Iodine monochloride

ChemicalBook > CAS DataBase List > Iodine monochloride

Iodine monochloride

Product Name: Iodine monochloride
CAS No.: 7790-99-0
Chemical Name: Iodine monochloride
Synonyms: ICl;IODINE CHLORIDE;WIJS REAGENT;IODOCHLORIDE;WIJS SOLUTION;IODOMONOCHLORIDE;Iodine Monochlorid;Iodine monochloride solution;Iodine Monochloride 40% Solution in Acetic Acid;iodochlorine
CBNumber: CB8664819
Molecular Formula: ClI
Formula Weight: 162.36
MOL File: 7790-99-0.mol

Less

Iodine monochloride Property

Melting point:: 25-27°C
Boiling point:: 97.4 °C (lit.)
Density: 3.24 g/mL at 25 °C (lit.)
vapor density: 5.5 (vs air)
Flash point:: 96-98°C
storage temp.: 2-8°C
solubility: acetic acid: soluble(lit.)
form: Liquid
color: Red-brown
PH: <1 (H2O, 20°C)
Water Solubility: decomposes
Sensitive: Moisture Sensitive
Merck: 14,5017
BRN: 3902972
Exposure limits: ACGIH: TWA 50 ppm
OSHA: TWA 25 ppm; STEL 125 ppm
NIOSH: IDLH 2300 ppm
Stability:: Stable. Incompatible with organic materials, strong bases, metals. Air, light and moisture sensitive.
CAS DataBase Reference: 7790-99-0(CAS DataBase Reference)
NIST Chemistry Reference: Iodine monochloride(7790-99-0)
EPA Substance Registry System: Iodine chloride (ICl) (7790-99-0)

Less

Safety

Hazard Codes: C
Risk Statements: 34-42-35-10-40-67-37
Safety Statements: 26-36/37/39-45-23
RIDADR: UN 1792 8/PG 2
WGK Germany: 3
RTECS: NN1650000
F: 1-8-10
TSCA: Yes
HS Code: 3822 00 00
HazardClass: 8
PackingGroup: II
Hazardous Substances Data: 7790-99-0(Hazardous Substances Data)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.04771
Product name: Iodine monochloride
Purity: for synthesis
Packaging: 100g
Price: $151
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.04771
Product name: Iodine monochloride
Purity: for synthesis
Packaging: 250g
Price: $304
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208221
Product name: Iodine monochloride
Purity: reagent grade, ≥95%
Packaging: 5g
Price: $58.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208221
Product name: Iodine monochloride
Purity: reagent grade, ≥95%
Packaging: 100g
Price: $175
Updated: 2024/03/01

Sigma-Aldrich

Product number: 1.09163
Product name: Wijs solution
Purity: for determination of the iodine number c(ICl) = 0.1 mol/l Titripur?
Packaging: 1L
Price: $140
Updated: 2024/03/01

Less

Iodine monochloride Chemical Properties,Usage,Production

Chemical Properties

Iodine monochloride is a reddish brown liquid or black crystals, there are two variants of crystals. α-type is black needles, stable, ruby red under light. β-type is black flakes, unstable, brownish red under light. It has the odor of chlorine and iodine. It does not absorb moisture but can form iodine pentoxide when contacting air. Soluble in water, ethanol, ether, carbon disulfide, and acetic acid, relative density (d0) α-type 3.1822, (d34) β-type 3.24. Melting point α-type 27.2 ℃, β-type 13.9 ℃. Boiling point α-type 97.4°C, β-type 97.4, 100°C (decomposition). It also exhibits corrosive properties. It has the flavor of chlorine and iodine, and it is oxidative and strongly corrosive, and iodination with organic matter, it also shows chlorination, and it can be used for the substitution of the aromatic ring.

Uses

Iodine monochloride is used to estimate theiodine values of fats and oils and as a topicalanti-infective (Merck 1996). For determination of iodine absorption number of fats Iodine monochloride is used as a catalyst in organic synthesis. It is the source of electrophilic iodine in the synthesis of certain aromatic iodides.

