Ethyl chrysanthemumate

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Ethyl chrysanthemumate

Product Name: Ethyl chrysanthemumate
CAS No.: 97-41-6
Chemical Name: Ethyl chrysanthemumate
Synonyms: ETHYL CHRYSANTHEMATE;PNP-α-D-Gal;Ethyl chrysant;Cyclopropaneca;TIMTEC-BB SBB007714;Ethyl chrisanthemate;Ethyl chrysanthemat.;Ethyl chrysanthemuma;Ethyl ChrsantheMuMate;ETHYL CHRYSANTHEMUMATE
CBNumber: CB8400077
Molecular Formula: C12H20O2
Formula Weight: 196.29
MOL File: 97-41-6.mol

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Ethyl chrysanthemumate Property

Boiling point:: 112 °C10 mm Hg(lit.)
Density: 0.906 g/mL at 25 °C(lit.)
refractive index: n20/D 1.461(lit.)
Flash point:: 184 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Liquid
color: Yellow
Odor: at 10.00 % in dipropylene glycol. herbal wine fruity everlasting flower chrysanthemum sweet
Odor Type: herbal
BRN: 2045740
LogP: 4.181 (est)
CAS DataBase Reference: 97-41-6(CAS DataBase Reference)
NIST Chemistry Reference: Ethyl chrysanthemate(97-41-6)
EPA Substance Registry System: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)

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Safety

Safety Statements: 24/25
WGK Germany: 2
RTECS: GZ1727000
TSCA: Yes
HS Code: 29162090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2112
Product name: Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
Purity: >95.0%(GC)
Packaging: 25g
Price: $47
Updated: 2024/03/01

TCI Chemical

Product number: D2112
Product name: Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
Purity: >95.0%(GC)
Packaging: 100g
Price: $139
Updated: 2024/03/01

Alfa Aesar

Product number: H59589
Product name: Ethyl chrysanthemate, 95%
Packaging: 100g
Price: $84.2
Updated: 2021/12/16

Alfa Aesar

Product number: H59589
Product name: Ethyl chrysanthemate, 95%
Packaging: 25g
Price: $31.3
Updated: 2021/12/16

TRC

Product number: E903480
Product name: Ethyl chrysanthemate
Packaging: 25g
Price: $130
Updated: 2021/12/16

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Ethyl chrysanthemumate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid. Very slightly soluble in water, soluble in alcohol and oils. Powerful, winey-herbaccous, sweet and ethereal, very pleasant odor of intriguing complexity, and with a powerfully lifting minty undertone. The spicy-hcrbaccous, warm and almost green-floral notes resemble certain notes in the Jasmin complex.

Uses

Ethyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 1783, 1981 DOI: 10.1016/S0040-4039(01)90438-1
Synthesis, p. 600, 1976 DOI: 10.1055/s-1976-24132

Purification Methods

Purify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]

Ethyl chrysanthemumate Preparation Products And Raw materials

Raw materials

Copper diazoacetic acid methyl(±)cis，trans-2，2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate) Hydroquinone Ethylene glycol 2,5-Dimethyl-2,4-hexadiene Methyl acetate Ethyl diazoacetate

Preparation Products

2,2-Dimethyl-3-(2-methylpropyl)cyclopropanecarboxylic acid p-(methoxymethyl)benzyl ester Allethrin trans-(±)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid 2,2-DIMETHYL-3-(2-METHYLPROP-1-ENYL)CYCLOPROPANECARBOXYLIC ACID Tetramethrin

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View Lastest Price from Ethyl chrysanthemumate manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Ethyl chrysanthemumate 97-41-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-22

Hebei Chuanghai Biotechnology Co,.LTD

Product: Ethyl chrysanthemumate 97-41-6
Price: US $50.00-20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-16

Hebei Mojin Biotechnology Co., Ltd

Product: Ethyl chrysanthemumate 97-41-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-20

97-41-6, Ethyl chrysanthemumateRelated Search:

Poly(dimethylsiloxane) Diethyl malonate Dimethyl phthalate Ethyl acetate Ethyl acrylate Ethanol Ethyl propiolate Diethyl methylmalonate Ethyl formate Ethyl pyruvate Cyclopropane Dimethyl fumarate Ethylparaben Triethyl citrate Dimethyl sulfoxide RESMETHRIN Ethyl cinnamate 2-AMINODIETHYLMALONATE

(1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester

2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANE CARBOXYLIC ACID ETHYL ESTER

2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLIC ACID ETHYL ESTER

ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate

CHRYSANTHEMUM MONOCARBOXYLIC ACID ETHYL ESTER

CHRYSANTHEMYLMONOCARBOXYLIC ACID ETHYL ESTER

ETHYL CHRYSANTHEMATE

ETHYL CHRYSANTHEMUMATE

ETHYL 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLATE

ETHYL 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANECARBOXYLATE

TIMTEC-BB SBB007714

Chrisanthemic acid ethylester

Ethyl chrisanthemate

(+/-)-ETHYL CHRYSANTHEMUMATE, 95%, MIXTU RE OF CIS AND TRANS

ETHYL CHRYSANTHEMUMATE 95+% MIXTURE O&

Ethyl Chrysanthemate (Primary)

Ethyl chrysanthemumate, cis + trans, 98%

Primary ethyl chrysanthemat

Ethyl chrysanthemat.

Chrysanthemum monocarboxylic acid ethyl ester, 2,2-Dimethyl-3-(1-isobutenyl)cyclopropane-1-carboxylic acid ethyl ester

ethyl(±)cis，trans-2，2-dimethyl-3-(2-methyl propenyl cyclopropane carboxylate)

2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaciethylester

2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid ethyl ester

2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylicacidethylester

2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxylicaciethylester

chrysanthemicacidethylester

Chrysanthemum-monocarboxlic acid ethyl ester

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester

Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ethyl ester

ethylchrysanthemumate,mixtureofcisandtrans

Ethyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate

2,2-Dimethyl-3-isobutenylcyclopropanecarboxylic acid ethyl ester

3-[2-Methyl-1-propenyl]-2,2-dimethylcyclopropanecarboxylic acid ethyl ester

3-Isobutenyl-2,2-dimethyl-1-cyclopropanecarboxylic acid ethyl ester

Ethyl chrysanthemate,95%,mixture of cis and trans

2,2-Dimethyl-3-(2-methylpropenyl)-cyclo

Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate

Ethyl chrysanthemumate (cis/trans mixture)

Ethyl chrysanthemuma

Ethyl chrysanthemate, mixture of cis and trans, 95%

Ethyl chrysantheMate, Mixture of cis and trans, 95% 500GR

Chrysanthemylmonocarboxylic Acid Ethyl Ester Ethyl Chrysanthemate Ethyl Chrysanthemumate 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylic Acid Ethyl Ester

Ethyl ChrsantheMuMate

ethyl 2,2-diMethyl-3-(2-Methylprop-1-en-1-yl)cyclopropanecarboxylate

Cyclopropanecarboxylicacid, 2,2-diMethyl-3-(2-Methyl-1-propen-1-yl)-, ethyl ester

Ethyl chrysant

2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester

2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylic acid ethyl ester

Chrysanthemummonocarboxylic acid, ethyl ester (6CI)

Cyclopropaneca

L.C. Acid (2,2-Dimethyl-3-Trifloro Propenyl Cyclopropane Carbolic Acid)

Ethyl2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate&gt

Tetramethrin Related Compound 1

PNP-α-D-Gal

Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate, ≥ 95.0%

97-41-6

C12H20O2C12H20O2C12H20O2C12H20O2C12H20O2

Cyclopropanes