2-Chlorobenzothiazo-6-amine

Product Name: 2-Chlorobenzothiazo-6-amine
CAS No.: 2406-90-8
Chemical Name: 2-Chlorobenzothiazo-6-amine
Synonyms: 2-CHLOROBENZOTHIAZO-6-AMINE;2-CHLOROBENZOTHIAZO-6YL-AMINE;6-Amino-2-chlorobenzothiazole;2-Chloro-6-aminobenzothiazole;6-Benzothiazolamine, 2-chloro-;2-chlorobenzo[d]thiazol-6-amine;2-CHLORO-BENZOTHIAZOL-6-YLAMINE;2-chloro-1,3-benzothiazol-6-aMine;6-Benzothiazolamine,2-chloro-(9CI);6-Amino-2-chlorobenzothiazole 97%
CBNumber: CB8392903
Molecular Formula: C7H5ClN2S
Formula Weight: 184.65
MOL File: 2406-90-8.mol

More

Less

2-Chlorobenzothiazo-6-amine Property

Melting point:: 155-157 °C
Boiling point:: 337.3±15.0 °C(Predicted)
Density: 1.532
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 2.09±0.10(Predicted)
Appearance: Light brown to yellow Solid
InChI: InChI=1S/C7H5ClN2S/c8-7-10-5-2-1-4(9)3-6(5)11-7/h1-3H,9H2
InChIKey: YPTWPDOGEAHMOR-UHFFFAOYSA-N
SMILES: S1C2=CC(N)=CC=C2N=C1Cl

More

Less

Safety

HS Code: 29342000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

TRC

Product number: A595410
Product name: 6-Amino-2-chlorobenzothiazole
Packaging: 1g
Price: $130
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC139615
Product name: 2-Chlorobenzo[d]thiazol-6-amine
Packaging: 500mg
Price: $65
Updated: 2021/12/16

AK Scientific

Product number: J54161
Product name: 6-Amino-2-chlorobenzothiazole
Packaging: 1g
Price: $80
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC139615
Product name: 2-Chlorobenzo[d]thiazol-6-amine
Packaging: 1g
Price: $116
Updated: 2021/12/16

SynQuest Laboratories

Product number: 7H70-5-76
Product name: 6-Amino-2-chlorobenzothiazole
Packaging: 1g
Price: $122
Updated: 2021/12/16

More

Less

2-Chlorobenzothiazo-6-amine Chemical Properties,Usage,Production

Synthesis

2407-11-6

2406-90-8

General procedure for the synthesis of 2-chloro-6-aminobenzothiazole from 2-chloro-6-nitrobenzothiazole: (B) Synthesis of 2-chloro-6-aminobenzothiazole (3) Compound 2 (1.96 g, 9.14 mmol) was dissolved in a solvent mixture of ethanol (150 mL) and purified water (100 mL), and anhydrous tin (II) chloride (20.7 g) was subsequently added to the solution (20.7 g, 91.7 mmol) was added to the solution. Next, a 4.8 mol/L hydrochloric acid solution (20 mL, 96 mmol) was added dropwise to the reaction mixture and the reaction was refluxed at 120 °C. The progress of the reaction was monitored by thin-layer chromatography (unfolding agent: dichloromethane), and after confirming the complete disappearance of the feedstock, the reaction mixture was alkalized with aqueous sodium hydroxide solution. The insoluble precipitate was removed by filtration and the filtrate was subsequently concentrated under reduced pressure. The residue was extracted three times with ethyl acetate, and the combined organic layers were washed with saturated brine, dried over anhydrous sodium sulfate, and finally concentrated under reduced pressure. The resulting crude product was purified by silica gel column chromatography (eluent: ethyl acetate/hexane = 1/1) to afford compound 3 in white solid form (1.02 g, 61% yield).1H-NMR (300 MHz, CDCl3) δ 3.85 (br, 2H), 6.81 (dd, 1H, J = 2.4, 8.7 Hz), 6.99 (d, 1H, J = 2.4 Hz), 7.70 (d, 1H, J = 8.7 Hz). ms (ESI+) m/z 185.0 [M + H]+.

References

[1] Patent: WO2004/37251, 2004, A1. Location in patent: Page/Page column 99; 100
[2] Journal of the American Chemical Society, 2010, vol. 132, # 39, p. 13586 - 13587
[3] Patent: US2007/155806, 2007, A1. Location in patent: Page/Page column 5
[4] Chemistry - An Asian Journal, 2011, vol. 6, # 7, p. 1800 - 1810
[5] Chemical Communications, 2013, vol. 49, # 77, p. 8644 - 8646

2-Chlorobenzothiazo-6-amine Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-Chlorobenzothiazo-6-amine Suppliers

China 72 Europe 1 France 1 India 1 United Kingdom 2 United States 13 Global 90

Fuyang JSK Biomedical Technology Co., Ltd

Tel: 18915409046
Fax: 0510-86566870
Email: 1102409417@qq.com
Country: China
ProdList: 268
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Pure Chemistry Scientific Inc.

Tel: 001-857-928-2050 or 1-888-588-9418
Fax: 001-617-206-9595
Email: sales@chemreagents.com
Country: United States
ProdList: 10186
Advantage: 62

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: chenyj@titansci.com
Country: China
ProdList: 14101
Advantage: 59

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Chengdu Forest Science and Technology Development Co., Ltd.

Tel: 18030648795
Fax: 028-61777050
Email: sales@cdforestchem.com
Country: China
ProdList: 1998
Advantage: 58

Shanghai Topbiochem Technology Co., Ltd

Tel: +86-21-60341587
Fax: +86-21-61294319
Email: sales@topbiochem.com
Country: China
ProdList: 6175
Advantage: 58

shanghai aokchem co., ltd

Tel: 021-68712331 39130253
Fax: 18621350903
Email: aokchem@gmail.com
Country: China
ProdList: 332
Advantage: 58

More

Less

View Lastest Price from 2-Chlorobenzothiazo-6-amine manufacturers

Career Henan Chemical Co

Product: 2-Chlorobenzothiazo-6-amine 2406-90-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg; 10kg; 100kg
Release date: 2019-08-30

2406-90-8, 2-Chlorobenzothiazo-6-amineRelated Search:

3-Aminophenol Dibenzylamine 2,2'-Dithiobis(benzothiazole) Glycine 6-Aminocaproic acid Triallylamine 2-Chlorobenzothiazole 6-Aminobenzothiazole Sulfamic acid 2-Benzothiazolamine Bis(2-ethylhexyl)amine Benzothiazole Acetaminophen Triethanolamine Glucosamine ALTRENOGEST EC 2.6.1.2 Tris(hydroxymethyl)aminomethane

6-Amino-2-chlorobenzothiazole 97%

2-CHLORO-BENZOTHIAZOL-6-YLAMINE

6-Benzothiazolamine,2-chloro-(9CI)

6-Benzothiazolamine, 2-chloro-

2-CHLOROBENZOTHIAZO-6-AMINE

2-Chloro-6-aminobenzothiazole

6-Amino-2-chlorobenzothiazole

2-CHLOROBENZOTHIAZO-6YL-AMINE

Benzothiazole, 6-amino-2-chloro- (6CI,7CI,8CI)

2-chlorobenzo[d]thiazol-6-amine

2-chloro-1,3-benzothiazol-6-aMine

2-Chloro-6-aminobenzo[d]thiazole, 97%

2406-90-8

BENZOTHIAZOLE