BENZYL 2,2,2-TRICHLOROACETIMIDATE

Product Name: BENZYL 2,2,2-TRICHLOROACETIMIDATE
CAS No.: 81927-55-1
Chemical Name: BENZYL 2,2,2-TRICHLOROACETIMIDATE
Synonyms: Benzyl trichloroacetimidate;oroacetimidate;BENZYLPHOSPONIC ACID;LABOTEST-BB LT00455324;Benzyl 2,2,2-trichloroacetimide;BENZYL 2,2,2-TRICHLOROACETIMIDATE;benzyl 2,2,2-trichloroethaniMidate;Benzyl 2,2,2-trichloroethanimidoate;O-Benzyl 2,2,2-trichloroacetiMidate;TRICHLOROACETIMIDIC ACID BENZYL ESTER
CBNumber: CB8409616
Molecular Formula: C9H8Cl3NO
Formula Weight: 252.52
MOL File: 81927-55-1.mol

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BENZYL 2,2,2-TRICHLOROACETIMIDATE Property

Melting point:: 3 °C
Boiling point:: 106-114 °C0.5 mm Hg(lit.)
Density: 1.359 g/mL at 25 °C(lit.)
refractive index: n20/D 1.545(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Miscible with cyclohexane/dichloromethane.
form: Liquid
pka: 2.23±0.70(Predicted)
color: Clear colorless to yellow
Sensitive: Moisture Sensitive
BRN: 2525375
Stability:: Moisture Sensitive
CAS DataBase Reference: 81927-55-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38
Safety Statements: 26
WGK Germany: 3
F: 8-10-21
HS Code: 29252900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 140333
Product name: Benzyl 2,2,2-trichloroacetimidate
Purity: 99%
Packaging: 5g
Price: $41.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 140333
Product name: Benzyl 2,2,2-trichloroacetimidate
Purity: 99%
Packaging: 25g
Price: $138
Updated: 2024/03/01

TCI Chemical

Product number: B1483
Product name: Benzyl 2,2,2-Trichloroacetimidate
Purity: >97.0%(GC)
Packaging: 25g
Price: $94
Updated: 2024/03/01

Alfa Aesar

Product number: A12387
Product name: Benzyl 2,2,2-trichloroacetimidate, 98%
Packaging: 5g
Price: $32.65
Updated: 2024/03/01

Alfa Aesar

Product number: A12387
Product name: Benzyl 2,2,2-trichloroacetimidate, 98%
Packaging: 25g
Price: $90.65
Updated: 2024/03/01

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BENZYL 2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.

Uses

Benzyl 2,2,2-trichloroacetimidate was used as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It was used in the acid-catalyzed benzylation of hydroxy groups.

Uses

Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups.

Purification Methods

Purify the imidate by distillation to remove up to 1% of PhCH2OH as stabiliser. A solution in hexane can be stored for up to 2 months without decomposition. It is hygroscopic and has to be stored dry. [Wessel et al. J Chem Soc, Perkin Trans 1 2247 1985, Beilstein 6 IV 2265.]

BENZYL 2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZYL 2,2,2-TRICHLOROACETIMIDATE Suppliers

Americas 1 Belgium 1 China 133 Europe 3 France 2 Germany 3 India 4 Japan 1 Switzerland 2 United Kingdom 4 United States 21 Global 175

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-68311833 18306219922
Fax: 0512-68417696
Email: merry@highfine.com
Country: China
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J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
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Energy Chemical

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Accela ChemBio Co.,Ltd.

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Fax: 021-50795055
Email: sales@accelachem.com
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Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
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Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
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Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
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View Lastest Price from BENZYL 2,2,2-TRICHLOROACETIMIDATE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 99% HPLC
Supply Ability: 2000tons
Release date: 2019-12-30

Henan Aochuang Chemical Co.,Ltd.

Product: BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

81927-55-1, BENZYL 2,2,2-TRICHLOROACETIMIDATERelated Search:

2-Chloroethyl ethyl ether METHYL 2,2,2-TRICHLOROACETIMIDATE METHYL ACETIMIDATE HYDROCHLORIDE 6-Bromo-1-hexene ETHYL FORMIMIDATE HYDROCHLORIDE 1,1,1-Trichloroethane Dichloromethane Ammonium chloride BENZYL ETHYL ETHER 2-Chloroethanol BENZYL 2,2,2-TRICHLOROACETIMIDATE Trichloroethanol Chloroform Ethyl acetimidate hydrochloride Benzyl alcohol Benzyl methyl ether 2,2,2-Trichloroacetamide Chloroacetamide

2,2,2-TRICHLOROACETIMIDIC ACID BENZYL ESTER

Benzyl 2,2,2-trichloroacetimidate, 98+%

Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester

Benzyl 2,2,2-trichloroacetimidate, GC 99%

BENZYLPHOSPONIC ACID

Benzyl 2,2,2-trichloroethanimidoate

Benzyl trichloroacetimidate

TRICHLOROACETIMIDIC ACID BENZYL ESTER

LABOTEST-BB LT00455324

BENZYL 2,2,2-TRICHLOROACETIMIDATE

Benzyl 2,2,2-trichloroacetimidate, 99 %

AcetiMidic acid, 2,2,2-trichloro-, benzyl ester (6CI)

O-Benzyl 2,2,2-trichloroacetiMidate

Benzyl 2,2,2-trichloroacetimide

Benzyl 2,2,2-trichloroacetimidate 99%

Benzyl 2,2,2-trichloroacetiMidate, 99% 25GR

benzyl 2,2,2-trichloroethaniMidate

(2,2,2-trichloro-1-phenylmethoxyethylidene)azanide

Benzyl 2,2,2-Trichloroacetimidate &gt

oroacetimidate

BENZYL 2,2,2-TRICHLOROACETIMIDATE ISO 9001：2015 REACH

Phenylmethyl 2,2,2-trichloroethanimidate

81927-55-1

CCl3CNHOCH2C6H5

C9H8Cl3NO

Amidates/Imidates

Building Blocks

Nitrogen Compounds

Organic Building Blocks

Protection & Derivatization Reagents (for Synthesis)

Synthetic Organic Chemistry

Amidates/Imidates

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks

Benzene series