ChemicalBook > CAS DataBase List > BENZYL 2,2,2-TRICHLOROACETIMIDATE

BENZYL 2,2,2-TRICHLOROACETIMIDATE

Product Name
BENZYL 2,2,2-TRICHLOROACETIMIDATE
CAS No.
81927-55-1
Chemical Name
BENZYL 2,2,2-TRICHLOROACETIMIDATE
Synonyms
Benzyl trichloroacetimidate;oroacetimidate;BENZYLPHOSPONIC ACID;LABOTEST-BB LT00455324;Benzyl 2,2,2-trichloroacetimide;BENZYL 2,2,2-TRICHLOROACETIMIDATE;benzyl 2,2,2-trichloroethaniMidate;Benzyl 2,2,2-trichloroethanimidoate;O-Benzyl 2,2,2-trichloroacetiMidate;TRICHLOROACETIMIDIC ACID BENZYL ESTER
CBNumber
CB8409616
Molecular Formula
C9H8Cl3NO
Formula Weight
252.52
MOL File
81927-55-1.mol
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BENZYL 2,2,2-TRICHLOROACETIMIDATE Property

Melting point:
3 °C
Boiling point:
106-114 °C0.5 mm Hg(lit.)
Density 
1.359 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.545(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Miscible with cyclohexane/dichloromethane.
form 
Liquid
pka
2.23±0.70(Predicted)
color 
Clear colorless to yellow
Sensitive 
Moisture Sensitive
BRN 
2525375
Stability:
Moisture Sensitive
CAS DataBase Reference
81927-55-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26
WGK Germany 
3
F 
8-10-21
HS Code 
29252900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
140333
Product name
Benzyl 2,2,2-trichloroacetimidate
Purity
99%
Packaging
5g
Price
$41.8
Updated
2024/03/01
Sigma-Aldrich
Product number
140333
Product name
Benzyl 2,2,2-trichloroacetimidate
Purity
99%
Packaging
25g
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
B1483
Product name
Benzyl 2,2,2-Trichloroacetimidate
Purity
>97.0%(GC)
Packaging
25g
Price
$94
Updated
2024/03/01
Alfa Aesar
Product number
A12387
Product name
Benzyl 2,2,2-trichloroacetimidate, 98%
Packaging
5g
Price
$32.65
Updated
2024/03/01
Alfa Aesar
Product number
A12387
Product name
Benzyl 2,2,2-trichloroacetimidate, 98%
Packaging
25g
Price
$90.65
Updated
2024/03/01
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BENZYL 2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.

Uses

Benzyl 2,2,2-trichloroacetimidate was used as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It was used in the acid-catalyzed benzylation of hydroxy groups.

Uses

Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups.

Purification Methods

Purify the imidate by distillation to remove up to 1% of PhCH2OH as stabiliser. A solution in hexane can be stored for up to 2 months without decomposition. It is hygroscopic and has to be stored dry. [Wessel et al. J Chem Soc, Perkin Trans 1 2247 1985, Beilstein 6 IV 2265.]

BENZYL 2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZYL 2,2,2-TRICHLOROACETIMIDATE Suppliers

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View Lastest Price from BENZYL 2,2,2-TRICHLOROACETIMIDATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
99% HPLC
Supply Ability
2000tons
Release date
2019-12-30
Henan Aochuang Chemical Co.,Ltd.
Product
BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

81927-55-1, BENZYL 2,2,2-TRICHLOROACETIMIDATERelated Search:

2-Chloroethyl ethyl ether METHYL 2,2,2-TRICHLOROACETIMIDATE METHYL ACETIMIDATE HYDROCHLORIDE 6-Bromo-1-hexene ETHYL FORMIMIDATE HYDROCHLORIDE 1,1,1-Trichloroethane Dichloromethane Ammonium chloride BENZYL ETHYL ETHER 2-Chloroethanol BENZYL 2,2,2-TRICHLOROACETIMIDATE Trichloroethanol Chloroform Ethyl acetimidate hydrochloride Benzyl alcohol Benzyl methyl ether 2,2,2-Trichloroacetamide Chloroacetamide

  • 2,2,2-TRICHLOROACETIMIDIC ACID BENZYL ESTER
  • Benzyl 2,2,2-trichloroacetimidate, 98+%
  • Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester
  • Benzyl 2,2,2-trichloroacetimidate, GC 99%
  • BENZYLPHOSPONIC ACID
  • Benzyl 2,2,2-trichloroethanimidoate
  • Benzyl trichloroacetimidate
  • TRICHLOROACETIMIDIC ACID BENZYL ESTER
  • LABOTEST-BB LT00455324
  • BENZYL 2,2,2-TRICHLOROACETIMIDATE
  • Benzyl 2,2,2-trichloroacetimidate, 99 %
  • AcetiMidic acid, 2,2,2-trichloro-, benzyl ester (6CI)
  • O-Benzyl 2,2,2-trichloroacetiMidate
  • Benzyl 2,2,2-trichloroacetimide
  • Benzyl 2,2,2-trichloroacetimidate 99%
  • Benzyl 2,2,2-trichloroacetiMidate, 99% 25GR
  • benzyl 2,2,2-trichloroethaniMidate
  • (2,2,2-trichloro-1-phenylmethoxyethylidene)azanide
  • Benzyl 2,2,2-Trichloroacetimidate &gt
  • oroacetimidate
  • BENZYL 2,2,2-TRICHLOROACETIMIDATE ISO 9001：2015 REACH
  • Phenylmethyl 2,2,2-trichloroethanimidate
  • 81927-55-1
  • CCl3CNHOCH2C6H5
  • C9H8Cl3NO
  • Amidates/Imidates
  • Building Blocks
  • Nitrogen Compounds
  • Organic Building Blocks
  • Protection & Derivatization Reagents (for Synthesis)
  • Protection & Derivatization Reagents (for Synthesis)
  • Synthetic Organic Chemistry
  • Amidates/Imidates
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Benzene series