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1-METHYLPHENANTHRENE

Product Name
1-METHYLPHENANTHRENE
CAS No.
832-69-9
Chemical Name
1-METHYLPHENANTHRENE
Synonyms
NSC 146583;1-methyl-phenanthren;1-METHYLPHENANTHRENE;PHENANTHRENE,1-METHYL-;1-Methylphenanthrene 100mg [832-69-9];1-MethylphenanthreneSolution,50mg/L,1ml;1-Methylphenanthrene @50 μg/mL in Toluene;1-MethylphenanthreneSolution,5,000mg/L,1ml;1-MethylphenanthreneSolution,2,000mg/L,1ml
CBNumber
CB8339474
Molecular Formula
C15H12
Formula Weight
192.26
MOL File
832-69-9.mol
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1-METHYLPHENANTHRENE Property

Melting point:
123°C
Boiling point:
353.25°C (rough estimate)
Density 
1.0561 (estimate)
refractive index 
1.6031 (estimate)
storage temp. 
Room Temperature
solubility 
Soluble in alcohol (Weast, 1986)
form 
Solid
color 
White powder or solid.
Water Solubility 
269ug/L(25 ºC)
Henry's Law Constant
1.56, 2.33, 3.42, 4.93, and 6.68 x 10-5 atm?m3/mol at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998)
IARC
3 (Vol. Sup 7, 92) 2010
EPA Substance Registry System
1-Methylphenanthrene (832-69-9)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P281Use personal protective equipment as required.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

P330Rinse mouth.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
M325415
Product name
1-Methylphenanthrene
Packaging
50mg
Price
$185
Updated
2021/12/16
TRC
Product number
M325415
Product name
1-Methylphenanthrene
Packaging
500mg
Price
$1455
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0238012
Product name
1-METHYLPHENANTHRENE
Purity
98.00%
Packaging
25G
Price
$2021.25
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
52320
Product name
1-Methylphenanthrene
Packaging
500mg
Price
$2200
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0238012
Product name
1-METHYLPHENANTHRENE
Purity
98.00%
Packaging
1G
Price
$1212.75
Updated
2021/12/16
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1-METHYLPHENANTHRENE Chemical Properties,Usage,Production

Uses

1-Methylphenanthrene is a polycyclic aromatic hydrocarbon that has been found in particulate matter from small-scale biomass combustion from old and modern technologies and that has caused acute systemic and lung inflammation in mice after intratracheal aspiration.

Definition

ChEBI: A member of the class of phenanthrenes that is phenanthrene substituted by a methyl group at position 1.

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 2009, 1980 DOI: 10.1021/jo01298a054
Tetrahedron Letters, 6, p. 359, 1965

General Description

White crystalline powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1-METHYLPHENANTHRENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction. 1-METHYLPHENANTHRENE is sensitive to excessive heat and light.

Fire Hazard

Flash point data for 1-METHYLPHENANTHRENE are not available. 1-METHYLPHENANTHRENE is probably combustible.

Source

Detected in 8 diesel fuels at concentrations ranging from 0.10 to 210 mg/L with a mean value of 44.33 mg/L (Westerholm and Li, 1994). Identified in a South Louisiana crude oil at a concentration of 111 ppm (Pancirov and Brown, 1975). Schauer et al. (1999) reported 1- methylphenanthrene in diesel fuel at a concentration of 28 μg/g and in a diesel-powered mediumduty truck exhaust at an emission rate of 17.0 μg/km.
California Phase II reformulated gasoline contained 1-methylphenathrene at a concentration of 3.91 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were approximately 1.63 and 122 μg/km, respectively (Schauer et al., 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase and particle-phase emission rates of 1-methylphenanthrene were 2.22 and 0.579 mg/kg of pine burned and 1.04 and 0.050 mg/kg of oak burned. The gas-phase emission rate was 0.720 mg/kg of eucalyptus burned.

1-METHYLPHENANTHRENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-METHYLPHENANTHRENE Suppliers

Canada 1 China 16 France 1 Germany 2 Japan 1 Norway 1 The Netherlands 1 United Kingdom 3 United States 9 Global 35
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
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China
ProdList
9664
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Hangzhou Sage Chemical Co., Ltd.
Tel
+86057186818502 13588463833
Fax
Pls mail us for more information!
Email
info@sagechem.com
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China
ProdList
10269
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Shanghai BeiZhuo Biotech Co., Ltd.
Tel
021-61119791,13386096464
Fax
021-50190009
Email
bzswkf@foxmail.com
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China
ProdList
3924
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50
Beijing YiboYuntian Technology Co., Ltd.
Tel
13811826434
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lichen13811826434@126.com
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China
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534
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Sichuan BaiPeng Biotechnology Co., Ltd.
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028-65791793 18140026355
Fax
QQ568470422
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568470422@qq.com
Country
China
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9320
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
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+86-400-002-6226 13028896684
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sales@rrkchem.com
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China
ProdList
55827
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Amel Pharmatech Corporation
Tel
888-4366503
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888-502-1736
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sales@amelpharmatech.com
Country
China
ProdList
5351
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58
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing@energy-chemical.com
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China
ProdList
44941
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58
TCI (Shanghai) Chemical Trading Co., Ltd.
Tel
021-61109150
Fax
021-61105897
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sales@tcisct.com
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China
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31163
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58

832-69-9, 1-METHYLPHENANTHRENERelated Search:

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  • 1-METHYLPHENANTHRENE
  • 1-methyl-phenanthren
  • PHENANTHRENE,1-METHYL-
  • 1-Methylphenanthrene 100mg [832-69-9]
  • NSC 146583
  • 1-MethylphenanthreneSolution,2,000mg/L,1ml
  • 1-Methylphenanthrene @50 μg/mL in Toluene
  • 1-MethylphenanthreneSolution,5,000mg/L,1ml
  • 1-MethylphenanthreneSolution,50mg/L,1ml
  • 832-69-9
  • CH3C14H9