ChemicalBook > CAS DataBase List > Ethyl chrysanthemumate
Ethyl chrysanthemumate
- Product Name
- Ethyl chrysanthemumate
- CAS No.
- 97-41-6
- Chemical Name
- Ethyl chrysanthemumate
- Synonyms
- ETHYL CHRYSANTHEMATE;PNP-α-D-Gal;Ethyl chrysant;Cyclopropaneca;TIMTEC-BB SBB007714;Ethyl chrisanthemate;Ethyl chrysanthemat.;Ethyl chrysanthemuma;Ethyl ChrsantheMuMate;ETHYL CHRYSANTHEMUMATE
- CBNumber
- CB8400077
- Molecular Formula
- C12H20O2
- Formula Weight
- 196.29
- MOL File
- 97-41-6.mol
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Ethyl chrysanthemumate Property
- Boiling point:
- 112 °C10 mm Hg(lit.)
- Density
- 0.906 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.461(lit.)
- Flash point:
- 184 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Yellow
- Odor
- at 10.00 % in dipropylene glycol. herbal wine fruity everlasting flower chrysanthemum sweet
- Odor Type
- herbal
- BRN
- 2045740
- LogP
- 4.181 (est)
- CAS DataBase Reference
- 97-41-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Ethyl chrysanthemate(97-41-6)
- EPA Substance Registry System
- Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)
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Safety
- Safety Statements
- 24/25
- WGK Germany
- 2
- RTECS
- GZ1727000
- TSCA
- Yes
- HS Code
- 29162090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H303May be harmfulif swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D2112
- Product name
- Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $47
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D2112
- Product name
- Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate
- Purity
- >95.0%(GC)
- Packaging
- 100g
- Price
- $139
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H59589
- Product name
- Ethyl chrysanthemate, 95%
- Packaging
- 100g
- Price
- $84.2
- Updated
- 2021/12/16
Alfa Aesar
- Product number
- H59589
- Product name
- Ethyl chrysanthemate, 95%
- Packaging
- 25g
- Price
- $31.3
- Updated
- 2021/12/16
TRC
- Product number
- E903480
- Product name
- Ethyl chrysanthemate
- Packaging
- 25g
- Price
- $130
- Updated
- 2021/12/16
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Ethyl chrysanthemumate Chemical Properties,Usage,Production
Chemical Properties
clear colorless to yellow liquid. Very slightly soluble in water, soluble in alcohol and oils. Powerful, winey-herbaccous, sweet and ethereal, very pleasant odor of intriguing complexity, and with a powerfully lifting minty undertone. The spicy-hcrbaccous, warm and almost green-floral notes resemble certain notes in the Jasmin complex.
Uses
Ethyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.
Synthesis Reference(s)
Tetrahedron Letters, 22, p. 1783, 1981 DOI: 10.1016/S0040-4039(01)90438-1
Synthesis, p. 600, 1976 DOI: 10.1055/s-1976-24132
Purification Methods
Purify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]
Ethyl chrysanthemumate Preparation Products And Raw materials
Raw materials
Copper
diazoacetic acid
methyl(±)cis，trans-2，2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate)
Hydroquinone
Ethylene glycol
2,5-Dimethyl-2,4-hexadiene
Methyl acetate
Ethyl diazoacetate
Preparation Products
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Ethyl chrysanthemumate Suppliers
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- Germany
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- Germany
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- Germany
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- Germany
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- Germany
- ProdList
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View Lastest Price from Ethyl chrysanthemumate manufacturers
Hebei Chuanghai Biotechnology Co,.LTD
- Product
- Ethyl chrysanthemumate 97-41-6
- Price
- US $50.00-20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-16
Hebei Weibang Biotechnology Co., Ltd
- Product
- Ethyl chrysanthemumate 97-41-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-07-21
Hebei Mojin Biotechnology Co., Ltd
- Product
- Ethyl chrysanthemumate 97-41-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-06-20
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