(R)-DM-BINAP

Reaction

Product Name: (R)-DM-BINAP
CAS No.: 137219-86-4
Chemical Name: (R)-DM-BINAP
Synonyms: Xylbinap;(R)-(+)-XyL;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
CBNumber: CB8381549
Molecular Formula: C52H48P2
Formula Weight: 734.89
MOL File: 137219-86-4.mol

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(R)-DM-BINAP Property

Melting point:: 203-206°C
Boiling point:: 825.3±65.0 °C(Predicted)
alpha: 169 º (c=1 in chloroform)
storage temp.: Inert atmosphere,Room Temperature
Water Solubility: Insoluble in water
form: crystal
color: white to pale yellow
optical activity: [α]20/D +169°, c = 1 in chloroform

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-37
WGK Germany: 3
TSCA: No
HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692379
Product name: (R)-DM-BINAP
Packaging: 100mg
Price: $78.7
Updated: 2024/03/01

TCI Chemical

Product number: X0070
Product name: (R)-(+)-XylBINAP
Purity: >97.0%(HPLC)
Packaging: 200mg
Price: $60
Updated: 2024/03/01

TCI Chemical

Product number: X0070
Product name: (R)-(+)-XylBINAP
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $203
Updated: 2024/03/01

Alfa Aesar

Product number: H27680
Product name: (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging: 500mg
Price: $214
Updated: 2021/12/16

Alfa Aesar

Product number: H27680
Product name: (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging: 100mg
Price: $72.4
Updated: 2021/12/16

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(R)-DM-BINAP Chemical Properties,Usage,Production

Reaction

Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
Ligand used in the enantioselective fluorination of oxindoles.
Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
Asymmetric hydroboration of unsaturated imines.

Uses

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-DM-BINAP Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-DM-BINAP Suppliers

China 102 Germany 3 India 4 Japan 2 Norway 1 Russia 1 Switzerland 1 United Kingdom 1 United States 18 Global 133

HBCChem, Inc.

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View Lastest Price from (R)-DM-BINAP manufacturers

Chemwill Asia Co.,Ltd.

Product: (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 137219-86-4
Price: US $6.00/kg
Min. Order: 1kg
Purity: High quality Professional Factory
Supply Ability: Ms Ella chemwill_asia@126.com www.chemwill.com
Release date: 2019-04-04

Career Henan Chemical Co

Product: (R)-DM-BINAP 137219-86-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 100KG
Release date: 2019-08-29

137219-86-4, (R)-DM-BINAPRelated Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-(+)-TolBINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN] (R)-3,5-XYLYL-BINAP (S)-Ru(OAc)2(DM-BINAP) (S)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-Ru(OAc)2(DM-BINAP) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] (R)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]

(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL

(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL

RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL

RAC-XYLYL-BINAP

(R)-3,5-XYLYL-BINAP

(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP

(R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl

(R)-3,5-Xyl-BINAP

(R)-DM-BINAP

Xylbinap

(r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy

PHOSPHINE, 1,1''-[(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-

(R)-(+)-2,2μ-Bis[di(3,5-xylyl)phosphino]-1,1μ-binaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine]

2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL

2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL

(R)-(+)-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (R)-3,5-XYLYL-BINAP

(R)-Xylyl-BINAP

1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-Phosphine

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP

(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, 98%((R)-Xylyl-BINAP)

98% (R)-XylBINAP

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%

(R)-(+)-XylBINAP

(R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP

(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP)

(R)-(+)-XyL

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap

(r)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap

137219-86-4

BINAP Series

Chiral Phosphine