BENZYL 2,2,2-TRICHLOROACETIMIDATE
- Product Name
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
- CAS No.
- 81927-55-1
- Chemical Name
- BENZYL 2,2,2-TRICHLOROACETIMIDATE
- Synonyms
- Benzyl trichloroacetimidate;oroacetimidate;BENZYLPHOSPONIC ACID;LABOTEST-BB LT00455324;Benzyl 2,2,2-trichloroacetimide;BENZYL 2,2,2-TRICHLOROACETIMIDATE;benzyl 2,2,2-trichloroethaniMidate;Benzyl 2,2,2-trichloroethanimidoate;O-Benzyl 2,2,2-trichloroacetiMidate;TRICHLOROACETIMIDIC ACID BENZYL ESTER
- CBNumber
- CB8409616
- Molecular Formula
- C9H8Cl3NO
- Formula Weight
- 252.52
- MOL File
- 81927-55-1.mol
BENZYL 2,2,2-TRICHLOROACETIMIDATE Property
- Melting point:
- 3 °C
- Boiling point:
- 106-114 °C0.5 mm Hg(lit.)
- Density
- 1.359 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.545(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Miscible with cyclohexane/dichloromethane.
- form
- Liquid
- pka
- 2.23±0.70(Predicted)
- color
- Clear colorless to yellow
- Sensitive
- Moisture Sensitive
- BRN
- 2525375
- Stability:
- Moisture Sensitive
- CAS DataBase Reference
- 81927-55-1(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26
- WGK Germany
- 3
- F
- 8-10-21
- HS Code
- 29252900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 140333
- Product name
- Benzyl 2,2,2-trichloroacetimidate
- Purity
- 99%
- Packaging
- 5g
- Price
- $41.8
- Updated
- 2024/03/01
- Product number
- 140333
- Product name
- Benzyl 2,2,2-trichloroacetimidate
- Purity
- 99%
- Packaging
- 25g
- Price
- $138
- Updated
- 2024/03/01
- Product number
- B1483
- Product name
- Benzyl 2,2,2-Trichloroacetimidate
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $94
- Updated
- 2024/03/01
- Product number
- A12387
- Product name
- Benzyl 2,2,2-trichloroacetimidate, 98%
- Packaging
- 5g
- Price
- $32.65
- Updated
- 2024/03/01
- Product number
- A12387
- Product name
- Benzyl 2,2,2-trichloroacetimidate, 98%
- Packaging
- 25g
- Price
- $90.65
- Updated
- 2024/03/01
BENZYL 2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Usage,Production
Chemical Properties
clear colorless to yellow liquid
Uses
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Uses
Benzyl 2,2,2-trichloroacetimidate was used as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It was used in the acid-catalyzed benzylation of hydroxy groups.
Uses
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups.
Purification Methods
Purify the imidate by distillation to remove up to 1% of PhCH2OH as stabiliser. A solution in hexane can be stored for up to 2 months without decomposition. It is hygroscopic and has to be stored dry. [Wessel et al. J Chem Soc, Perkin Trans 1 2247 1985, Beilstein 6 IV 2265.]
BENZYL 2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
BENZYL 2,2,2-TRICHLOROACETIMIDATE Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from BENZYL 2,2,2-TRICHLOROACETIMIDATE manufacturers
- Product
- BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 99% HPLC
- Supply Ability
- 2000tons
- Release date
- 2019-12-30
- Product
- BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-26
- Product
- BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10