Preparation

Iodine monochloride is prepared by the action of liquid or dry chlorine on astoichiometric quantity of solid iodine. Aqueous solutions of ICl are preparedby passing chlorine gas into a suspension of iodine in moderately stronghydrochloric acid:
5I₂ + 4HCl + 3Cl₂ → 10ICl + 2H₂
Alternatively, iodine monochloride may be made by oxidation of iodine withiodic acid in strong hydrochloric acid solution:
2I₂ + HIO₃ + 2HCl → 2ICl + 3HIO

Air & Water Reactions

Reacts with air to form iodine pentaoxide (I2O5), which decomposes into iodine (I2) and oxygen (O2) with heat beginning at 275°C and proceeding rapidly at 350°C. Soluble in water; reacts with water or steam to produce toxic and corrosive fumes [Lewis].

Reactions

Iodine monochloride is moderately explosive when heated [Lewis]. Reacts with rubber and many organic materials. Enflames (after a period of delay) with aluminum foil [Mellor 2:119(1946-1947)]. Reacts dangerously with other active metals. Reacts vigorously with cadmium sulfide, lead sulfide, silver sulfide, and zinc sulfide [Mellor 2, Supp. 1:502(1956)]. Combines very exothermically with phosphorus trichloride [Mellor 2, Supp. 1:502(1956)]. Forms Iodine pentaoxide in air which reacts explosively when warmed with carbon, sulfur, sugar, resin, or powdered combustible elements [Mellor 8: 841(1946-1947)].

Hazard

Toxic by ingestion and inhalation, strong irritant to eyes and skin. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Health Hazard

Iodine monochloride is highly corrosive tothe skin. Contact with the skin causes burns and dark patches. Upon contact, washimmediately with 15-20% HCl. Vapors areirritating to the skin, eyes, and mucous mem branes. The compound is moderate to highlytoxic by an oral route. The lethal dose in ratsis 59 mg/kg (NIOSH 1986).

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Purification Methods

Purify it by repeated fractional crystallisation from its melt at low temperatures. The black crystals melt to a red-brown liquid. [Cornog & Karges Inorg Synth I 165 1939.]

Iodine monochloride Preparation Products And Raw materials

Raw materials

Preparation Products

5-IODOISATIN 6,10,12-trichloronaphth[2,3-c]acridine-5,8,14(13H)-trione 5-Amino-2,4,6-triiodo-N-methylisophthalamic Acid 2-Amino-5-iodobenzoic acid 3,5-Diiodosalicylic acid 2,6-DIIODO-4-NITROANILINE N-Acetyl-3,5-diiodo-L-tyrosine ethyl ester 3-Amino-2,4,6-triiodobenzoic acid 4-Iodoanisole 3-(3-AMINO-2,4,6-TRIIODOPHENYL)PROPIONIC ACID 2,4-DICHLORO-5-IODOPYRIMIDINE 3-Cyano-4-hydroxybenzoic acid

Less

Iodine monochloride Suppliers

Belgium 1 Canada 1 China 206 Europe 2 Germany 5 India 43 Japan 4 Switzerland 1 United Kingdom 6 United States 36 Global 305

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Yield Pharmaceutical Techonlogy (Suzhou) Co.,Ltd.

Tel: 13382188332
Email: 307446954@qq.com
Country: China
ProdList: 32
Advantage: 58

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Shanghai Taijilin Industrial Co., Ltd.

Tel: 021-021-50630626 18964684208
Fax: 021-50563898
Email: kate@tajilin.com
Country: China
ProdList: 1230
Advantage: 58

Qingdao Tocean iodine products co. LTD

Tel: 18669835223
Email: tuohaidian@163.com
Country: China
ProdList: 49
Advantage: 58

Shanghai Qiao Chemical Science Co., Ltd

Tel: 021-58892003
Email: info@qiaochem.com
Country: China
ProdList: 5902
Advantage: 65

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Beijing dtftchem Technology Co., Ltd.

