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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

Product Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
CAS No.
59159-39-6
Chemical Name
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
Synonyms
(2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide;NSC 82468;carbo-tert-butoxymethyl triphenylphosp;59159-39-6;(Boc-methyl)triphenylphosphonium Bromide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide;tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CBNumber
CB8388977
Molecular Formula
C24H26BrO2P
Formula Weight
457.34
MOL File
59159-39-6.mol
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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Property

Melting point:
178 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Almost white
BRN 
4631405
CAS DataBase Reference
59159-39-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
50g
Price
$153
Updated
2024/03/01
Sigma-Aldrich
Product number
369047
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
10g
Price
$75.6
Updated
2023/06/20
TCI Chemical
Product number
B3928
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$108
Updated
2024/03/01
Alfa Aesar
Product number
L15165
Product name
(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98%
Packaging
5g
Price
$36.8
Updated
2021/12/16
TRC
Product number
B657120
Product name
(Boc-methyl)triphenylphosphoniumBromide
Packaging
500mg
Price
$60
Updated
2021/12/16
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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Chemical Properties,Usage,Production

Uses

Reactant for:

  • Rhodium-catalyzed asymmetric hydrogenation reactions
  • Wittig reaction
  • Wittig methylenation
  • Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
  • Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
  • Wittig chain extension reactions

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Suppliers

Americas 1 Canada 1 China 78 Europe 1 France 2 Germany 2 India 5 Japan 1 Slovakia 1 Switzerland 3 The Netherlands 1 United Kingdom 7 United States 11 Global 114
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
（Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
（Tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Career Henan Chemical Co
Product
(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide 59159-39-6
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-09

59159-39-6, (tert-Butoxycarbonylmethyl)triphenylphosphanium bromideRelated Search:

Ethidium bromide tert-Butanol Tetrabutylammonium bromide Rocuronium bromide Allyl bromide Sodium bromate Sodium bromide Tetrabutyl titanate Chlorodimethylphenylsilane Methylmagnesium Bromide Potassium bromide Methyl bromide Methyltriphenylphosphonium bromide (2-HYDROXYETHYL)TRIPHENYLPHOSPHONIUM BROMIDE (Carbomethoxymethyl)triphenylphosphonium bromide (Carbethoxymethyl)triphenylphosphonium bromide CARBOXYMETHYL DIPHENYLPHOSPHINE OXIDE (ETHOXYCARBONYLMETHYL)DIPHENYLPHOSPHINE

  • [2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphonium bromide
  • tert-Butoxycarbonylmethyltriphenylphosphoniumbrom
  • (tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide
  • (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • carbo-tert-butoxymethyl triphenylphosphonium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %
  • carbo-tert-butoxymethyl triphenylphosp
  • triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide
  • T-butoxycarbonylMethyltriphenylphosphoniuMbroMide
  • NSC 82468
  • (2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98%
  • tert-Butoxycarbonylmethyl triphenylphosphonium bromide,97%
  • Phosphonium,[2-(1,1-dimethylethoxy)-2-oxoethyl]triphenyl-, bromide (1:1)
  • (tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide &gt
  • (iterti-Butoxycarbonylmethyl)triphenylphosphoniumBromide
  • (Boc-methyl)triphenylphosphonium Bromide
  • [2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium
  • <font color="#ff0000">59159-39-6</font>
  • 2-(1,1-dimethylethoxy)-2-oxoethyl]triphenyl-Phosphonium bromide (1:1)
  • 59159-39-6
  • CH33CO2CCH2PC6H53Br
  • Synthetic Reagents
  • Wittig Reagents
  • Olefination
  • C-C Bond Formation
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents