ChemicalBook > CAS DataBase List > 3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID

3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID

Product Name
3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
CAS No.
499-02-5
Chemical Name
3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
Synonyms
FEIST'S ACID;(-)-Feist acid;TIMTEC-BB SBB008097;SALOR-INT L167959-1EA;3-Methylenecyclopropane-trans-1;3-Methylene-1,2-cyclopropanedicarboxylic acid;3-METHYLIDENECYCLOPROPANE-1,2-DICARBOXYLIC ACID;trans-3-methylenecyclopropane-1,2-dicarboxylic acid;TRANS-1-METHYLENECYCLOPROPANE-2,3-DICARBOXYLIC ACID;3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
CBNumber
CB8422527
Molecular Formula
C6H6O4
Formula Weight
142.11
MOL File
499-02-5.mol
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3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID Property

Melting point:
197-201 °C
Boiling point:
219.65°C (rough estimate)
Density 
1.3863 (rough estimate)
refractive index 
1.5800 (estimate)
storage temp. 
-20°C
pka
3.48±0.40(Predicted)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-36/37/38
Safety Statements 
24/25-36-26
HS Code 
29172000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
S686618
Product name
3-Methylenecyclopropane-trans-1,2-dicarboxylicAcid
Packaging
50mg
Price
$175
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0023851
Product name
3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
Purity
95.00%
Packaging
1G
Price
$852.55
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0023851
Product name
3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
Purity
95.00%
Packaging
2.5G
Price
$1227.82
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0023851
Product name
3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
Purity
95.00%
Packaging
5G
Price
$1548.26
Updated
2021/12/16
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3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

off-white to beige crystalline powder

Uses

(1S,2S)-3-methylidenecyclopropane-1,2-dicarboxylic acid (cas# 499-02-5) is used in the regioselective green preparation antibacterial and antifungal activity of (arylnitroethyl)indoles and (arylnitroethyl)pyrroles by Michael addition of indole and pyrrole to trans-β-nitroolefins catalyzed by hydrogen bond donor Feist''s catalyst.

3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID Suppliers

499-02-5, 3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACIDRelated Search:


  • 1,2-Cyclopropanedicarboxylic acid, 3-methylene-, trans-
  • 3-Methylene-1,2-cyclopropanedicarboxylic acid
  • 3-Methylenecyclopropane-1,2-dicarboxylic acid, trans-
  • SALOR-INT L167959-1EA
  • TIMTEC-BB SBB008097
  • TRANS-1-METHYLENECYCLOPROPANE-2,3-DICARBOXYLIC ACID
  • trans-3-methylenecyclopropane-1,2-dicarboxylic acid
  • 3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID (FEIST''S ACID)
  • 3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
  • 3-METHYLIDENECYCLOPROPANE-1,2-DICARBOXYLIC ACID
  • FEIST'S ACID
  • DL-3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID
  • trans-3-Methylene-1,2-cyclopropanedicarboxylic acid
  • (-)-Feist acid
  • (1R,2R)-3-Methylene-1,2-cyclopropanedicarboxylic acid
  • (1R,2R)-3-Methylenecyclopropane-1,2-dicarboxylic acid
  • (1S)-3-Methylenecyclopropane-1β,2α-dicarboxylic acid
  • 3-Methylenecyclopropane-trans-1,2-dicarboxylic acid (Feist's aci
  • 3-Methylenecyclopropane-trans-1,2-dicarboxylic acid,98%
  • 1-Methylenecyclopropane-trans-2,3-dicarboxylic acid
  • 3-Methylenecyclopropane-trans-1
  • rac-(1R,2R)-3-methylidenecyclopropane-1,2-dicarboxylic acid, trans
  • 1,2-Cyclopropanedicarboxylic acid, 3-methylene-, (1R,2R)-rel-
  • 499-02-5