Tel: 010-60275820 13031183356
Fax: 010-60270825
Email: elainezt@sina.com
Country: China
ProdList: 1390
Advantage: 62

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Secco work (Beijing) chemical technology co., LTD

Tel: 0566-8928158
Fax: 010-69755668
Email: 343367102@QQ.COM
Country: China
ProdList: 360
Advantage: 54

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
Advantage: 57

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11707
Advantage: 57

China Langchem Inc.

Tel: 0086-21-58956006
Fax: 0086-21-58956100
Country: China
ProdList: 7811
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Henan Wanxiang Chemical Industry Co., Ltd.

Tel: 0371-56669001 13949088811
Fax: 0371-56669008
Email: Sales@58chem.cn
Country: China
ProdList: 89
Advantage: 62

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4378
Advantage: 65

Springchem New Material Technology Co.,Limited

Tel: +86-021-62885108 +8613917661608
Email: info@spring-chem.com
Country: China
ProdList: 2068
Advantage: 57

Spectrum Chemical Manufacturing Corp.

Tel: 021-021-021-67601398-809-809-809 15221380277
Fax: 021-57711696
Email: marketing_china@spectrumchemical.com
Country: China
ProdList: 9658
Advantage: 60

Shanghai Shenyue Chemical Co., Ltd.

Tel: 021-021-52212593 18049974220
Fax: +86 (21) 51062076
Email: 2982497773@qq.com
Country: China
ProdList: 1622
Advantage: 60

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9545
Advantage: 55

Cantotech Chemicals, Ltd.

Tel: 86-0755-86635001
Fax: 86-0755-22642228
Email: cantotech@126.com
Country: China
ProdList: 4566
Advantage: 55

Shanghai Yolne Chemical Co., Ltd.

Tel: 021-62960152
Fax: 021-52212593
Email: 934678158@qq.com
Country: China
ProdList: 9899
Advantage: 55

Quzhou Juhua Friendship Co., Ltd

Tel: 0570-3066667
Fax: 0570-3063388
Country: China
ProdList: 3930
Advantage: 58

ShangHai Zexin Chemical Technology Co., Ltd.

Tel: 021-60136491 15901897992
Fax: 021-60136492
Country: China
ProdList: 455
Advantage: 55

Beijing Universal Century Technology Co., Ltd.

Tel: 400-8706899
Fax: 400-8706899
Email: hysj_bj.com
Country: China
ProdList: 3583
Advantage: 55

Shanghai Meishui Chemical Technology Co., Ltd

Tel: 021-60549325 18616193163
Fax: 021-33250306
Country: China
ProdList: 4526
Advantage: 56

Mei Lan Industrial (Shanghai) Co., Ltd.

Tel: 021-58958189
Fax: 021-58957967
Email: wouchina@126.com
Country: China
ProdList: 2666
Advantage: 55

Shanghai ideal Industrial Co., Ltd.

Tel: 021-58957966 18930537195
Fax: 021-60899437
Email: wouchina@126.com
Country: China
ProdList: 3027
Advantage: 58

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

GuangTuo Chemical (Shanghai) Co., Ltd.

Tel: 021-60899189-8001 18918189673
Fax: 021-60899304
Email: gtchem@126.com
Country: China
ProdList: 2656
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10276
Advantage: 55

ShangHai DeBang Chemical Co., Ltd.

Tel: 021-61531158
Fax: 021-66315205
Email: 910583793@qq.com
Country: China
ProdList: 284
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 16166
Advantage: 55

SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.

Tel: 021-69106960 13701823733
Fax: 021-69106780
Email: 13701823733@163.com
Country: China
ProdList: 4767
Advantage: 60

Shanghai Song Yuan Chemical Technology Co., Ltd.

Tel: 010-1234567 18521000990
Fax: 86-021-33275113
Email: sonyuanchemical@163.com
Country: China
ProdList: 6479
Advantage: 50

Shanghai YouPeng Chemical Co. Ltd.

Tel: 021-69005955 13701776567
Fax: 021-69005775
Email: youpengchem@163.com
Country: China
ProdList: 4293
Advantage: 56

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 18112977050
Email: cb6@aikonchem.com
Country: China
ProdList: 16684
Advantage: 50

Shanghai TongYuan Chemical Co., Ltd.

