ChemicalBook > CAS DataBase List > (-)-CITRONELLAL

(-)-CITRONELLAL

Product Name
(-)-CITRONELLAL
CAS No.
5949-05-3
Chemical Name
(-)-CITRONELLAL
Synonyms
96.0%(GC);Citrnellal;(-)-Citrnellal;CITRONELLAL(L-);(-)-CITRONELLAL;L(-)-Citronellal;(S)-(-)-CITRONELLAL;(-)-Citronellal >L(-)-Citronellal,97%;(S)-(-)-Citronellal 96%
CBNumber
CB8666510
Molecular Formula
C10H18O
Formula Weight
154.25
MOL File
5949-05-3.mol
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(-)-CITRONELLAL Property

Boiling point:
227.64°C (estimate)
Density 
0.851 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.447
Flash point:
168 °F
storage temp. 
Hygroscopic, Refrigerator, under inert atmosphere
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Oil
color 
Colourless
Odor
at 10.00 % in dipropylene glycol. clean herbal citrus
Odor Type
citrus
optical activity
[α]20/D 15°, neat
BRN 
1720790
LogP
3.482 (est)
CAS DataBase Reference
5949-05-3(CAS DataBase Reference)
EPA Substance Registry System
6-Octenal, 3,7-dimethyl-, (3S)- (5949-05-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
F 
10-23
HS Code 
29121900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
373753
Product name
(S)-(?)-Citronellal
Purity
96%
Packaging
1g
Price
$48.3
Updated
2024/03/01
Sigma-Aldrich
Product number
373753
Product name
(S)-(?)-Citronellal
Purity
96%
Packaging
5g
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
C1454
Product name
(-)-Citronellal
Purity
>96.0%(GC)
Packaging
5mL
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
C1454
Product name
(-)-Citronellal
Purity
>96.0%(GC)
Packaging
25mL
Price
$185
Updated
2024/03/01
TRC
Product number
C525050
Product name
(-)-Citronellal
Packaging
25ml
Price
$660
Updated
2021/12/16
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(-)-CITRONELLAL Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO PALE YELLOW LIQUID

Uses

(S)-(-)-Citronellal may be used in the synthesis of bioactive compounds like (+)-hexahydrocannabinol, (S)-isopulegol, machaeriols A and B.

Definition

ChEBI: The (3S)-stereoisomer of 3,7-dimethyloct-6-enal (citronellal).

General Description

(S)-(-)-Citronellal is a monoterpenoid compound mainly found in Corymbia citriodora and Cymbopogon nardus essential oils.

Purification Methods

Fractionally distil it. Alternatively extract it with NaHSO3 solution, wash it with Et2O, then acidify it to decompose the bisulfite adduct and extract with Et2O, dry (Na2SO4), evaporate and distil. Check for purity by hydroxylamine titration. The ORD in MeOH (c 0.167) is: []700 +9o, []589 +11o, []275 +12o and []260 +12o. The semicarbazone has m 85o, and the 2,4-dinitrophenylhydrazone has m 79-80o. [(+)-compound: Tietze & Beifuss Org Synth 71 167 1993, IR: Carroll et al. J Chem Soc 3457 1950, ORD: Djerassi & Krakower J Am Chem Soc 81 237 1959, Beilstein 1 IV 3515.]

(-)-CITRONELLAL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (-)-CITRONELLAL manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(S)-(-)-Citronellal 96% 5949-05-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

5949-05-3, (-)-CITRONELLALRelated Search:

Dehydroepiandrosterone Sodium prasterone sulfate PHORBOL 12-MYRISTATE 13-ACETATE Citronellal DEHYDROANDROSTERONE ACETATE PHORBOL 12,13,20-TRIACETATE, 4BETA 4ALPHA-PHORBOL PHORBOL-12-MONOMYRISTATE 4ALPHA-PHORBOL 12,13-DIDECANOATE 20-OXO-20-DEOXYPHORBOL 12,13-DIBUTYRATE PHORBOL 12-MYRISTATE 13-ACETATE 4-O-METHYL ETHER, 4BETA PHORBOL 13-ACETATE PHORBOL 12,13-DIACETATE PHORBOL-12-DECANOATE PHORBOL 12,13-DIBUTYRATE PHORBOL 12,13-DIBENZOATE PHORBOL 13,20-DIACETATE PHORBOL 12-MONOACETATE, 4BETA

  • (S)-(-)-Citronellal 96%
  • L(-)-Citronellal
  • CITRONELLAL(L-)
  • (3S)-3,7-dimethyl-6-Octenal
  • (-)-CITRONELLAL WITH GC
  • (S)-(-)-3,7-DIMETHYL-6-OCTENAL
  • (S)-3,7-DIMETHYL-6-OCTENAL
  • (S)-(-)-CITRONELLAL
  • 3,7-dimethyl-,(3S)-6-Octenal
  • 7-dimethyl-(s)-6-octena
  • (-)-Citrnellal
  • Citrnellal
  • (-)-Citronellal, (3S)-3,7-Dimethyl-6-octenal
  • L(-)-Citronellal,97%
  • 2-Chloro-4-phenylphenol &gt
  • 3,5-Bis(tert-butylthio)benzyl Alcohol &gt
  • 96.0%(GC)
  • (S)-4-(4-Methoxybenzyloxy)-1,3-butanediol&gt
  • (-)-Citronellal &gt
  • 1-(2-Bromoethoxy)-2-ethoxybenzene &gt
  • 6-Octenal, 3,7-dimethyl-, (3S)-
  • (-)-CITRONELLAL
  • Endogenous Metabolite,Inhibitor,(S)? ?( ?)? ?Citronellal,(S)??(?)??Citronellal,inhibit
  • (S)-(-)-3,7-Dimethyl-6-Octenal|||(-?)?-?Citronellal
  • (3S)-3,7-dimethyloct-6-enal
  • 5949-05-3
  • Terpenes
  • Acyclic Monoterpenes
  • ALDEHYDE
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Aldehydes
  • Organic Building Blocks
  • Asymmetric Synthesis
  • Building Blocks
  • C10-C12
  • Carbonyl Compounds
  • Chemical Synthesis
  • Chiral Building Blocks
  • Citrus aurantium (Seville orange)
  • Elettaria Cardamomum (Cardamom)
  • Nutrition Research
  • Organic Building Blocks
  • Phytochemicals by Plant (Food/Spice/Herb)
  • Zingiber officinale (Ginger)
  • Acyclic Monoterpenes
  • Biochemistry
  • Terpenes
  • Aldehydes