics at 50 ppm: fruity, green and ethereal with a berry lift.

General Description

A clear colorless liquid with a pleasant odor. Flash point 27°F. Slightly soluble in water and less dense than water. Hence floats on water. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

PROPYL FORMATES are esters. React with acids to liberate heat along with propanols and formic acid. Strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.

Hazard

Flammable, dangerous fire risk.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Moderately toxic by ingestion. An irritant to skin, eyes, and mucous membranes. Narcotic in high concentration. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Ignites on contact with potassium-tert-butoxide. Explosive in the form of vapor when exposed to heat or flame. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Purification Methods

Distil the formate, then wash it with saturated aqueous NaCl, and with saturated aqueous NaHCO3 in the presence of solid NaCl, dry it with MgSO4 and fractionally distil it. [Beilstein 2 IV 26.]

PROPYL FORMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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PROPYL FORMATE Suppliers

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110-74-7, PROPYL FORMATERelated Search:

Propyl gallate Octyl gallate Perfluoropropionic anhydride Butyl chloroformate (-)-CARVYL PROPIONATE 2-Ethylhexyl chloroformate 4-Chlorobutyl acetate FEMA 2348 4-Bromobutyl acetate Dibenzoyltartaric acid 16-methyl-20-oxopregna-5,16-dien-3-beta-yl acetate CHLOROFORMIC ACID N-OCTYL ESTER (-)-DIHYDROCARVYL ACETATE ε-Caprolactone 3-Chloropropyl acetate Propyl chloroformate Cortisone acetate Butyl formate

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110-74-7

HCO2CH2CH2CH3

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C2 to C5

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