Tel: 021-021-69182866 13701855675
Fax: 021-69182022
Email: tongyuanchem@126.com
Country: China
ProdList: 4321
Advantage: 58

Shanghai Kaisai Chemical Co., Ltd

Tel: 021-33516722 13701817765
Fax: 021-33516776
Email: kaisaichem@163.com
Country: China
ProdList: 4741
Advantage: 58

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 13096311329 028-88469284 616445927
Fax: 028-88469284
Email: 616445927@qq.com
Country: China
ProdList: 2874
Advantage: 50

Shanghai LanRun Chemical Co., Ltd.

Tel: 021-69515658 ; 69515628 13701998368
Fax: 021-69515998
Email: longrunchem@163.com
Country: China
ProdList: 3912
Advantage: 50

Less

View Lastest Price from Iodine monochloride manufacturers

Career Henan Chemical Co

Product: Iodine monochloride 7790-99-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-11

7790-99-0, Iodine monochlorideRelated Search:

Povidone iodine Chlorobenzene Calcium chloride Potassium chloride Aluminum chlorohydrate Ammonium chloride Disulfur dichloride Sodium chloride Iodine monobromide Iodine Magnesium chloride hexahydrate Iodomethane 1-Chloropinacolone Difluorochloromethane 2-CHLORO-2,2-DIFLUOROACETOPHENONE TETRA-N-BUTYLAMMONIUM IODOTETRACHLORIDE Acetic acid (DICHLOROIODO)-BENZENE Iodine Monochloride Solution

IodineMonochlorideForSynthesis(5X25Grams)

Iodinemonochloride,97%

Iodinechloride,ACS

Iodine monochloride, ACS

Iodine monochloride solution (Wijs' chloride)

Chloroiodide solution, Iodine according to Wijs for the iodine value determination, Iodine monochloride solution, Wijs solution

Chloroiodide solution, Wijs solution

Iodine Monochloride, Reagent

IODOMONOCHLORIDE

IODOCHLORIDE

IODINE SOLUTION ACCORDING TO WIJS

iodochlorine

Protochlorure D'iode

protochlorured’iode

protochlorured’iode(french)

IODINE MONOCHLORIDE, A.C.S. REAGENT

Wijs solution, 0,1 mol Cl/l, volumetric solution

Iodine monochloride, 99.998% metals basis

WIJS SOL. FOR DET. OF IODINE VALUE 0.1

IODINE MONOCHLORIDE REAGENT GRADE 98%

IODINE MONOCHLORIDE 1.0M SOLUTION &

IODINE MONOCHLORIDE, 1.0M SOLUTION IN DI CHLOROMETHANE

IODINE MONOCHLORIDE BOTTLE OF 100 G

IodineMonochlorideForSynthesis(5X50Grams)

IodineMonochlorideForSynthesis

Iodine(I) chloride

Iodine monochloride, reagent ACS

Iodine monochloride solution

Iodine monochloride,1M solution in dichloromethane

Iodine monochloride,98%

Iodine monochL

Iodmonochlorid

Monochloroiodine

(DG) Iodine monochloride 10g [7790-99-0]

Iodine chloride/ 98+%

Iodine monochloride,Chloroiodide

Iodine monochloride, 1M solution in dichloromethane, AcroSeal

Iodine Monochloride, 98% 100GR

Iodine Monochloride, reagent ACS 25GR

Iodine Monochlorid

Iodine Monochloride, approx. 0.22N soln. in glacial acetic acid

WIJS SOLUTION

WIJS' SOLUTION

WIJS REAGENT

WIJS' REAGENT

WIJS IODINE SOLUTION

WIJ'S IODINE SOLUTION

WIJS CHLORIDE

WIJS' CHLORIDE

chlorineiodide(cli)

ICl

Iodine chloride (ICl)

iodinechloride(icl)

iodinechloride[icl]

iodinemonochloride(dot)

Chloroiodide solution, Iodine according to Wijs for the iodine valu

IODINE MONOCHLORIDE SOLUTION, WIJS

IODINE MONOCHLORIDE